Promoting effect of halogen- and phosphorus-containing flame retardants on the autoignition of a methane–oxygen mixture View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-07

AUTHORS

A. V. Drakon, A. V. Eremin, O. P. Korobeinichev, V. M. Shvartsberg, A. G. Shmakov

ABSTRACT

This paper presents a numerical and experimental study of the effect of flame-retardant additives on the autoignition of methane behind shock waves. It is shown that at a temperature of 1300–1900 K, the compounds CCl4, CF3H, and (CH3O)3PO not only do not suppress ignition but significantly reduce the induction time of methane–oxygen mixtures. A kinetic mechanism is proposed which relates the promoting effect to the reactivity of the pyrolysis products of the additives. More... »

PAGES

375-385

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0010508216040018

DOI

http://dx.doi.org/10.1134/s0010508216040018

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042520365


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