Sulfur Isotopes in the Upper Part of the Black Sea Anoxic Zone View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-11

AUTHORS

A. V. Dubinin, E. O. Dubinina, T. P. Demidova, V. K. Chasovnikov

ABSTRACT

New data are reported on the sulfur isotope composition and concentration of sulfide and sulfate in the upper part of the Black Sea anoxic zone as a function of the potential water density. The observations were performed at a station with the coordinates 44.489° N and 37.869° E three times a week every two days. A local negative deficiency in sulfate concentration up to 1.7% related to the sulfate reduction processes was recorded. This anomaly in sulfate concentration was short-lived and did not affect the sulfur isotope composition. In the upper part of the anaerobic zone, the δ34S(SO4) value varied from 21.2 to 21.5‰, which could have occurred from mixing of water masses from the oxic zone (21.1‰) and the Bottom Convective Layer (23.0 ± 0.2‰). The sulfur isotope composition of sulfide ranged from −40.8% at a depth of 250 m to −39.4‰ at the upper boundary of the anoxic zone with a H2S content of only 2.7 μM. Two models (mass balance and fractionation of sulfur isotopes using the Rayleigh equation) are considered to explain the differences in δ34S(H2S) values observed. More... »

PAGES

797-805

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0001437017060030

DOI

http://dx.doi.org/10.1134/s0001437017060030

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101408844


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