Electrochemical synthesis of cobalt polyporphine films View Full Text


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Article Info

DATE

2016-11

AUTHORS

O. I. Istakova, D. V. Konev, C. H. Devillers, M. A. Vorotyntsev, A. S. Zyubin, E. M. Antipov, S. M. Aldoshin

ABSTRACT

A method for modification of the inert electrode surface with an electroactive polymeric film containing the CoN4 catalytic site has been suggested and approved. The described approach affords the maximal content of the metal porphine moiety per unit weight of the coating. The classical method of introduction of an ion into the porphine macrocycle has been replaced by electrochemical polarization of an electrode with a metallated film in a dilute solution. The metalation efficiency has been demonstrated by the presence of changes in the current–voltage and spectral characteristics of the resulting polymeric films of the unsubstituted porphine pH2P and cobalt polyporphine pCoP. More... »

PAGES

181-184

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012501616110038

DOI

http://dx.doi.org/10.1134/s0012501616110038

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033786291


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