Molecular and crystal structures of the products of crystallization of (N′-furfurylidene)isonicotinoylhydrazide from aqueous solutions of hydrochloric and acetic acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-05

AUTHORS

I. I. Chuev, L. A. Nikonova, E. G. Atovmyan, A. N. Utenyshev, S. M. Aldoshin

ABSTRACT

Crystals of (N′-furfurylidene)isonicotinoylhydrazide (I), which have been isolated from a water-methanol solution of hydrochloric acid (Ia) and an aqueous solution (∼50%) of acetic acid (Ib), are studied by X-ray diffraction. In Ia, the nitrogen atom of the pyridine ring is protonated. In the crystal, the intermolecular C=O⋯HN(Py) hydrogen bonds link the I · H+ cations into chains which are bound through centrosymmetric NH⋯W⋯Cl−⋯W′⋯H′N′ bridges. In molecule Ib, no protonation occurs; however, its pyridine N atom is blocked by the hydroxyl H atom of a solvate molecule of acetic acid. Crystals Ib have a layered structure. The crystallization water molecule is involved in the formation of three intermolecular hydrogen bonds, namely, those with the H atom of the amide group and the carbonyl O atoms of molecule I and an acetic acid molecule of the neighboring layer. More... »

PAGES

394-397

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1376467

DOI

http://dx.doi.org/10.1134/1.1376467

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032861650


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chuev", 
        "givenName": "I. I.", 
        "id": "sg:person.012555612421.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555612421.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nikonova", 
        "givenName": "L. A.", 
        "id": "sg:person.010420665017.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010420665017.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Atovmyan", 
        "givenName": "E. G.", 
        "id": "sg:person.07417605661.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07417605661.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Utenyshev", 
        "givenName": "A. N.", 
        "id": "sg:person.015236213545.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aldoshin", 
        "givenName": "S. M.", 
        "id": "sg:person.013232115673.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2001-05", 
    "datePublishedReg": "2001-05-01", 
    "description": "Crystals of (N\u2032-furfurylidene)isonicotinoylhydrazide (I), which have been isolated from a water-methanol solution of hydrochloric acid (Ia) and an aqueous solution (\u223c50%) of acetic acid (Ib), are studied by X-ray diffraction. In Ia, the nitrogen atom of the pyridine ring is protonated. In the crystal, the intermolecular C=O\u22efHN(Py) hydrogen bonds link the I \u00b7 H+ cations into chains which are bound through centrosymmetric NH\u22efW\u22efCl\u2212\u22efW\u2032\u22efH\u2032N\u2032 bridges. In molecule Ib, no protonation occurs; however, its pyridine N atom is blocked by the hydroxyl H atom of a solvate molecule of acetic acid. Crystals Ib have a layered structure. The crystallization water molecule is involved in the formation of three intermolecular hydrogen bonds, namely, those with the H atom of the amide group and the carbonyl O atoms of molecule I and an acetic acid molecule of the neighboring layer.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/1.1376467", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1295066", 
        "issn": [
          "1063-7745", 
          "1562-689X"
        ], 
        "name": "Crystallography Reports", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "keywords": [
      "hydrogen bonds", 
      "aqueous solution", 
      "crystallization water molecules", 
      "intermolecular hydrogen bonds", 
      "H atoms", 
      "acetic acid molecules", 
      "acetic acid", 
      "water-methanol solutions", 
      "X-ray diffraction", 
      "pyridine N atom", 
      "hydroxyl H atom", 
      "solvate molecules", 
      "water molecules", 
      "nitrogen atoms", 
      "acid molecules", 
      "carbonyl O atom", 
      "amide group", 
      "pyridine ring", 
      "crystal structure", 
      "N atoms", 
      "O atoms", 
      "molecule I", 
      "hydrochloric acid", 
      "atoms", 
      "molecules", 
      "bonds", 
      "neighboring layers", 
      "acid", 
      "ns", 
      "crystals", 
      "protonation", 
      "cations", 
      "centrosymmetric", 
      "solution", 
      "products of crystallization", 
      "diffraction", 
      "structure", 
      "crystallization", 
      "ring", 
      "chain", 
      "formation", 
      "products", 
      "bridge", 
      "layer", 
      "group", 
      "IB", 
      "IA"
    ], 
    "name": "Molecular and crystal structures of the products of crystallization of (N\u2032-furfurylidene)isonicotinoylhydrazide from aqueous solutions of hydrochloric and acetic acids", 
    "pagination": "394-397", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1032861650"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/1.1376467"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/1.1376467", 
      "https://app.dimensions.ai/details/publication/pub.1032861650"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_312.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/1.1376467"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/1.1376467'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/1.1376467'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/1.1376467'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/1.1376467'


 

This table displays all metadata directly associated to this object as RDF triples.

136 TRIPLES      20 PREDICATES      73 URIs      64 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/1.1376467 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0306
4 schema:author N29f0c38cdddc4cbe88b26739e6ec1191
5 schema:datePublished 2001-05
6 schema:datePublishedReg 2001-05-01
7 schema:description Crystals of (N′-furfurylidene)isonicotinoylhydrazide (I), which have been isolated from a water-methanol solution of hydrochloric acid (Ia) and an aqueous solution (∼50%) of acetic acid (Ib), are studied by X-ray diffraction. In Ia, the nitrogen atom of the pyridine ring is protonated. In the crystal, the intermolecular C=O⋯HN(Py) hydrogen bonds link the I · H+ cations into chains which are bound through centrosymmetric NH⋯W⋯Cl−⋯W′⋯H′N′ bridges. In molecule Ib, no protonation occurs; however, its pyridine N atom is blocked by the hydroxyl H atom of a solvate molecule of acetic acid. Crystals Ib have a layered structure. The crystallization water molecule is involved in the formation of three intermolecular hydrogen bonds, namely, those with the H atom of the amide group and the carbonyl O atoms of molecule I and an acetic acid molecule of the neighboring layer.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf N6d918acaca0040d0924240aa555e11de
11 Na0a6f536492344ec98e2fe38910cd573
12 sg:journal.1295066
13 schema:keywords H atoms
14 IA
15 IB
16 N atoms
17 O atoms
18 X-ray diffraction
19 acetic acid
20 acetic acid molecules
21 acid
22 acid molecules
23 amide group
24 aqueous solution
25 atoms
26 bonds
27 bridge
28 carbonyl O atom
29 cations
30 centrosymmetric
31 chain
32 crystal structure
33 crystallization
34 crystallization water molecules
35 crystals
36 diffraction
37 formation
38 group
39 hydrochloric acid
40 hydrogen bonds
41 hydroxyl H atom
42 intermolecular hydrogen bonds
43 layer
44 molecule I
45 molecules
46 neighboring layers
47 nitrogen atoms
48 ns
49 products
50 products of crystallization
51 protonation
52 pyridine N atom
53 pyridine ring
54 ring
55 solution
56 solvate molecules
57 structure
58 water molecules
59 water-methanol solutions
60 schema:name Molecular and crystal structures of the products of crystallization of (N′-furfurylidene)isonicotinoylhydrazide from aqueous solutions of hydrochloric and acetic acids
61 schema:pagination 394-397
62 schema:productId N2bc8b536d1ce47748319c47bd518a7c0
63 N55f705311e154b3ca1cbbe15fe6d76c3
64 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032861650
65 https://doi.org/10.1134/1.1376467
66 schema:sdDatePublished 2022-11-24T20:49
67 schema:sdLicense https://scigraph.springernature.com/explorer/license/
68 schema:sdPublisher N4ca9db4eaeb04c00879cd8e3faa5ba9b
69 schema:url https://doi.org/10.1134/1.1376467
70 sgo:license sg:explorer/license/
71 sgo:sdDataset articles
72 rdf:type schema:ScholarlyArticle
73 N04dcea38ac894d5aba439fbf2a6fdecc rdf:first sg:person.013232115673.09
74 rdf:rest rdf:nil
75 N29f0c38cdddc4cbe88b26739e6ec1191 rdf:first sg:person.012555612421.75
76 rdf:rest Ncaad8b09f0174ed9bc40b8052bd8fc99
77 N2bc8b536d1ce47748319c47bd518a7c0 schema:name dimensions_id
78 schema:value pub.1032861650
79 rdf:type schema:PropertyValue
80 N3605684683b84244b13af61d98680fe3 rdf:first sg:person.07417605661.11
81 rdf:rest N563a6d84026f4c7999129b7c8274c5a6
82 N4ca9db4eaeb04c00879cd8e3faa5ba9b schema:name Springer Nature - SN SciGraph project
83 rdf:type schema:Organization
84 N55f705311e154b3ca1cbbe15fe6d76c3 schema:name doi
85 schema:value 10.1134/1.1376467
86 rdf:type schema:PropertyValue
87 N563a6d84026f4c7999129b7c8274c5a6 rdf:first sg:person.015236213545.72
88 rdf:rest N04dcea38ac894d5aba439fbf2a6fdecc
89 N6d918acaca0040d0924240aa555e11de schema:issueNumber 3
90 rdf:type schema:PublicationIssue
91 Na0a6f536492344ec98e2fe38910cd573 schema:volumeNumber 46
92 rdf:type schema:PublicationVolume
93 Ncaad8b09f0174ed9bc40b8052bd8fc99 rdf:first sg:person.010420665017.96
94 rdf:rest N3605684683b84244b13af61d98680fe3
95 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
96 schema:name Chemical Sciences
97 rdf:type schema:DefinedTerm
98 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
99 schema:name Inorganic Chemistry
100 rdf:type schema:DefinedTerm
101 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
102 schema:name Physical Chemistry (incl. Structural)
103 rdf:type schema:DefinedTerm
104 sg:journal.1295066 schema:issn 1063-7745
105 1562-689X
106 schema:name Crystallography Reports
107 schema:publisher Pleiades Publishing
108 rdf:type schema:Periodical
109 sg:person.010420665017.96 schema:affiliation grid-institutes:grid.4886.2
110 schema:familyName Nikonova
111 schema:givenName L. A.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010420665017.96
113 rdf:type schema:Person
114 sg:person.012555612421.75 schema:affiliation grid-institutes:grid.4886.2
115 schema:familyName Chuev
116 schema:givenName I. I.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555612421.75
118 rdf:type schema:Person
119 sg:person.013232115673.09 schema:affiliation grid-institutes:grid.4886.2
120 schema:familyName Aldoshin
121 schema:givenName S. M.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09
123 rdf:type schema:Person
124 sg:person.015236213545.72 schema:affiliation grid-institutes:grid.4886.2
125 schema:familyName Utenyshev
126 schema:givenName A. N.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72
128 rdf:type schema:Person
129 sg:person.07417605661.11 schema:affiliation grid-institutes:grid.4886.2
130 schema:familyName Atovmyan
131 schema:givenName E. G.
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07417605661.11
133 rdf:type schema:Person
134 grid-institutes:grid.4886.2 schema:alternateName Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia
135 schema:name Institute of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia
136 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...