Multi-layer electrode with nano-Li4Ti5O12 aggregates sandwiched between carbon nanotube and graphene networks for high power Li-ion batteries View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2015-05

AUTHORS

Jin-Hoon Choi, Won-Hee Ryu, Kyusung Park, Jeong-Dai Jo, Sung-Moo Jo, Dae-Soon Lim, Il-Doo Kim

ABSTRACT

Self-aggregated Li4Ti5O12 particles sandwiched between graphene nanosheets (GNSs) and single-walled carbon nanotubes (SWCNTs) network are reported as new hybrid electrodes for high power Li-ion batteries. The multi-layer electrodes are fabricated by sequential process comprising air-spray coating of GNSs layer and the following electrostatic spray (E-spray) coating of well-dispersed colloidal Li4Ti5O12 nanoparticles, and subsequent air-spray coating of SWCNTs layer once again. In multi-stacked electrodes of GNSs/nanoporous Li4Ti5O12 aggregates/SWCNTs networks, GNSs and SWCNTs serve as conducting bridges, effectively interweaving the nanoporous Li4Ti5O12 aggregates, and help achieve superior rate capability as well as improved mechanical stability of the composite electrode by holding Li4Ti5O12 tightly without a binder. The multi-stacked electrodes deliver a specific capacity that maintains an impressively high capacity of 100 mA h g(-1) at a high rate of 100C even after 1000 cycles. More... »

PAGES

7334

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep07334

DOI

http://dx.doi.org/10.1038/srep07334

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022749099

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/25476980


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