Ontology type: schema:ScholarlyArticle
2019-12
AUTHORSNaoki Shida, Yasushi Imada, Shingo Nagahara, Yohei Okada, Kazuhiro Chiba
ABSTRACTFluorinated solvents such as hexafluoroisopropanol (HFIP) are often useful in reactions involving radical cations. Here the role of HFIP in photoredox and electrochemical Diels-Alder reactions is explored experimentally and theoretically, and attributed to solvation of anions to reduce their nucleophilicity.
PAGES24
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DOIhttp://dx.doi.org/10.1038/s42004-019-0125-4
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