Electroreduction of bromate anion in acidic solutions at the inactive rotating disc electrode under steady-state conditions: Numerical modeling of the ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-05

AUTHORS

M. A. Vorotyntsev, A. E. Antipov, Yu. V. Tolmachev, E. M. Antipov, S. M. Aldoshin

ABSTRACT

The process of electroreduction of bromate anion BrO3 in acidic solutions at catalytically inactive electrodes when bromate anions are in excess compared to protons has been studied by numerical integration of transport equations. Under these conditions, the maximum possible current is limited by the limiting diffusion current of protons (rather than bromate), since both ions are consumed in the comproportionation reaction. It has been demonstrated that the curve of maximum current versus diffusion layer thickness has an anomalous segment where the current increases with an increase of the latter. More... »

PAGES

141-147

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012500816050025

DOI

http://dx.doi.org/10.1134/s0012500816050025

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020461426


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "CNRS-Universit\u00e9 de Bourgogne, Dijon, France", 
          "id": "http://www.grid.ac/institutes/grid.5613.1", 
          "name": [
            "Moscow State University, 119991, Moscow, Russia", 
            "Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia", 
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia", 
            "CNRS-Universit\u00e9 de Bourgogne, Dijon, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vorotyntsev", 
        "givenName": "M. A.", 
        "id": "sg:person.01110714773.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01110714773.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.39572.3a", 
          "name": [
            "Moscow State University, 119991, Moscow, Russia", 
            "Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antipov", 
        "givenName": "A. E.", 
        "id": "sg:person.014025050645.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014025050645.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ftorion, Inc., 02120, Boston, MA, USA", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia", 
            "Ftorion, Inc., 02120, Boston, MA, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tolmachev", 
        "givenName": "Yu. V.", 
        "id": "sg:person.012234367767.30", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012234367767.30"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.39572.3a", 
          "name": [
            "Moscow State University, 119991, Moscow, Russia", 
            "Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antipov", 
        "givenName": "E. M.", 
        "id": "sg:person.01005226707.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01005226707.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Moscow State University, 119991, Moscow, Russia", 
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aldoshin", 
        "givenName": "S. M.", 
        "id": "sg:person.014353217357.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014353217357.41"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/b:ruel.0000023933.51203.b1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053690187", 
          "https://doi.org/10.1023/b:ruel.0000023933.51203.b1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10008-015-2805-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045704466", 
          "https://doi.org/10.1007/s10008-015-2805-z"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-05", 
    "datePublishedReg": "2016-05-01", 
    "description": "The process of electroreduction of bromate anion BrO3 in acidic solutions at catalytically inactive electrodes when bromate anions are in excess compared to protons has been studied by numerical integration of transport equations. Under these conditions, the maximum possible current is limited by the limiting diffusion current of protons (rather than bromate), since both ions are consumed in the comproportionation reaction. It has been demonstrated that the curve of maximum current versus diffusion layer thickness has an anomalous segment where the current increases with an increase of the latter.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0012500816050025", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082681", 
        "issn": [
          "0012-5008", 
          "1608-3113"
        ], 
        "name": "Doklady Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "468"
      }
    ], 
    "keywords": [
      "bromate anion", 
      "acidic solution", 
      "process of electroreduction", 
      "comproportionation reaction", 
      "disk electrode", 
      "diffusion layer thickness", 
      "anions", 
      "electroreduction", 
      "inactive electrodes", 
      "electrode", 
      "protons", 
      "BrO3", 
      "ions", 
      "steady-state conditions", 
      "solution", 
      "reaction", 
      "current increases", 
      "excess", 
      "layer thickness", 
      "diffusion", 
      "process", 
      "conditions", 
      "maximum possible current", 
      "thickness", 
      "increase", 
      "current", 
      "curves", 
      "numerical modeling", 
      "transport equation", 
      "modeling", 
      "segments", 
      "possible current", 
      "numerical integration", 
      "equations", 
      "integration", 
      "anomalous segments"
    ], 
    "name": "Electroreduction of bromate anion in acidic solutions at the inactive rotating disc electrode under steady-state conditions: Numerical modeling of the process with bromate anions being in excess compared to protons", 
    "pagination": "141-147", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1020461426"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0012500816050025"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0012500816050025", 
      "https://app.dimensions.ai/details/publication/pub.1020461426"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:33", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_689.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0012500816050025"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0012500816050025'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0012500816050025'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0012500816050025'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0012500816050025'


 

This table displays all metadata directly associated to this object as RDF triples.

140 TRIPLES      21 PREDICATES      62 URIs      53 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0012500816050025 schema:about anzsrc-for:03
2 schema:author N4f1a6aae154545a69f8970372c4a2a6a
3 schema:citation sg:pub.10.1007/s10008-015-2805-z
4 sg:pub.10.1023/b:ruel.0000023933.51203.b1
5 schema:datePublished 2016-05
6 schema:datePublishedReg 2016-05-01
7 schema:description The process of electroreduction of bromate anion BrO3 in acidic solutions at catalytically inactive electrodes when bromate anions are in excess compared to protons has been studied by numerical integration of transport equations. Under these conditions, the maximum possible current is limited by the limiting diffusion current of protons (rather than bromate), since both ions are consumed in the comproportionation reaction. It has been demonstrated that the curve of maximum current versus diffusion layer thickness has an anomalous segment where the current increases with an increase of the latter.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf N26a34a13b31b48478f030c0a2eedbff2
11 Ndd7e6b1f68d04f2c87e8fc5499c3a55b
12 sg:journal.1082681
13 schema:keywords BrO3
14 acidic solution
15 anions
16 anomalous segments
17 bromate anion
18 comproportionation reaction
19 conditions
20 current
21 current increases
22 curves
23 diffusion
24 diffusion layer thickness
25 disk electrode
26 electrode
27 electroreduction
28 equations
29 excess
30 inactive electrodes
31 increase
32 integration
33 ions
34 layer thickness
35 maximum possible current
36 modeling
37 numerical integration
38 numerical modeling
39 possible current
40 process
41 process of electroreduction
42 protons
43 reaction
44 segments
45 solution
46 steady-state conditions
47 thickness
48 transport equation
49 schema:name Electroreduction of bromate anion in acidic solutions at the inactive rotating disc electrode under steady-state conditions: Numerical modeling of the process with bromate anions being in excess compared to protons
50 schema:pagination 141-147
51 schema:productId N24a728a525ec42e985baf4249b6924f3
52 Nf0730f3f288a4909b2d4bbc7ea06bcb5
53 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020461426
54 https://doi.org/10.1134/s0012500816050025
55 schema:sdDatePublished 2022-12-01T06:33
56 schema:sdLicense https://scigraph.springernature.com/explorer/license/
57 schema:sdPublisher N7dbee2935a454918a495574d607331ed
58 schema:url https://doi.org/10.1134/s0012500816050025
59 sgo:license sg:explorer/license/
60 sgo:sdDataset articles
61 rdf:type schema:ScholarlyArticle
62 N24a728a525ec42e985baf4249b6924f3 schema:name dimensions_id
63 schema:value pub.1020461426
64 rdf:type schema:PropertyValue
65 N26a34a13b31b48478f030c0a2eedbff2 schema:volumeNumber 468
66 rdf:type schema:PublicationVolume
67 N4f1a6aae154545a69f8970372c4a2a6a rdf:first sg:person.01110714773.18
68 rdf:rest Na096c09db24e4b059f298546506cc9ff
69 N58482f3678cd4abbbc0e635253f76992 rdf:first sg:person.014353217357.41
70 rdf:rest rdf:nil
71 N7dbee2935a454918a495574d607331ed schema:name Springer Nature - SN SciGraph project
72 rdf:type schema:Organization
73 N8ce3fbecd62c4effbd85627acde3c360 rdf:first sg:person.01005226707.06
74 rdf:rest N58482f3678cd4abbbc0e635253f76992
75 Na096c09db24e4b059f298546506cc9ff rdf:first sg:person.014025050645.81
76 rdf:rest Nb3490a1437d64598a08100ad6228bbb8
77 Nb3490a1437d64598a08100ad6228bbb8 rdf:first sg:person.012234367767.30
78 rdf:rest N8ce3fbecd62c4effbd85627acde3c360
79 Ndd7e6b1f68d04f2c87e8fc5499c3a55b schema:issueNumber 1
80 rdf:type schema:PublicationIssue
81 Nf0730f3f288a4909b2d4bbc7ea06bcb5 schema:name doi
82 schema:value 10.1134/s0012500816050025
83 rdf:type schema:PropertyValue
84 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
85 schema:name Chemical Sciences
86 rdf:type schema:DefinedTerm
87 sg:journal.1082681 schema:issn 0012-5008
88 1608-3113
89 schema:name Doklady Chemistry
90 schema:publisher Pleiades Publishing
91 rdf:type schema:Periodical
92 sg:person.01005226707.06 schema:affiliation grid-institutes:grid.39572.3a
93 schema:familyName Antipov
94 schema:givenName E. M.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01005226707.06
96 rdf:type schema:Person
97 sg:person.01110714773.18 schema:affiliation grid-institutes:grid.5613.1
98 schema:familyName Vorotyntsev
99 schema:givenName M. A.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01110714773.18
101 rdf:type schema:Person
102 sg:person.012234367767.30 schema:affiliation grid-institutes:None
103 schema:familyName Tolmachev
104 schema:givenName Yu. V.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012234367767.30
106 rdf:type schema:Person
107 sg:person.014025050645.81 schema:affiliation grid-institutes:grid.39572.3a
108 schema:familyName Antipov
109 schema:givenName A. E.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014025050645.81
111 rdf:type schema:Person
112 sg:person.014353217357.41 schema:affiliation grid-institutes:grid.418949.9
113 schema:familyName Aldoshin
114 schema:givenName S. M.
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014353217357.41
116 rdf:type schema:Person
117 sg:pub.10.1007/s10008-015-2805-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1045704466
118 https://doi.org/10.1007/s10008-015-2805-z
119 rdf:type schema:CreativeWork
120 sg:pub.10.1023/b:ruel.0000023933.51203.b1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053690187
121 https://doi.org/10.1023/b:ruel.0000023933.51203.b1
122 rdf:type schema:CreativeWork
123 grid-institutes:None schema:alternateName Ftorion, Inc., 02120, Boston, MA, USA
124 schema:name Ftorion, Inc., 02120, Boston, MA, USA
125 Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia
126 rdf:type schema:Organization
127 grid-institutes:grid.39572.3a schema:alternateName Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia
128 schema:name Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia
129 Moscow State University, 119991, Moscow, Russia
130 rdf:type schema:Organization
131 grid-institutes:grid.418949.9 schema:alternateName Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia
132 schema:name Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia
133 Moscow State University, 119991, Moscow, Russia
134 rdf:type schema:Organization
135 grid-institutes:grid.5613.1 schema:alternateName CNRS-Université de Bourgogne, Dijon, France
136 schema:name CNRS-Université de Bourgogne, Dijon, France
137 Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia
138 Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047, Moscow, Russia
139 Moscow State University, 119991, Moscow, Russia
140 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...