Efficient artificial mineralization route to decontaminate Arsenic(III) polluted water - the Tooeleite Way View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-05-18

AUTHORS

Arindam Malakar, Bidisa Das, Samirul Islam, Carlo Meneghini, Giovanni De Giudici, Marco Merlini, Yury V. Kolen’ko, Antonella Iadecola, Giuliana Aquilanti, Somobrata Acharya, Sugata Ray

ABSTRACT

Increasing exposure to arsenic (As) contaminated ground water is a great threat to humanity. Suitable technology for As immobilization and removal from water, especially for As(III) than As(V), is not available yet. However, it is known that As(III) is more toxic than As(V) and most groundwater aquifers, particularly the Gangetic basin in India, is alarmingly contaminated with it. In search of a viable solution here, we took a cue from the natural mineralization of Tooeleite, a mineral containing Fe(III) and As(III)ions, grown under acidic condition, in presence of SO4(2-) ions. Complying to this natural process, we could grow and separate Tooeleite-like templates from Fe(III) and As(III) containing water at overall circumneutral pH and in absence of SO4(2-) ions by using highly polar Zn-only ends of wurtzite ZnS nanorods as insoluble nano-acidic-surfaces. The central idea here is to exploit these insoluble nano-acidic-surfaces (called as INAS in the manuscript) as nucleation centres for Tooeleite growth while keeping the overall pH of the aqueous media neutral. Therefore, we propose a novel method of artificial mineralization of As(III) by mimicking a natural process at nanoscale. More... »

PAGES

26031

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep26031

DOI

http://dx.doi.org/10.1038/srep26031

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017858282

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/27189251


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