Copper nanocavities confine intermediates for efficient electrosynthesis of C3 alcohol fuels from carbon monoxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-10-29

AUTHORS

Tao-Tao Zhuang, Yuanjie Pang, Zhi-Qin Liang, Ziyun Wang, Yi Li, Chih-Shan Tan, Jun Li, Cao Thang Dinh, Phil De Luna, Pei-Lun Hsieh, Thomas Burdyny, Hui-Hui Li, Mengxia Liu, Yuhang Wang, Fengwang Li, Andrew Proppe, Andrew Johnston, Dae-Hyun Nam, Zhen-Yu Wu, Ya-Rong Zheng, Alexander H. Ip, Hairen Tan, Lih-Juann Chen, Shu-Hong Yu, Shana O. Kelley, David Sinton, Edward H. Sargent

ABSTRACT

The electrosynthesis of higher-order alcohols from carbon dioxide and carbon monoxide addresses the need for the long-term storage of renewable electricity; unfortunately, the present-day performance remains below what is needed for practical applications. Here we report a catalyst design strategy that promotes C3 formation via the nanoconfinement of C2 intermediates, and thereby promotes C2:C1 coupling inside a reactive nanocavity. We first employed finite-element method simulations to assess the potential for the retention and binding of C2 intermediates as a function of cavity structure. We then developed a method of synthesizing open Cu nanocavity structures with a tunable geometry via the electroreduction of Cu2O cavities formed through acidic etching. The nanocavities showed a morphology-driven shift in selectivity from C2 to C3 products during the carbon monoxide electroreduction, to reach a propanol Faradaic efficiency of 21 ± 1% at a conversion rate of 7.8 ± 0.5 mA cm−2 at −0.56 V versus a reversible hydrogen electrode. The production of higher alcohols is very valuable because of their high volumetric energy density. Now, Sargent, Sinton and co-workers report the design of copper nanoparticles with tailored nanocavities that promote n-propanol formation by the coupling of C2 and C1 intermediates inside the cavity. More... »

PAGES

1-6

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41929-018-0168-4

DOI

http://dx.doi.org/10.1038/s41929-018-0168-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107689621


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