Atomic-scale decoration for improving the pitting corrosion resistance of austenitic stainless steels View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2015-05

AUTHORS

Y. T. Zhou, B. Zhang, S. J. Zheng, J. Wang, X. Y. San, X. L.

ABSTRACT

Stainless steels are susceptible to the localized pitting corrosion that leads to a huge loss to our society. Studies in the past decades confirmed that the pitting events generally originate from the local dissolution in MnS inclusions which are more or less ubiquitous in stainless steels. Although a recent study indicated that endogenous MnCr2O4 nano-octahedra within the MnS medium give rise to local nano-galvanic cells which are responsible for the preferential dissolution of MnS, effective solutions of restraining the cells from viewpoint of electrochemistry are being tantalizingly searched. Here we report such a galvanic corrosion can be greatly resisted via bathing the steels in Cu(2+)-containing solutions. This chemical bath generates Cu(2-δ)S layers on the surfaces of MnS inclusions, invalidating the nano-galvanic cells. Our study provides a low-cost approach via an atomic scale decoration to improve the pitting corrosion resistance of stainless steels in a volume-treated manner. More... »

PAGES

3604

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/srep03604

DOI

http://dx.doi.org/10.1038/srep03604

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025771980

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/24398863


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