Synthesis of B-Chloro(organo)silylmethyl-o-carboranes View Full Text


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Article Info

DATE

2020-05

AUTHORS

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

ABSTRACT

Monosubstituted B-chloro(organo)silylmethyl-o-carboranes have been synthesized for the first time by the reaction of o-carborane with chloromethyl(organo)chlorosilanes in the presence of catalytic amount of aluminum chloride. The reaction proceeds at temperature of 200–250°C under a pressure of 22–25 atm. A decrease in the number of chlorine atoms in the molecule of chloromethyl(organo)chlorosilane decreases the yield of the target product. More... »

PAGES

73-75

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Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s001250082005002x

DOI

http://dx.doi.org/10.1134/s001250082005002x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1131843087


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