Standard Enthalpy of Formation of the Bimolecular Crystal of CL-20 with Tris-Oxadiazolo-Azepine and Its Thermal Stability View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-01

AUTHORS

A. I. Kazakov, T. K. Goncharov, D. B. Lempert, N. A. Plishkin, K. V. Bozhenko, A. N. Utenyshev, D. V. Dashko, A. I. Stepanov, S. M. Aldoshin

ABSTRACT

The standard enthalpies of combustion and formation of 7H-tris([1,2,5]oxadiazolo) [3,4-b:3′,4′-d:3″,4″-f]azepine, its bimolecular crystal with the γ-polymorph of CL-20, and the γ-polymorph of CL-20 have been experimentally determined. The standard enthalpies of formation of the bimolecular crystal and an equimolecular mechanical mixture of γ-CL-20 with azepine differ by less than 12.8 kJ/mol. This small difference is validated by quantum chemical calculations. It has been experimentally found that the presence of azepine in the bimolecular crystal inhibits the thermal decomposition of γ-CL-20 and increases the thermal stability of γ-CL-20 in the bimolecular crystal as compared to original γ-CL-20. More... »

PAGES

89-96

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0010508218010136

DOI

http://dx.doi.org/10.1134/s0010508218010136

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101386929


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