Direct measurement of topological interactions in polymers under shear using neutron spin echo spectroscopy View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-02-26

AUTHORS

Maciej Kawecki, Franz A. Adlmann, Philipp Gutfreund, Peter Falus, David Uhrig, Sudipta Gupta, Bela Farago, Piotr Zolnierczuk, Malcom Cochran, Max Wolff

ABSTRACT

We present in-situ neutron spin echo measurements on an entangled polydimethylsiloxane melt under shear and demonstrate the ability to monitor nano-scale dynamics in flowing liquids. We report no changes in the topological interactions of the chains for shear rates approaching the inverse longest relaxation time. Further experiments following along this line will allow to systematically test the predictions of theories, like e.g. convective constraint release. More... »

PAGES

2823

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41598-019-39437-2

DOI

http://dx.doi.org/10.1038/s41598-019-39437-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112391069

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30808946


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177 schema:name Institute Laue Langevin (ILL), 71 Avenue des Martyrs, 38000 Grenoble, France
178 rdf:type schema:Organization
179 grid-institutes:grid.8993.b schema:alternateName Department of Physics and Astronomy, Uppsala University, P.O. Box 516, SE-75120 Uppsala, Sweden
180 schema:name Department of Physics and Astronomy, Uppsala University, P.O. Box 516, SE-75120 Uppsala, Sweden
181 rdf:type schema:Organization
 




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