Ontology type: schema:ScholarlyArticle
2018-01
AUTHORSA. I. Kazakov, T. K. Goncharov, D. B. Lempert, N. A. Plishkin, K. V. Bozhenko, A. N. Utenyshev, D. V. Dashko, A. I. Stepanov, S. M. Aldoshin
ABSTRACTThe standard enthalpies of combustion and formation of 7H-tris([1,2,5]oxadiazolo) [3,4-b:3′,4′-d:3″,4″-f]azepine, its bimolecular crystal with the γ-polymorph of CL-20, and the γ-polymorph of CL-20 have been experimentally determined. The standard enthalpies of formation of the bimolecular crystal and an equimolecular mechanical mixture of γ-CL-20 with azepine differ by less than 12.8 kJ/mol. This small difference is validated by quantum chemical calculations. It has been experimentally found that the presence of azepine in the bimolecular crystal inhibits the thermal decomposition of γ-CL-20 and increases the thermal stability of γ-CL-20 in the bimolecular crystal as compared to original γ-CL-20. More... »
PAGES89-96
http://scigraph.springernature.com/pub.10.1134/s0010508218010136
DOIhttp://dx.doi.org/10.1134/s0010508218010136
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