Ontology type: schema:ScholarlyArticle
2001-06
AUTHORSI. I. Fazlizhanov, V. A. Ulanov, M. M. Zaripov
ABSTRACTStructural distortions of the SrF2 crystal lattice near the bivalent copper impurity Jahn-Teller center are investigated by the ENDOR method (v=9.3 GHz, T=4.2 K). The approximate directions and the magnitudes of displacements of a Cu2+ impurity ion and its surrounding F− ions are determined with respect to one of the anionic networks in the crystal matrix. The tensor components for the ligand hyperfine interaction (LHFI) with fluorine ions separated from the impurity by a distance R≤6.2 Å are obtained from the angular dependences of the location of the ENDOR resonance lines. It is found that the parameters of magnetic interactions between the impurity and these ligands contain the contributions determined by the covalence of bonds in the impurity complex and the polarization of electron shells of the ligands. More... »
PAGES1052-1058
http://scigraph.springernature.com/pub.10.1134/1.1378144
DOIhttp://dx.doi.org/10.1134/1.1378144
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