Ontology type: schema:ScholarlyArticle
2017-06
AUTHORSI. K. Kochneva, I. N. Polyakova, V. V. Avdeeva, N. N. Efimov, E. A. Ugolkova, V. V. Minin, E. A. Malinina, N. T. Kuznetsov
ABSTRACTThe processes taking place in the CuI/L/solv system (L = bipy, phen) in the presence of the [B12H12]2– anion, which exhibited the lowest reducing ability among the [BnHn]2– cluster anions (n = 6, 10, 12), were studied. The binuclear complexes [Cu2(L)4(μ-CO3)][B12H12] · n(solv) were found to be formed upon the redox reaction of (C6H5)4P[Cu[B12H12]] with a twofold excess of L or the reaction of copper(II) complex [(Cu2(phen)4(CO3)]Cl2 with [(C4H9)3NH]2[B12H12]. The Cu(II) complexes were characterized by X-ray diffraction; their EPR-spectra were studied at 295 K and the magnetic measurements were performed in the 300–2 K range. In the [Cu2(phen)4(μ-CO3)][B12H12] · DMF dimer with the anti-anti coordination of the (μ-CO3)-group, strong antiferromagnetic interactions occur between the Cu(II) atoms (Cu⋯Cu = 5.107 Å). More... »
PAGES137-140
http://scigraph.springernature.com/pub.10.1134/s0012500817060015
DOIhttp://dx.doi.org/10.1134/s0012500817060015
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