Polymers with Regular Alternation of 1,7-Bis[(dimethyl)silylmethylene]-m-carborane and Diorganosiloxane Units View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-10

AUTHORS

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

ABSTRACT

New highly thermally stable carboranylmethyl-containing diorganosiloxane polymers were obtained by polycondensation of equimolar amounts of 1.7-bis[hydroxy(dimethyl)silylmethylene]-m-carborane and bis(dimethylamino)diorganosilanes. It was shown that replacement of 24 to 33 mol % of dimethylsiloxane units in the polymer backbone by methyl(phenyl)siloxane or diphenylsiloxane units containing bulky phenyl groups results in the formation of only amorphous polymers. The polymers are readily soluble in organic solvents and have high thermal stability. More... »

PAGES

249-251

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s001250081910001x

DOI

http://dx.doi.org/10.1134/s001250081910001x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1122512993


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Izmaylov", 
        "givenName": "B. A.", 
        "id": "sg:person.014243522747.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014243522747.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vasnev", 
        "givenName": "V. A.", 
        "id": "sg:person.016446506525.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016446506525.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Markova", 
        "givenName": "G. D.", 
        "id": "sg:person.016434044347.74", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016434044347.74"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2019-10", 
    "datePublishedReg": "2019-10-01", 
    "description": "New highly thermally stable carboranylmethyl-containing diorganosiloxane polymers were obtained by polycondensation of equimolar amounts of 1.7-bis[hydroxy(dimethyl)silylmethylene]-m-carborane and bis(dimethylamino)diorganosilanes. It was shown that replacement of 24 to 33 mol % of dimethylsiloxane units in the polymer backbone by methyl(phenyl)siloxane or diphenylsiloxane units containing bulky phenyl groups results in the formation of only amorphous polymers. The polymers are readily soluble in organic solvents and have high thermal stability.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s001250081910001x", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082681", 
        "issn": [
          "0012-5008", 
          "1608-3113"
        ], 
        "name": "Doklady Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "488"
      }
    ], 
    "keywords": [
      "bulky phenyl groups", 
      "diphenylsiloxane units", 
      "high thermal stability", 
      "polymer backbone", 
      "dimethylsiloxane units", 
      "organic solvents", 
      "phenyl group", 
      "polymers", 
      "amorphous polymers", 
      "equimolar amounts", 
      "thermal stability", 
      "carboranes", 
      "polycondensation", 
      "solvent", 
      "backbone", 
      "regular alternation", 
      "stability", 
      "formation", 
      "units", 
      "amount", 
      "alternation", 
      "group", 
      "replacement"
    ], 
    "name": "Polymers with Regular Alternation of 1,7-Bis[(dimethyl)silylmethylene]-m-carborane and Diorganosiloxane Units", 
    "pagination": "249-251", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1122512993"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s001250081910001x"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s001250081910001x", 
      "https://app.dimensions.ai/details/publication/pub.1122512993"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T21:03", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_790.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s001250081910001x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s001250081910001x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s001250081910001x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s001250081910001x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s001250081910001x'


 

This table displays all metadata directly associated to this object as RDF triples.

94 TRIPLES      20 PREDICATES      48 URIs      40 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s001250081910001x schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N5ee16ac6498541ac9294c824b323341e
4 schema:datePublished 2019-10
5 schema:datePublishedReg 2019-10-01
6 schema:description New highly thermally stable carboranylmethyl-containing diorganosiloxane polymers were obtained by polycondensation of equimolar amounts of 1.7-bis[hydroxy(dimethyl)silylmethylene]-m-carborane and bis(dimethylamino)diorganosilanes. It was shown that replacement of 24 to 33 mol % of dimethylsiloxane units in the polymer backbone by methyl(phenyl)siloxane or diphenylsiloxane units containing bulky phenyl groups results in the formation of only amorphous polymers. The polymers are readily soluble in organic solvents and have high thermal stability.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf Na1c1db6ca74d4d2daa53868763b01c17
10 Nd1d76d3e9cf94bbaaf8cf52a92584107
11 sg:journal.1082681
12 schema:keywords alternation
13 amorphous polymers
14 amount
15 backbone
16 bulky phenyl groups
17 carboranes
18 dimethylsiloxane units
19 diphenylsiloxane units
20 equimolar amounts
21 formation
22 group
23 high thermal stability
24 organic solvents
25 phenyl group
26 polycondensation
27 polymer backbone
28 polymers
29 regular alternation
30 replacement
31 solvent
32 stability
33 thermal stability
34 units
35 schema:name Polymers with Regular Alternation of 1,7-Bis[(dimethyl)silylmethylene]-m-carborane and Diorganosiloxane Units
36 schema:pagination 249-251
37 schema:productId N57c4c293c1314cd39996e02800886e0c
38 Nf03a07e502f34e07af53b496355b8aa7
39 schema:sameAs https://app.dimensions.ai/details/publication/pub.1122512993
40 https://doi.org/10.1134/s001250081910001x
41 schema:sdDatePublished 2022-11-24T21:03
42 schema:sdLicense https://scigraph.springernature.com/explorer/license/
43 schema:sdPublisher N73b475c2db394d1fb96837e8dadb2650
44 schema:url https://doi.org/10.1134/s001250081910001x
45 sgo:license sg:explorer/license/
46 sgo:sdDataset articles
47 rdf:type schema:ScholarlyArticle
48 N20c4cccff82f46b78a1b626e714f3c1e rdf:first sg:person.016434044347.74
49 rdf:rest rdf:nil
50 N57c4c293c1314cd39996e02800886e0c schema:name doi
51 schema:value 10.1134/s001250081910001x
52 rdf:type schema:PropertyValue
53 N5ee16ac6498541ac9294c824b323341e rdf:first sg:person.014243522747.51
54 rdf:rest N95fbc76aed0a40aa99172043d47ec3c9
55 N73b475c2db394d1fb96837e8dadb2650 schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 N95fbc76aed0a40aa99172043d47ec3c9 rdf:first sg:person.016446506525.11
58 rdf:rest N20c4cccff82f46b78a1b626e714f3c1e
59 Na1c1db6ca74d4d2daa53868763b01c17 schema:issueNumber 2
60 rdf:type schema:PublicationIssue
61 Nd1d76d3e9cf94bbaaf8cf52a92584107 schema:volumeNumber 488
62 rdf:type schema:PublicationVolume
63 Nf03a07e502f34e07af53b496355b8aa7 schema:name dimensions_id
64 schema:value pub.1122512993
65 rdf:type schema:PropertyValue
66 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
67 schema:name Chemical Sciences
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
70 schema:name Macromolecular and Materials Chemistry
71 rdf:type schema:DefinedTerm
72 sg:journal.1082681 schema:issn 0012-5008
73 1608-3113
74 schema:name Doklady Chemistry
75 schema:publisher Pleiades Publishing
76 rdf:type schema:Periodical
77 sg:person.014243522747.51 schema:affiliation grid-institutes:grid.431939.5
78 schema:familyName Izmaylov
79 schema:givenName B. A.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014243522747.51
81 rdf:type schema:Person
82 sg:person.016434044347.74 schema:affiliation grid-institutes:grid.431939.5
83 schema:familyName Markova
84 schema:givenName G. D.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016434044347.74
86 rdf:type schema:Person
87 sg:person.016446506525.11 schema:affiliation grid-institutes:grid.431939.5
88 schema:familyName Vasnev
89 schema:givenName V. A.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016446506525.11
91 rdf:type schema:Person
92 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
93 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
94 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...