Ontology type: schema:ScholarlyArticle
2017-06
AUTHORSI. K. Kochneva, I. N. Polyakova, V. V. Avdeeva, N. N. Efimov, E. A. Ugolkova, V. V. Minin, E. A. Malinina, N. T. Kuznetsov
ABSTRACTThe processes taking place in the CuI/L/solv system (L = bipy, phen) in the presence of the [B12H12]2– anion, which exhibited the lowest reducing ability among the [BnHn]2– cluster anions (n = 6, 10, 12), were studied. The binuclear complexes [Cu2(L)4(μ-CO3)][B12H12] · n(solv) were found to be formed upon the redox reaction of (C6H5)4P[Cu[B12H12]] with a twofold excess of L or the reaction of copper(II) complex [(Cu2(phen)4(CO3)]Cl2 with [(C4H9)3NH]2[B12H12]. The Cu(II) complexes were characterized by X-ray diffraction; their EPR-spectra were studied at 295 K and the magnetic measurements were performed in the 300–2 K range. In the [Cu2(phen)4(μ-CO3)][B12H12] · DMF dimer with the anti-anti coordination of the (μ-CO3)-group, strong antiferromagnetic interactions occur between the Cu(II) atoms (Cu⋯Cu = 5.107 Å). More... »
PAGES137-140
http://scigraph.springernature.com/pub.10.1134/s0012500817060015
DOIhttp://dx.doi.org/10.1134/s0012500817060015
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1090598297
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Kochneva",
"givenName": "I. K.",
"id": "sg:person.011507121237.10",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011507121237.10"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Polyakova",
"givenName": "I. N.",
"id": "sg:person.01021356734.64",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01021356734.64"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Avdeeva",
"givenName": "V. V.",
"id": "sg:person.0753243534.69",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0753243534.69"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Efimov",
"givenName": "N. N.",
"id": "sg:person.01024204401.44",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01024204401.44"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Ugolkova",
"givenName": "E. A.",
"id": "sg:person.015265162315.78",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Minin",
"givenName": "V. V.",
"id": "sg:person.011207441575.56",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Malinina",
"givenName": "E. A.",
"id": "sg:person.015304226647.16",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015304226647.16"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Kuznetsov",
"givenName": "N. T.",
"id": "sg:person.011030545024.95",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011030545024.95"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1134/s0012500811090035",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017149125",
"https://doi.org/10.1134/s0012500811090035"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-06",
"datePublishedReg": "2017-06-01",
"description": "The processes taking place in the CuI/L/solv system (L = bipy, phen) in the presence of the [B12H12]2\u2013 anion, which exhibited the lowest reducing ability among the [BnHn]2\u2013 cluster anions (n = 6, 10, 12), were studied. The binuclear complexes [Cu2(L)4(\u03bc-CO3)][B12H12] \u00b7 n(solv) were found to be formed upon the redox reaction of (C6H5)4P[Cu[B12H12]] with a twofold excess of L or the reaction of copper(II) complex [(Cu2(phen)4(CO3)]Cl2 with [(C4H9)3NH]2[B12H12]. The Cu(II) complexes were characterized by X-ray diffraction; their EPR-spectra were studied at 295 K and the magnetic measurements were performed in the 300\u20132 K range. In the [Cu2(phen)4(\u03bc-CO3)][B12H12] \u00b7 DMF dimer with the anti-anti coordination of the (\u03bc-CO3)-group, strong antiferromagnetic interactions occur between the Cu(II) atoms (Cu\u22efCu = 5.107 \u00c5).",
"genre": "article",
"id": "sg:pub.10.1134/s0012500817060015",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1082681",
"issn": [
"0012-5008",
"1608-3113"
],
"name": "Doklady Chemistry",
"publisher": "Pleiades Publishing",
"type": "Periodical"
},
{
"issueNumber": "2",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "474"
}
],
"keywords": [
"binuclear complexes",
"cluster anions",
"redox reactions",
"twofold excess",
"anions",
"complexes",
"reaction",
"excess",
"presence",
"process",
"ability",
"system",
"place"
],
"name": "New binuclear copper(II) complexes [Cu2(L)4(\u03bc-CO3)][B12H12] (L = bipy, phen): Synthesis, structure, and magnetic properties",
"pagination": "137-140",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1090598297"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s0012500817060015"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s0012500817060015",
"https://app.dimensions.ai/details/publication/pub.1090598297"
],
"sdDataset": "articles",
"sdDatePublished": "2022-09-02T16:00",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_732.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1134/s0012500817060015"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0012500817060015'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0012500817060015'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0012500817060015'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0012500817060015'
This table displays all metadata directly associated to this object as RDF triples.
123 TRIPLES
21 PREDICATES
39 URIs
30 LITERALS
6 BLANK NODES