In-plane chemical pressure essential for superconductivity in BiCh2-based (Ch: S, Se) layered structure View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2015-12

AUTHORS

Yoshikazu Mizuguchi, Akira Miura, Joe Kajitani, Takafumi Hiroi, Osuke Miura, Kiyoharu Tadanaga, Nobuhiro Kumada, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa

ABSTRACT

BiCh2-based compounds (Ch: S, Se) are a new series of layered superconductors, and the mechanisms for the emergence of superconductivity in these materials have not yet been elucidated. In this study, we investigate the relationship between crystal structure and superconducting properties of the BiCh2-based superconductor family, specifically, optimally doped Ce1-xNdxO0.5F0.5BiS2 and LaO0.5F0.5Bi(S1-ySey)2. We use powder synchrotron X-ray diffraction to determine the crystal structures. We show that the structure parameter essential for the emergence of bulk superconductivity in both systems is the in-plane chemical pressure, rather than Bi-Ch bond lengths or in-plane Ch-Bi-Ch bond angle. Furthermore, we show that the superconducting transition temperature for all REO0.5F0.5BiCh2 superconductors can be determined from the in-plane chemical pressure. More... »

PAGES

14968

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep14968

DOI

http://dx.doi.org/10.1038/srep14968

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042815828

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/26447333


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