Specific stereochemical features of metallochelate complexes with tridentate N,N,N(N,N,O)-donating ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-05

AUTHORS

A. S. Antsyshkina, G. G. Sadikov, V. S. Sergienko, D. A. Garnovskii

ABSTRACT

Earlier X-ray diffraction studies of a series of 12 adducts (I–XII) between metallochelate complexes [M = Co(II), Ni(II), and Cu(II)] with tridentate N,N,N(N,N,O)-donating Schiff bases (L) and monodentate or bidentate ligands (L′) revealed a similarity in the stereochemistry of these compounds. The coordination polyhedron of metal atoms in compounds I–XII is a tetragonal pyramid (bipyramid) with two vertices occupied competitively. The L ligand occupies three coordination sites in the base of the pyramid. The L′ ligand approaches the metal atom, as a rule, in a direction perpendicular to the basal plane. The fourth site in the base of the pyramid and the apical vertex are occupied competitively. Different patterns of occupation of these positions are observed: they include the donor atoms of both the L and L′ ligands. More... »

PAGES

422-425

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1578126

DOI

http://dx.doi.org/10.1134/1.1578126

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048494546


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antsyshkina", 
        "givenName": "A. S.", 
        "id": "sg:person.015007226477.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015007226477.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sadikov", 
        "givenName": "G. G.", 
        "id": "sg:person.016005276117.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016005276117.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194, 119991, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sergienko", 
        "givenName": "V. S.", 
        "id": "sg:person.0656275315.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194, 119991, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Garnovskii", 
        "givenName": "D. A.", 
        "id": "sg:person.016673540421.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016673540421.37"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0020-1693(99)00304-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015124128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0277-5387(98)00372-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018823553"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2003-05", 
    "datePublishedReg": "2003-05-01", 
    "description": "Earlier X-ray diffraction studies of a series of 12 adducts (I\u2013XII) between metallochelate complexes [M = Co(II), Ni(II), and Cu(II)] with tridentate N,N,N(N,N,O)-donating Schiff bases (L) and monodentate or bidentate ligands (L\u2032) revealed a similarity in the stereochemistry of these compounds. The coordination polyhedron of metal atoms in compounds I\u2013XII is a tetragonal pyramid (bipyramid) with two vertices occupied competitively. The L ligand occupies three coordination sites in the base of the pyramid. The L\u2032 ligand approaches the metal atom, as a rule, in a direction perpendicular to the basal plane. The fourth site in the base of the pyramid and the apical vertex are occupied competitively. Different patterns of occupation of these positions are observed: they include the donor atoms of both the L and L\u2032 ligands.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/1.1578126", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1295066", 
        "issn": [
          "0023-4761", 
          "0038-5638"
        ], 
        "name": "Crystallography Reports", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "name": "Specific stereochemical features of metallochelate complexes with tridentate N,N,N(N,N,O)-donating ligands", 
    "pagination": "422-425", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e704fd7be08e1f164d76d77489bea2585d1d850edd23a70197300ef4170b7782"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/1.1578126"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1048494546"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/1.1578126", 
      "https://app.dimensions.ai/details/publication/pub.1048494546"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:13", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000501.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/1.1578126"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/1.1578126'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/1.1578126'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/1.1578126'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/1.1578126'


 

This table displays all metadata directly associated to this object as RDF triples.

91 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/1.1578126 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N9818275fea854d608e795eafff49c048
4 schema:citation https://doi.org/10.1016/s0020-1693(99)00304-7
5 https://doi.org/10.1016/s0277-5387(98)00372-6
6 schema:datePublished 2003-05
7 schema:datePublishedReg 2003-05-01
8 schema:description Earlier X-ray diffraction studies of a series of 12 adducts (I–XII) between metallochelate complexes [M = Co(II), Ni(II), and Cu(II)] with tridentate N,N,N(N,N,O)-donating Schiff bases (L) and monodentate or bidentate ligands (L′) revealed a similarity in the stereochemistry of these compounds. The coordination polyhedron of metal atoms in compounds I–XII is a tetragonal pyramid (bipyramid) with two vertices occupied competitively. The L ligand occupies three coordination sites in the base of the pyramid. The L′ ligand approaches the metal atom, as a rule, in a direction perpendicular to the basal plane. The fourth site in the base of the pyramid and the apical vertex are occupied competitively. Different patterns of occupation of these positions are observed: they include the donor atoms of both the L and L′ ligands.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N2492724cc3484b5584a1c3866e3d0450
13 Nef8aef5e50cd48ac9187dfd4ede130e2
14 sg:journal.1295066
15 schema:name Specific stereochemical features of metallochelate complexes with tridentate N,N,N(N,N,O)-donating ligands
16 schema:pagination 422-425
17 schema:productId N67a4d7fef7a94539a93fae9f084180ca
18 N7334b74aefc14d53919a60c80fb09a74
19 Ndaa3dd5fe4e44e148db0cfbdadf20961
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048494546
21 https://doi.org/10.1134/1.1578126
22 schema:sdDatePublished 2019-04-11T00:13
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher Ne0f61bfe69214a4ea97cc480e43a32fc
25 schema:url http://link.springer.com/10.1134/1.1578126
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N2492724cc3484b5584a1c3866e3d0450 schema:volumeNumber 48
30 rdf:type schema:PublicationVolume
31 N67a4d7fef7a94539a93fae9f084180ca schema:name dimensions_id
32 schema:value pub.1048494546
33 rdf:type schema:PropertyValue
34 N7334b74aefc14d53919a60c80fb09a74 schema:name doi
35 schema:value 10.1134/1.1578126
36 rdf:type schema:PropertyValue
37 N769971f623614a558097c5f001bf90cc rdf:first sg:person.016673540421.37
38 rdf:rest rdf:nil
39 N9818275fea854d608e795eafff49c048 rdf:first sg:person.015007226477.01
40 rdf:rest Ne53b993d417243628d02a534ef77f60c
41 Ndaa3dd5fe4e44e148db0cfbdadf20961 schema:name readcube_id
42 schema:value e704fd7be08e1f164d76d77489bea2585d1d850edd23a70197300ef4170b7782
43 rdf:type schema:PropertyValue
44 Ne0f61bfe69214a4ea97cc480e43a32fc schema:name Springer Nature - SN SciGraph project
45 rdf:type schema:Organization
46 Ne53b993d417243628d02a534ef77f60c rdf:first sg:person.016005276117.42
47 rdf:rest Nffb9e73a654742bc821fd1552810e867
48 Nef8aef5e50cd48ac9187dfd4ede130e2 schema:issueNumber 3
49 rdf:type schema:PublicationIssue
50 Nffb9e73a654742bc821fd1552810e867 rdf:first sg:person.0656275315.49
51 rdf:rest N769971f623614a558097c5f001bf90cc
52 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
53 schema:name Chemical Sciences
54 rdf:type schema:DefinedTerm
55 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
56 schema:name Inorganic Chemistry
57 rdf:type schema:DefinedTerm
58 sg:journal.1295066 schema:issn 0023-4761
59 0038-5638
60 schema:name Crystallography Reports
61 rdf:type schema:Periodical
62 sg:person.015007226477.01 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
63 schema:familyName Antsyshkina
64 schema:givenName A. S.
65 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015007226477.01
66 rdf:type schema:Person
67 sg:person.016005276117.42 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
68 schema:familyName Sadikov
69 schema:givenName G. G.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016005276117.42
71 rdf:type schema:Person
72 sg:person.016673540421.37 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
73 schema:familyName Garnovskii
74 schema:givenName D. A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016673540421.37
76 rdf:type schema:Person
77 sg:person.0656275315.49 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
78 schema:familyName Sergienko
79 schema:givenName V. S.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49
81 rdf:type schema:Person
82 https://doi.org/10.1016/s0020-1693(99)00304-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015124128
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1016/s0277-5387(98)00372-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018823553
85 rdf:type schema:CreativeWork
86 https://www.grid.ac/institutes/grid.182798.d schema:alternateName Southern Federal University
87 schema:name Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194, 119991, Rostov-on-Don, Russia
88 rdf:type schema:Organization
89 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
90 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
91 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...