Rechargeable magnesium-ion battery based on a TiSe2-cathode with d-p orbital hybridized electronic structure View Full Text


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Article Info

DATE

2015-12

AUTHORS

Yunpeng Gu, Yukari Katsura, Takafumi Yoshino, Hidenori Takagi, Kouji Taniguchi

ABSTRACT

Rechargeable ion-batteries, in which ions such as Li(+) carry charges between electrodes, have been contributing to the improvement of power-source performance in a wide variety of mobile electronic devices. Among them, Mg-ion batteries are recently attracting attention due to possible low cost and safety, which are realized by abundant natural resources and stability of Mg in the atmosphere. However, only a few materials have been known to work as rechargeable cathodes for Mg-ion batteries, owing to strong electrostatic interaction between Mg(2+) and the host lattice. Here we demonstrate rechargeable performance of Mg-ion batteries at ambient temperature by selecting TiSe2 as a model cathode by focusing on electronic structure. Charge delocalization of electrons in a metal-ligand unit through d-p orbital hybridization is suggested as a possible key factor to realize reversible intercalation of Mg(2+) into TiSe2. The viewpoint from the electronic structure proposed in this study might pave a new way to design electrode materials for multivalent-ion batteries. More... »

PAGES

12486

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep12486

DOI

http://dx.doi.org/10.1038/srep12486

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010008326

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/26228263


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/srep12486'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/srep12486'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/srep12486'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/srep12486'


 

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