Polarized Fluorescence of Jet-Cooled indole and Carbazole and Their Complexes with Water View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-11

AUTHORS

N. A. Borisevich, S. L. Dziarzhytski, V. A. Povedailo, D. L. Yakovlev

ABSTRACT

The spectra of the fluorescence excitation within the rotational contours of the bands of the pure electronic long-wavelength S0-S1 transitions of jet-cooled indole and carbazole molecules and their complexes with water are measured. For the carbazole-water complex, a contour with three maxima is registered, which is possibly related to the occurrence of two isomers, differing in a slight displacement of hydrogen between the nitrogen atom of the imine group of carbazole and the oxygen atom of the water molecule. The degrees of polarization of integral fluorescence upon excitation within the rotational contours of the S0-S1 electronic transition bands of the above molecules and their complexes with water are determined for the first time. The coincidence of the calculated (7.7%) and measured (7.3%) values of the degree of polarization upon excitation in the rotational Q branch of the bL1-A electronic transition of indole confirms the accepted intramolecular orientation of the transition dipole moment at an angle of 38.3° with respect to the principal axis of inertia A. Upon excitation of indole, its complex with water, and carbazole into the P and R branches, the measured and calculated degrees of polarization are also close to each other and amount to 2–3%. This confirms the occurrence of contributions to the fluorescence polarization due to the rotations of the indole molecules around the principal axes of inertia A and C. More... »

PAGES

819-823

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1771413

DOI

http://dx.doi.org/10.1134/1.1771413

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051207341


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