A New Approach to the Synthesis of Carboranylmethylsiloxanes View Full Text


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Article Info

DATE

2019-05

AUTHORS

B. A. Izmailov, V. A. Vasnev, G. D. Markova

ABSTRACT

An efficient method for the synthesis of o(m)-carboranylmethylsiloxanes by the Grignard reaction from 1,2(7)-bis(bromomagnesiummethyl)-o(m)-carboranes and 1-chloro-1,1,3,3,3-pentamethyldisiloxane has been developed. As a result, 1-(1,1,3,3,3-pentamethyldisiloxanylmethyl)-2(7)-methyl-o(m)-carboranes, 1,2(7)-bis(1,1,3.3,3-pentamethyldisiloxanylmethyl)-o(m)-carboranes, exocyclic 1,2-(o-carborano)-4,6-bis(dimethylsilyl)-5-oxacycloheptane, 1,7-bis(chloro-1,1,3,3-tetramethyldisiloxanylmethyl)-m-carborane, and oligomer containing two 1,7-bis(dimethylsilylmethyl)-m-carborane units have been obtained.

PAGES

119-121

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s001250081905001x

DOI

http://dx.doi.org/10.1134/s001250081905001x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1117138642


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