Interplay of arene radical cations with anions and fluorinated alcohols in hole catalysis View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-12

AUTHORS

Naoki Shida, Yasushi Imada, Shingo Nagahara, Yohei Okada, Kazuhiro Chiba

ABSTRACT

Fluorinated solvents such as hexafluoroisopropanol (HFIP) are often useful in reactions involving radical cations. Here the role of HFIP in photoredox and electrochemical Diels-Alder reactions is explored experimentally and theoretically, and attributed to solvation of anions to reduce their nucleophilicity.

PAGES

24

References to SciGraph publications

  • 2014-09. The electron is a catalyst in NATURE CHEMISTRY
  • 2017-11-08. Hexafluoroisopropanol as a highly versatile solvent in NATURE REVIEWS CHEMISTRY
  • Journal

    TITLE

    Communications Chemistry

    ISSUE

    1

    VOLUME

    2

    From Grant

  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/s42004-019-0125-4

    DOI

    http://dx.doi.org/10.1038/s42004-019-0125-4

    DIMENSIONS

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