Local structure of bivalent copper centers in SrF2 crystals: An ENDOR spectroscopic study View Full Text


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Article Info

DATE

2001-06

AUTHORS

I. I. Fazlizhanov, V. A. Ulanov, M. M. Zaripov

ABSTRACT

Structural distortions of the SrF2 crystal lattice near the bivalent copper impurity Jahn-Teller center are investigated by the ENDOR method (v=9.3 GHz, T=4.2 K). The approximate directions and the magnitudes of displacements of a Cu2+ impurity ion and its surrounding F− ions are determined with respect to one of the anionic networks in the crystal matrix. The tensor components for the ligand hyperfine interaction (LHFI) with fluorine ions separated from the impurity by a distance R≤6.2 Å are obtained from the angular dependences of the location of the ENDOR resonance lines. It is found that the parameters of magnetic interactions between the impurity and these ligands contain the contributions determined by the covalence of bonds in the impurity complex and the polarization of electron shells of the ligands. More... »

PAGES

1052-1058

References to SciGraph publications

Journal

TITLE

Physics of the Solid State

ISSUE

6

VOLUME

43

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1378144

DOI

http://dx.doi.org/10.1134/1.1378144

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000176851


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