Crystal and molecular structures of a samarium complex with the 3,5-Di-tert-butyl-1,2-quinone-1-(2-hydroxy-3,5-Di-tert-butylphenyl)imine ligand View Full Text


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Article Info

DATE

2000-05

AUTHORS

N. G. Furmanova, S. N. Lyubchenko, V. A. Kogan, L. P. Olekhnovich

ABSTRACT

X-ray structure analysis of Sm(C28H40NO2)3 is performed. The crystals are monoclinic, a = 13.490(2) Å, b = 27.955(5) Å, c = 23.000(6) Å, β = 105.30(2)°, Z = 4, space group P21/c, and R = 0.0332 for 9670 reflections. The coordination number of the Sm atom is nine (tricapped trigonal prism with the O atoms in the base and the N atoms at the caps). The approximate symmetry of the complex is D3. The mean C-O and C-N bond lengths (1.266 and 1.342 Å, respectively) correspond to the monoanion redox form of the ligands. In distinction to the earlier studied complexes ML2 with the same ligands, the six-membered rings in the ligands of this complex are essentially noncoplanar: the dihedral angles between them are 42.8°, 34.0°, and 41.1°. More... »

PAGES

439-443

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.171213

DOI

http://dx.doi.org/10.1134/1.171213

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050037446


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