New binuclear copper(II) complexes [Cu2(L)4(μ-CO3)][B12H12] (L = bipy, phen): Synthesis, structure, and magnetic properties View Full Text


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Article Info

DATE

2017-06

AUTHORS

I. K. Kochneva, I. N. Polyakova, V. V. Avdeeva, N. N. Efimov, E. A. Ugolkova, V. V. Minin, E. A. Malinina, N. T. Kuznetsov

ABSTRACT

The processes taking place in the CuI/L/solv system (L = bipy, phen) in the presence of the [B12H12]2– anion, which exhibited the lowest reducing ability among the [BnHn]2– cluster anions (n = 6, 10, 12), were studied. The binuclear complexes [Cu2(L)4(μ-CO3)][B12H12] · n(solv) were found to be formed upon the redox reaction of (C6H5)4P[Cu[B12H12]] with a twofold excess of L or the reaction of copper(II) complex [(Cu2(phen)4(CO3)]Cl2 with [(C4H9)3NH]2[B12H12]. The Cu(II) complexes were characterized by X-ray diffraction; their EPR-spectra were studied at 295 K and the magnetic measurements were performed in the 300–2 K range. In the [Cu2(phen)4(μ-CO3)][B12H12] · DMF dimer with the anti-anti coordination of the (μ-CO3)-group, strong antiferromagnetic interactions occur between the Cu(II) atoms (Cu⋯Cu = 5.107 Å). More... »

PAGES

137-140

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012500817060015

DOI

http://dx.doi.org/10.1134/s0012500817060015

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090598297


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