Regio- and stereoselective synthesis of tetra- and triarylethenes by N -methylimidodiacetyl boron-directed palladium-catalysed three-component coupling View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-12

AUTHORS

E. Emily Lin, Jia-Qiang Wu, Felix Schäfers, Xiao-Xuan Su, Ke-Feng Wang, Ji-Lin Li, Yunyun Chen, Xin Zhao, Huihui Ti, Qingjiang Li, Tian-Miao Ou, Frank Glorius, Honggen Wang

ABSTRACT

The synthesis of tri- and tetra-aryl alkenes is limited by poor regio- and stereoselectivity. Here MIDA boronate-substituted aryl alkynes are used to achieve regioselective three-component diarylation of the alkyne and to provide a cross-coupling handle for subsequent elaboration to tri- or tetra-substituted products.

PAGES

34

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s42004-019-0137-0

DOI

http://dx.doi.org/10.1038/s42004-019-0137-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112937501


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