Crystal structure of hydrazine 5-amino-1-benzyl-1,2,3-triazole-4-carboxylate hexafluorosilicate trihydrate View Full Text


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Article Info

DATE

2003-07

AUTHORS

M. S. Fonar', Yu. A. Simonov, J. Lipkowski, V. O. Gel'mbol'dt, É. V. Ganin, A. A. Yavolovskii

ABSTRACT

Hydrazine 5-amino-1-benzyl-1,2,3-triazole-4-carboxylate hexafluorosilicate trihydrate (I) is synthesized. The crystal structure of the compound synthesized is determined. Crystals I are monoclinic, a = 13.353(1) Å, b = 21.094(2) Å, c = 20.233(2) Å, β = 94.05(3)°, space group P21/c, and R = 0.0584 for 16 601 reflections with I > 2σ(I). In the asymmetric part of the unit cell, four organic cations protonated at the terminal hydrazine nitrogen atoms, two hexafluorosilicate anions, and six water molecules are linked into a three-dimensional framework through hydrogen bonds of the N-H⋯F, N-H⋯O, and O-H⋯F types. More... »

PAGES

630-637

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1595191

DOI

http://dx.doi.org/10.1134/1.1595191

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009730346


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