Twin orthorhombic structure of Haüyne from Sakrofano (Italy) View Full Text


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Article Info

DATE

2003-11

AUTHORS

N. B. Bolotina, R. K. Rastsvetaeva, A. N. Sapozhnikov, A. A. Kashaev

ABSTRACT

The structure of haüyne from Sakrofano (Italy) is solved using the superstructure reflections, which double the unit cell parameters in three directions. The cubic symmetry of the diffraction pattern of haüyne results from the twinning of the equidimensional orthorhombic components by the [111] threefold axis. The structure is refined in the orthorhombic space group Pba2 with the unit cell parameters a = b = 12.872(7) Å and c = 9.102(3) Å in the anisotropic approximation to R = 0.043 for 1737 reflections. Compared to high-potassium haüyne from Arissia (Italy), the mineral studied contains potassium in smaller amounts and the distribution of K, Na, and Ca atoms over four body diagonals of the cell is ordered, which apparently causes the lowering of symmetry from cubic to orthorhombic. More... »

PAGES

914-918

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1627431

DOI

http://dx.doi.org/10.1134/1.1627431

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016773265


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