Addition Polymerization of 5-Ethylidene-2-Norbornene in the Presence of Pd N-Heterocyclic Carbene Complexes View Full Text


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Article Info

DATE

2018-04

AUTHORS

G. O. Karpov, E. V. Bermesheva, A. V. Zudina, A. F. Asachenko, L. I. Minaeva, M. A. Topchiy, P. S. Gribanov, M. S. Nechaev, M. V. Bermeshev

ABSTRACT

New high-performance catalytic systems based on Pd N-heterocyclic carbene complexes for the selective addition polymerization of 5-ethylidene-2-norbornene (ENB) were proposed. With these catalysts, polymerization can be conducted at unprecedentedly high monomer/catalyst ratio (up to 5 × 105/1) and gives high-molecular-weight soluble polymers with good film-forming properties. Varying the polymerization conditions (reaction temperature, monomer and catalyst concentrations, monomer/Pd ratio) makes it possible to prepare soluble ENB-based addition polymers with specified molecular weights in reasonable yields. More... »

PAGES

49-52

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012500818040031

DOI

http://dx.doi.org/10.1134/s0012500818040031

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1104131065


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