Synthesis of 3-(2-hydroxyphenyl)-1,5-dialkyl-1H-1,2,4-triazoles and their Zn(II) complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-02

AUTHORS

I. E. Mikhailov, N. I. Vikrishchuk, L. D. Popov, A. D. Beldovskaya, G. A. Dushenko, Yu. V. Revinskii, V. I. Minkin

ABSTRACT

It has been demonstrated by 13C NMR and quantum-chemical calculations that alkylation of 5-(2-hydroxyphenyl)-3-methyl(vinylphenyl)-1H-1,2,4-triazoles with dialkyl sulfates in aqueous DMSO in the presence of alkali occurs exclusively in the 2-position of the triazole ring to give 3-(2-hydroxyphenyl)-1,5-dialkyl(alkylvinylphenyl)-1H-1,2,4-triazoles. Emission spectra of these compounds show two weak bands (λmaxfl = 317–346 and 430–447 nm, φ = 0.002–0.007), whereas their zinc complexes emit in the violet range of the visible spectrum (λmaxfl= 373–377 nm, φ = 0.20–0.25). More... »

PAGES

30-35

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012500817020045

DOI

http://dx.doi.org/10.1134/s0012500817020045

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084999892


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