Diamond-graphite phase transition in ultradisperse-diamond clusters View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-06

AUTHORS

A. E. Aleksenskii, M. V. Baidakova, A. Ya. Vul’, V. Yu. Davydov, Yu. A. Pevtsova

ABSTRACT

A systematic study of the diamond-graphite structural phase transition in ultradisperse-diamond clusters obtained by the detonation technique is reported. Samples of two types, differing in the kinetics of detonation-product cooling, were investigated. The phase transition was achieved under heating in an inert atmosphere in the temperature range 720–1400 K. The transition was identified by Raman scattering and x-ray diffraction data. Raman and x-ray characterization showed the ultradisperse diamond, irrespective of the cooling rate used, to be cluster material possessing diamond structure with a characteristic nanocrystal size of 43 Å. The diamond-graphite phase transition in ultradisperse diamond is shown to start from the cluster surface inwards at Tpt≈1200 K, i.e. at substantially lower temperatures than is the case with bulk diamond single crystals. More... »

PAGES

1007-1015

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/1.1129989

DOI

http://dx.doi.org/10.1134/1.1129989

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034649044


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