Three-Dimensional Fe2O3 Nanocubes/Nitrogen-doped Graphene Aerogels: Nucleation Mechanism and Lithium Storage Properties View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2015-05

AUTHORS

Ronghua Wang, Chaohe Xu, Jing Sun, Lian Gao

ABSTRACT

We developed a solvothermal-induced self-assembly approach to construct three dimensional (3D) macroscopic Fe2O3 nanocubes/nitrogen-doped graphene (Fe2O3-NC/GN) aerogel as anode materials for lithium-ion batteries (LIBs). The Fe2O3 nanocubes with length of ~50 nm are homogeneously anchored on 3D GN frameworks and as spacers to separate the neighboring GN sheets. Based on intensively investigations on the early stages of formation process, it is discovered that a non-classical nanoparticle-mediated crystallization process and a subsequent classical ion-mediated growth dominate the nanocube formation. This is totally different from the commonly recognized classical atom-mediated crystallization and ripening mechanism. Benefitting from the unique structures and characteristics, the optimized Fe2O3-NC/GN aerogel exhibits excellent rate capability, outstanding long-term cyclic stability at high current densities, which are outperforming most of Fe2O3/GS hybrid electrodes. These results suggest us to in-depth understand the detailed crystallization process, and rational design and precisely control the morphologies of nanocrystals on graphene for high performance energy applications. More... »

PAGES

7171

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep07171

DOI

http://dx.doi.org/10.1038/srep07171

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010419475

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/25421070


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Shanghai Institute of Ceramics", 
          "id": "https://www.grid.ac/institutes/grid.454856.e", 
          "name": [
            "The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Ding Xi Road, Shanghai 200050."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Ronghua", 
        "id": "sg:person.0662666043.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662666043.76"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Institute of Ceramics", 
          "id": "https://www.grid.ac/institutes/grid.454856.e", 
          "name": [
            "The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Ding Xi Road, Shanghai 200050."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xu", 
        "givenName": "Chaohe", 
        "id": "sg:person.01365400061.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365400061.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Institute of Ceramics", 
          "id": "https://www.grid.ac/institutes/grid.454856.e", 
          "name": [
            "The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Ding Xi Road, Shanghai 200050."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sun", 
        "givenName": "Jing", 
        "id": "sg:person.01277751116.74", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01277751116.74"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Institute of Ceramics", 
          "id": "https://www.grid.ac/institutes/grid.454856.e", 
          "name": [
            "The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Ding Xi Road, Shanghai 200050."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gao", 
        "givenName": "Lian", 
        "id": "sg:person.01346064316.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01346064316.37"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/adfm.201202254", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000517443"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/smll.201303371", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001681599"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2ee24148j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003293948"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2ra21825a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003456956"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201300190", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003823482"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200802783", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003945010"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200802783", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003945010"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3nr01392h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004644570"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201001054", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006330546"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201001054", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006330546"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2jm32893c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007064119"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aenm.201300958", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009208765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1cs15043j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009751206"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-009-9036-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010818072", 
          "https://doi.org/10.1007/s12274-009-9036-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-009-9036-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010818072", 
          "https://doi.org/10.1007/s12274-009-9036-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3ee23870a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012184867"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr3001884", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013918786"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar300094m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014615939"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1cc12171e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014683656"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3ee24158k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014730384"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1368", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014889034", 
          "https://doi.org/10.1038/nmat1368"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1368", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014889034", 
          "https://doi.org/10.1038/nmat1368"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.carbon.2012.09.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017707304"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2012.07.029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017769079"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2ta00753c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018140257"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn300082k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020068059"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201103163", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021247673"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b604589h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021895422"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3nr03484d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023351366"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2jm31053h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025026621"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja3030565", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026544898"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl080093z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027135783"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl080093z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027135783"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja206030c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027346802"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn200493r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032930906"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp103696u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033636944"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp103696u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033636944"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cc33469k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036121319"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja3089923", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036799995"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la047671l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036894018"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la047671l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036894018"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/smll.200800520", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037244190"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2nr30482a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038155967"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cc36620g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038649829"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/srep03502", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039552944", 
          "https://doi.org/10.1038/srep03502"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja102267j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040686253"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja102267j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040686253"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0nr01016b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040987986"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3ta00183k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041671882"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201303115", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043577883"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201303023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044711403"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201102838", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044978049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200901365", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047104652"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201001068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047953299"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201001068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047953299"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2jm15927a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048406077"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0cc04570e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050718892"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.nanoen.2013.10.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051700821"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cs35307e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052332082"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/am400387t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055143326"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/am405557c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055144914"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar200164u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055150099"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar300088q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055150232"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cg8001543", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055398250"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cg8001543", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055398250"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja100329d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055846786"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja100329d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055846786"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja909769a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055863050"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja909769a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055863050"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0473669", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056058052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0473669", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056058052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl102786k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056218195"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl102786k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056218195"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl302618s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056219596"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl8024467", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056221543"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl8024467", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056221543"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn101926g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056222858"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2907325", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057880965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2975237", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057889119"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-05", 
    "datePublishedReg": "2015-05-01", 
    "description": "We developed a solvothermal-induced self-assembly approach to construct three dimensional (3D) macroscopic Fe2O3 nanocubes/nitrogen-doped graphene (Fe2O3-NC/GN) aerogel as anode materials for lithium-ion batteries (LIBs). The Fe2O3 nanocubes with length of ~50 nm are homogeneously anchored on 3D GN frameworks and as spacers to separate the neighboring GN sheets. Based on intensively investigations on the early stages of formation process, it is discovered that a non-classical nanoparticle-mediated crystallization process and a subsequent classical ion-mediated growth dominate the nanocube formation. This is totally different from the commonly recognized classical atom-mediated crystallization and ripening mechanism. Benefitting from the unique structures and characteristics, the optimized Fe2O3-NC/GN aerogel exhibits excellent rate capability, outstanding long-term cyclic stability at high current densities, which are outperforming most of Fe2O3/GS hybrid electrodes. These results suggest us to in-depth understand the detailed crystallization process, and rational design and precisely control the morphologies of nanocrystals on graphene for high performance energy applications.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/srep07171", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.7018863", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.4964948", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.5015967", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1045337", 
        "issn": [
          "2045-2322"
        ], 
        "name": "Scientific Reports", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "4"
      }
    ], 
    "name": "Three-Dimensional Fe2O3 Nanocubes/Nitrogen-doped Graphene Aerogels: Nucleation Mechanism and Lithium Storage Properties", 
    "pagination": "7171", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "31a3a2e87e88f6495fb67b07f5ee954eeb052336289233ffd2b415c03a65986a"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "25421070"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101563288"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/srep07171"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1010419475"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/srep07171", 
      "https://app.dimensions.ai/details/publication/pub.1010419475"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T21:24", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000422.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://www.nature.com/srep/2014/141125/srep07171/full/srep07171.html"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/srep07171'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/srep07171'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/srep07171'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/srep07171'


 

This table displays all metadata directly associated to this object as RDF triples.

290 TRIPLES      21 PREDICATES      93 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/srep07171 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N537a3664433342d197a9622064d1539e
4 schema:citation sg:pub.10.1007/s12274-009-9036-5
5 sg:pub.10.1038/nmat1368
6 sg:pub.10.1038/srep03502
7 https://doi.org/10.1002/adfm.201001054
8 https://doi.org/10.1002/adfm.201202254
9 https://doi.org/10.1002/adfm.201300190
10 https://doi.org/10.1002/adfm.201303023
11 https://doi.org/10.1002/adma.200802783
12 https://doi.org/10.1002/adma.200901365
13 https://doi.org/10.1002/adma.201001068
14 https://doi.org/10.1002/adma.201102838
15 https://doi.org/10.1002/adma.201303115
16 https://doi.org/10.1002/aenm.201300958
17 https://doi.org/10.1002/anie.201103163
18 https://doi.org/10.1002/smll.200800520
19 https://doi.org/10.1002/smll.201303371
20 https://doi.org/10.1016/j.carbon.2012.09.004
21 https://doi.org/10.1016/j.electacta.2012.07.029
22 https://doi.org/10.1016/j.nanoen.2013.10.003
23 https://doi.org/10.1021/am400387t
24 https://doi.org/10.1021/am405557c
25 https://doi.org/10.1021/ar200164u
26 https://doi.org/10.1021/ar300088q
27 https://doi.org/10.1021/ar300094m
28 https://doi.org/10.1021/cg8001543
29 https://doi.org/10.1021/cr3001884
30 https://doi.org/10.1021/ja100329d
31 https://doi.org/10.1021/ja102267j
32 https://doi.org/10.1021/ja206030c
33 https://doi.org/10.1021/ja3030565
34 https://doi.org/10.1021/ja3089923
35 https://doi.org/10.1021/ja909769a
36 https://doi.org/10.1021/jp0473669
37 https://doi.org/10.1021/jp103696u
38 https://doi.org/10.1021/la047671l
39 https://doi.org/10.1021/nl080093z
40 https://doi.org/10.1021/nl102786k
41 https://doi.org/10.1021/nl302618s
42 https://doi.org/10.1021/nl8024467
43 https://doi.org/10.1021/nn101926g
44 https://doi.org/10.1021/nn200493r
45 https://doi.org/10.1021/nn300082k
46 https://doi.org/10.1039/b604589h
47 https://doi.org/10.1039/c0cc04570e
48 https://doi.org/10.1039/c0nr01016b
49 https://doi.org/10.1039/c1cc12171e
50 https://doi.org/10.1039/c1cs15043j
51 https://doi.org/10.1039/c2cc33469k
52 https://doi.org/10.1039/c2cc36620g
53 https://doi.org/10.1039/c2cs35307e
54 https://doi.org/10.1039/c2ee24148j
55 https://doi.org/10.1039/c2jm15927a
56 https://doi.org/10.1039/c2jm31053h
57 https://doi.org/10.1039/c2jm32893c
58 https://doi.org/10.1039/c2nr30482a
59 https://doi.org/10.1039/c2ra21825a
60 https://doi.org/10.1039/c2ta00753c
61 https://doi.org/10.1039/c3ee23870a
62 https://doi.org/10.1039/c3ee24158k
63 https://doi.org/10.1039/c3nr01392h
64 https://doi.org/10.1039/c3nr03484d
65 https://doi.org/10.1039/c3ta00183k
66 https://doi.org/10.1063/1.2907325
67 https://doi.org/10.1063/1.2975237
68 schema:datePublished 2015-05
69 schema:datePublishedReg 2015-05-01
70 schema:description We developed a solvothermal-induced self-assembly approach to construct three dimensional (3D) macroscopic Fe2O3 nanocubes/nitrogen-doped graphene (Fe2O3-NC/GN) aerogel as anode materials for lithium-ion batteries (LIBs). The Fe2O3 nanocubes with length of ~50 nm are homogeneously anchored on 3D GN frameworks and as spacers to separate the neighboring GN sheets. Based on intensively investigations on the early stages of formation process, it is discovered that a non-classical nanoparticle-mediated crystallization process and a subsequent classical ion-mediated growth dominate the nanocube formation. This is totally different from the commonly recognized classical atom-mediated crystallization and ripening mechanism. Benefitting from the unique structures and characteristics, the optimized Fe2O3-NC/GN aerogel exhibits excellent rate capability, outstanding long-term cyclic stability at high current densities, which are outperforming most of Fe2O3/GS hybrid electrodes. These results suggest us to in-depth understand the detailed crystallization process, and rational design and precisely control the morphologies of nanocrystals on graphene for high performance energy applications.
71 schema:genre research_article
72 schema:inLanguage en
73 schema:isAccessibleForFree true
74 schema:isPartOf N259abd31a5964c07ac62014939dcfbda
75 N8a880ef080d54e4abcc9a9694661fd22
76 sg:journal.1045337
77 schema:name Three-Dimensional Fe2O3 Nanocubes/Nitrogen-doped Graphene Aerogels: Nucleation Mechanism and Lithium Storage Properties
78 schema:pagination 7171
79 schema:productId N08989c96f46e4283a29a6c6756735932
80 N30300662705f4801accb9f9ab93d01d7
81 N5725cbdae52c4c1c82fe61c05822038f
82 N6e7cfedde31e4d27ab1b3af2b4be58f8
83 Nbf68ef938af0454489b63c8fa664a181
84 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010419475
85 https://doi.org/10.1038/srep07171
86 schema:sdDatePublished 2019-04-10T21:24
87 schema:sdLicense https://scigraph.springernature.com/explorer/license/
88 schema:sdPublisher Na26dd8b815874ef69a97a0012493cd42
89 schema:url http://www.nature.com/srep/2014/141125/srep07171/full/srep07171.html
90 sgo:license sg:explorer/license/
91 sgo:sdDataset articles
92 rdf:type schema:ScholarlyArticle
93 N08989c96f46e4283a29a6c6756735932 schema:name pubmed_id
94 schema:value 25421070
95 rdf:type schema:PropertyValue
96 N259abd31a5964c07ac62014939dcfbda schema:volumeNumber 4
97 rdf:type schema:PublicationVolume
98 N30300662705f4801accb9f9ab93d01d7 schema:name nlm_unique_id
99 schema:value 101563288
100 rdf:type schema:PropertyValue
101 N537a3664433342d197a9622064d1539e rdf:first sg:person.0662666043.76
102 rdf:rest Nfffdb40388b74b9ca39420b4f9508651
103 N5725cbdae52c4c1c82fe61c05822038f schema:name readcube_id
104 schema:value 31a3a2e87e88f6495fb67b07f5ee954eeb052336289233ffd2b415c03a65986a
105 rdf:type schema:PropertyValue
106 N6e7cfedde31e4d27ab1b3af2b4be58f8 schema:name doi
107 schema:value 10.1038/srep07171
108 rdf:type schema:PropertyValue
109 N8a880ef080d54e4abcc9a9694661fd22 schema:issueNumber 1
110 rdf:type schema:PublicationIssue
111 Na26dd8b815874ef69a97a0012493cd42 schema:name Springer Nature - SN SciGraph project
112 rdf:type schema:Organization
113 Nbf68ef938af0454489b63c8fa664a181 schema:name dimensions_id
114 schema:value pub.1010419475
115 rdf:type schema:PropertyValue
116 Nee8464c2e609434e894ad611a68f13f4 rdf:first sg:person.01277751116.74
117 rdf:rest Nf1cec61493dd47f4a1ab56e2165648f6
118 Nf1cec61493dd47f4a1ab56e2165648f6 rdf:first sg:person.01346064316.37
119 rdf:rest rdf:nil
120 Nfffdb40388b74b9ca39420b4f9508651 rdf:first sg:person.01365400061.45
121 rdf:rest Nee8464c2e609434e894ad611a68f13f4
122 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
123 schema:name Chemical Sciences
124 rdf:type schema:DefinedTerm
125 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
126 schema:name Physical Chemistry (incl. Structural)
127 rdf:type schema:DefinedTerm
128 sg:grant.4964948 http://pending.schema.org/fundedItem sg:pub.10.1038/srep07171
129 rdf:type schema:MonetaryGrant
130 sg:grant.5015967 http://pending.schema.org/fundedItem sg:pub.10.1038/srep07171
131 rdf:type schema:MonetaryGrant
132 sg:grant.7018863 http://pending.schema.org/fundedItem sg:pub.10.1038/srep07171
133 rdf:type schema:MonetaryGrant
134 sg:journal.1045337 schema:issn 2045-2322
135 schema:name Scientific Reports
136 rdf:type schema:Periodical
137 sg:person.01277751116.74 schema:affiliation https://www.grid.ac/institutes/grid.454856.e
138 schema:familyName Sun
139 schema:givenName Jing
140 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01277751116.74
141 rdf:type schema:Person
142 sg:person.01346064316.37 schema:affiliation https://www.grid.ac/institutes/grid.454856.e
143 schema:familyName Gao
144 schema:givenName Lian
145 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01346064316.37
146 rdf:type schema:Person
147 sg:person.01365400061.45 schema:affiliation https://www.grid.ac/institutes/grid.454856.e
148 schema:familyName Xu
149 schema:givenName Chaohe
150 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365400061.45
151 rdf:type schema:Person
152 sg:person.0662666043.76 schema:affiliation https://www.grid.ac/institutes/grid.454856.e
153 schema:familyName Wang
154 schema:givenName Ronghua
155 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662666043.76
156 rdf:type schema:Person
157 sg:pub.10.1007/s12274-009-9036-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010818072
158 https://doi.org/10.1007/s12274-009-9036-5
159 rdf:type schema:CreativeWork
160 sg:pub.10.1038/nmat1368 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014889034
161 https://doi.org/10.1038/nmat1368
162 rdf:type schema:CreativeWork
163 sg:pub.10.1038/srep03502 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039552944
164 https://doi.org/10.1038/srep03502
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1002/adfm.201001054 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006330546
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1002/adfm.201202254 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000517443
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1002/adfm.201300190 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003823482
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1002/adfm.201303023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044711403
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1002/adma.200802783 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003945010
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1002/adma.200901365 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047104652
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1002/adma.201001068 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047953299
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1002/adma.201102838 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044978049
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1002/adma.201303115 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043577883
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1002/aenm.201300958 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009208765
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1002/anie.201103163 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021247673
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1002/smll.200800520 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037244190
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1002/smll.201303371 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001681599
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1016/j.carbon.2012.09.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017707304
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1016/j.electacta.2012.07.029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017769079
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1016/j.nanoen.2013.10.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051700821
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1021/am400387t schema:sameAs https://app.dimensions.ai/details/publication/pub.1055143326
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1021/am405557c schema:sameAs https://app.dimensions.ai/details/publication/pub.1055144914
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1021/ar200164u schema:sameAs https://app.dimensions.ai/details/publication/pub.1055150099
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1021/ar300088q schema:sameAs https://app.dimensions.ai/details/publication/pub.1055150232
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1021/ar300094m schema:sameAs https://app.dimensions.ai/details/publication/pub.1014615939
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1021/cg8001543 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055398250
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1021/cr3001884 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013918786
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1021/ja100329d schema:sameAs https://app.dimensions.ai/details/publication/pub.1055846786
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1021/ja102267j schema:sameAs https://app.dimensions.ai/details/publication/pub.1040686253
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1021/ja206030c schema:sameAs https://app.dimensions.ai/details/publication/pub.1027346802
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1021/ja3030565 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026544898
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1021/ja3089923 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036799995
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1021/ja909769a schema:sameAs https://app.dimensions.ai/details/publication/pub.1055863050
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1021/jp0473669 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056058052
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1021/jp103696u schema:sameAs https://app.dimensions.ai/details/publication/pub.1033636944
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1021/la047671l schema:sameAs https://app.dimensions.ai/details/publication/pub.1036894018
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1021/nl080093z schema:sameAs https://app.dimensions.ai/details/publication/pub.1027135783
231 rdf:type schema:CreativeWork
232 https://doi.org/10.1021/nl102786k schema:sameAs https://app.dimensions.ai/details/publication/pub.1056218195
233 rdf:type schema:CreativeWork
234 https://doi.org/10.1021/nl302618s schema:sameAs https://app.dimensions.ai/details/publication/pub.1056219596
235 rdf:type schema:CreativeWork
236 https://doi.org/10.1021/nl8024467 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056221543
237 rdf:type schema:CreativeWork
238 https://doi.org/10.1021/nn101926g schema:sameAs https://app.dimensions.ai/details/publication/pub.1056222858
239 rdf:type schema:CreativeWork
240 https://doi.org/10.1021/nn200493r schema:sameAs https://app.dimensions.ai/details/publication/pub.1032930906
241 rdf:type schema:CreativeWork
242 https://doi.org/10.1021/nn300082k schema:sameAs https://app.dimensions.ai/details/publication/pub.1020068059
243 rdf:type schema:CreativeWork
244 https://doi.org/10.1039/b604589h schema:sameAs https://app.dimensions.ai/details/publication/pub.1021895422
245 rdf:type schema:CreativeWork
246 https://doi.org/10.1039/c0cc04570e schema:sameAs https://app.dimensions.ai/details/publication/pub.1050718892
247 rdf:type schema:CreativeWork
248 https://doi.org/10.1039/c0nr01016b schema:sameAs https://app.dimensions.ai/details/publication/pub.1040987986
249 rdf:type schema:CreativeWork
250 https://doi.org/10.1039/c1cc12171e schema:sameAs https://app.dimensions.ai/details/publication/pub.1014683656
251 rdf:type schema:CreativeWork
252 https://doi.org/10.1039/c1cs15043j schema:sameAs https://app.dimensions.ai/details/publication/pub.1009751206
253 rdf:type schema:CreativeWork
254 https://doi.org/10.1039/c2cc33469k schema:sameAs https://app.dimensions.ai/details/publication/pub.1036121319
255 rdf:type schema:CreativeWork
256 https://doi.org/10.1039/c2cc36620g schema:sameAs https://app.dimensions.ai/details/publication/pub.1038649829
257 rdf:type schema:CreativeWork
258 https://doi.org/10.1039/c2cs35307e schema:sameAs https://app.dimensions.ai/details/publication/pub.1052332082
259 rdf:type schema:CreativeWork
260 https://doi.org/10.1039/c2ee24148j schema:sameAs https://app.dimensions.ai/details/publication/pub.1003293948
261 rdf:type schema:CreativeWork
262 https://doi.org/10.1039/c2jm15927a schema:sameAs https://app.dimensions.ai/details/publication/pub.1048406077
263 rdf:type schema:CreativeWork
264 https://doi.org/10.1039/c2jm31053h schema:sameAs https://app.dimensions.ai/details/publication/pub.1025026621
265 rdf:type schema:CreativeWork
266 https://doi.org/10.1039/c2jm32893c schema:sameAs https://app.dimensions.ai/details/publication/pub.1007064119
267 rdf:type schema:CreativeWork
268 https://doi.org/10.1039/c2nr30482a schema:sameAs https://app.dimensions.ai/details/publication/pub.1038155967
269 rdf:type schema:CreativeWork
270 https://doi.org/10.1039/c2ra21825a schema:sameAs https://app.dimensions.ai/details/publication/pub.1003456956
271 rdf:type schema:CreativeWork
272 https://doi.org/10.1039/c2ta00753c schema:sameAs https://app.dimensions.ai/details/publication/pub.1018140257
273 rdf:type schema:CreativeWork
274 https://doi.org/10.1039/c3ee23870a schema:sameAs https://app.dimensions.ai/details/publication/pub.1012184867
275 rdf:type schema:CreativeWork
276 https://doi.org/10.1039/c3ee24158k schema:sameAs https://app.dimensions.ai/details/publication/pub.1014730384
277 rdf:type schema:CreativeWork
278 https://doi.org/10.1039/c3nr01392h schema:sameAs https://app.dimensions.ai/details/publication/pub.1004644570
279 rdf:type schema:CreativeWork
280 https://doi.org/10.1039/c3nr03484d schema:sameAs https://app.dimensions.ai/details/publication/pub.1023351366
281 rdf:type schema:CreativeWork
282 https://doi.org/10.1039/c3ta00183k schema:sameAs https://app.dimensions.ai/details/publication/pub.1041671882
283 rdf:type schema:CreativeWork
284 https://doi.org/10.1063/1.2907325 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057880965
285 rdf:type schema:CreativeWork
286 https://doi.org/10.1063/1.2975237 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057889119
287 rdf:type schema:CreativeWork
288 https://www.grid.ac/institutes/grid.454856.e schema:alternateName Shanghai Institute of Ceramics
289 schema:name The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Ding Xi Road, Shanghai 200050.
290 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...