Optical activity of the cellulose acetate-mesophase-generating solvent system in the formation of a lyotropic liquid-crystalline phase View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-04

AUTHORS

A. B. Shipovskaya, O. F. Kazmicheva, G. N. Timofeeva

ABSTRACT

It was demonstrated experimentally that the vapors of a mesophase-generating solvent, i.e., a solvent forming a lyotropic liquid-crystalline phase with a polymer, changed the spatial structure and optical density of natural polysaccharides (cellulose acetates). In this process, the value of specific optical rotation of the polymer modified by the vapors varied in a wide range up to sign inversion. The action of vapors on the polymer follows a peculiar dose-effect pattern, with lower doses producing a stronger effect. Application of this approach to the study into specific structural characteristics of biopolymers, such as DNA, is proposed. More... »

PAGES

215-225

References to SciGraph publications

Journal

TITLE

Biophysics

ISSUE

2

VOLUME

51

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0006350906020096

DOI

http://dx.doi.org/10.1134/s0006350906020096

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007412916


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