The effect of annealing on a 3D SnO2/graphene foam as an advanced lithium-ion battery anode View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-05

AUTHORS

Ran Tian, Yangyang Zhang, Zhihang Chen, Huanan Duan, Biyi Xu, Yiping Guo, Hongmei Kang, Hua Li, Hezhou Liu

ABSTRACT

3D annealed SnO2/graphene sheet foams (ASGFs) are synthesized by in situ self-assembly of graphene sheets prepared by mild chemical reduction. L-ascorbyl acid is used to effectively reduce the SnO2 nanoparticles/graphene oxide colloidal solution and form the 3D conductive graphene networks. The annealing treatment contributes to the formation of the Sn-O-C bonds between the SnO2 nanoparticles and the reduced graphene sheets, which improves the electrochemical performance of the foams. The ASGF has features of typical aerogels: low density (about 19 mg cm(-3)), smooth surface and porous structure. The ASGF anodes exhibit good specific capacity, excellent cycling stability and superior rate capability. The first reversible specific capacity is as high as 984.2 mAh g(-1) at a specific current of 200 mA g(-1). Even at the high specific current of 1000 mA g(-1) after 150 cycles, the reversible specific capacity of ASGF is still as high as 533.7 mAh g(-1), about twice as much as that of SGF (297.6 mAh g(-1)) after the same test. This synthesis method can be scaled up to prepare other metal oxides particles/ graphene sheet foams for high performance lithium-ion batteries, supercapacitors, and catalysts, etc. More... »

PAGES

19195

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep19195

DOI

http://dx.doi.org/10.1038/srep19195

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026912211

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/26754468


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