Ontology type: schema:ScholarlyArticle Open Access: True
2019-12
AUTHORSDhiren K. Pradhan, Ajay K. Mishra, Shalini Kumari, Abhisek Basu, Maddury Somayazulu, Elzbieta Gradauskaite, Rebecca M. Smith, Jonathan Gardner, P. W. Turner, Alpha T. N’Diaye, M. B. Holcomb, Ram S. Katiyar, Peng Zhou, Gopalan Srinivasan, J. M. Gregg, J. F. Scott
ABSTRACTWe have studied the atomic force microscopy (AFM), X-ray Bragg reflections, X-ray absorption spectra (XAS) of the Pd L-edge, Scanning electron microscopey (SEM) and Raman spectra, and direct magnetoelectric tensor of Pd-substituted lead titanate and lead zirconate-titanate. A primary aim is to determine the percentage of Pd+4 and Pd+2 substitutional at the Ti-sites (we find that it is almost fully substitutional). The atomic force microscopy data uniquely reveal a surprise: both threefold vertical (polarized out-of-plane) and fourfold in-plane domain vertices. This is discussed in terms of the general rules for Voronoi patterns (Dirichlet tessellations) in two and three dimensions. At high pressures Raman soft modes are observed, as in pure lead titanate, and X-ray diffraction (XRD) indicates a nearly second-order displacive phase transition. However, two or three transitions are involved: First, there are anomalies in c/a ratio and Raman spectra at low pressures (P = 1 - 2 GPa); and second, the c/a ratio reaches unity at ca. P = 10 GPa, where a monoclinic (Mc) but metrically cubic transition occurs from the ambient tetragonal P4 mm structure in pure PbTiO3; whereas the Raman lines (forbidden in the cubic phase) remain until ca. 17 GPa, where a monoclinic-cubic transition is known in lead titanate. More... »
PAGES1685
http://scigraph.springernature.com/pub.10.1038/s41598-018-38411-8
DOIhttp://dx.doi.org/10.1038/s41598-018-38411-8
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1112024931
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/30737467
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Other Physical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Puerto Rico System",
"id": "https://www.grid.ac/institutes/grid.267033.3",
"name": [
"Geophysical Laboratory, Carnegie Institution for Science, 20015, Washington, DC, USA",
"Department of Physics and Institute for Functional Nanomaterials, University of Puerto Rico, 00931, San Juan, PR, USA"
],
"type": "Organization"
},
"familyName": "Pradhan",
"givenName": "Dhiren K.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Geophysical Laboratory",
"id": "https://www.grid.ac/institutes/grid.467206.1",
"name": [
"Geophysical Laboratory, Carnegie Institution for Science, 20015, Washington, DC, USA"
],
"type": "Organization"
},
"familyName": "Mishra",
"givenName": "Ajay K.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "West Virginia University",
"id": "https://www.grid.ac/institutes/grid.268154.c",
"name": [
"Department of Physics and Institute for Functional Nanomaterials, University of Puerto Rico, 00931, San Juan, PR, USA",
"Department of Physics and Astronomy, West Virginia University, 26506, Morgantown, WV, USA"
],
"type": "Organization"
},
"familyName": "Kumari",
"givenName": "Shalini",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Florida State University",
"id": "https://www.grid.ac/institutes/grid.255986.5",
"name": [
"Geophysical Laboratory, Carnegie Institution for Science, 20015, Washington, DC, USA",
"Department of Earth, Ocean & Atmospheric Sciences, Florida State University, 32306, Tallahassee, Florida, USA"
],
"type": "Organization"
},
"familyName": "Basu",
"givenName": "Abhisek",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Geophysical Laboratory",
"id": "https://www.grid.ac/institutes/grid.467206.1",
"name": [
"Geophysical Laboratory, Carnegie Institution for Science, 20015, Washington, DC, USA"
],
"type": "Organization"
},
"familyName": "Somayazulu",
"givenName": "Maddury",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Swiss Federal Institute of Technology in Zurich",
"id": "https://www.grid.ac/institutes/grid.5801.c",
"name": [
"Department of Chemistry and Department of Physics, University of St. Andrews, St, KY16 ST, Andrews, UK",
"Department of Materials, ETH Zurich, Vladimir-Prelog-Weg 4, 8093 Zurich, 8093, Honggerberg, Zurich, Switzerland"
],
"type": "Organization"
},
"familyName": "Gradauskaite",
"givenName": "Elzbieta",
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of St Andrews",
"id": "https://www.grid.ac/institutes/grid.11914.3c",
"name": [
"Department of Chemistry and Department of Physics, University of St. Andrews, St, KY16 ST, Andrews, UK"
],
"type": "Organization"
},
"familyName": "Smith",
"givenName": "Rebecca M.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of St Andrews",
"id": "https://www.grid.ac/institutes/grid.11914.3c",
"name": [
"Department of Chemistry and Department of Physics, University of St. Andrews, St, KY16 ST, Andrews, UK"
],
"type": "Organization"
},
"familyName": "Gardner",
"givenName": "Jonathan",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Queen's University Belfast",
"id": "https://www.grid.ac/institutes/grid.4777.3",
"name": [
"Centre for Nanostructured Media, School of Maths and Physics, Queen\u2019s University of Belfast, BT7 1NN, Belfast, Northern Ireland, UK"
],
"type": "Organization"
},
"familyName": "Turner",
"givenName": "P. W.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Lawrence Berkeley National Laboratory",
"id": "https://www.grid.ac/institutes/grid.184769.5",
"name": [
"NCEM, Molecular Foundry, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA"
],
"type": "Organization"
},
"familyName": "N\u2019Diaye",
"givenName": "Alpha T.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "West Virginia University",
"id": "https://www.grid.ac/institutes/grid.268154.c",
"name": [
"Department of Physics and Astronomy, West Virginia University, 26506, Morgantown, WV, USA"
],
"type": "Organization"
},
"familyName": "Holcomb",
"givenName": "M. B.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Puerto Rico System",
"id": "https://www.grid.ac/institutes/grid.267033.3",
"name": [
"Department of Physics and Institute for Functional Nanomaterials, University of Puerto Rico, 00931, San Juan, PR, USA"
],
"type": "Organization"
},
"familyName": "Katiyar",
"givenName": "Ram S.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Oakland University",
"id": "https://www.grid.ac/institutes/grid.261277.7",
"name": [
"Department of Physics, Oakland University, 48309-4479, Rochester, MI, USA"
],
"type": "Organization"
},
"familyName": "Zhou",
"givenName": "Peng",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Oakland University",
"id": "https://www.grid.ac/institutes/grid.261277.7",
"name": [
"Department of Physics, Oakland University, 48309-4479, Rochester, MI, USA"
],
"type": "Organization"
},
"familyName": "Srinivasan",
"givenName": "Gopalan",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Queen's University Belfast",
"id": "https://www.grid.ac/institutes/grid.4777.3",
"name": [
"Centre for Nanostructured Media, School of Maths and Physics, Queen\u2019s University of Belfast, BT7 1NN, Belfast, Northern Ireland, UK"
],
"type": "Organization"
},
"familyName": "Gregg",
"givenName": "J. M.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of St Andrews",
"id": "https://www.grid.ac/institutes/grid.11914.3c",
"name": [
"Department of Chemistry and Department of Physics, University of St. Andrews, St, KY16 ST, Andrews, UK"
],
"type": "Organization"
},
"familyName": "Scott",
"givenName": "J. F.",
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/s1359-0286(01)00035-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000475207"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physreve.87.032151",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000542267"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physreve.87.032151",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000542267"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1088/0953-8984/7/22/013",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002777263"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1166/jnn.2014.9013",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1003187902"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c2ee22547f",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007387107"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.cattod.2006.05.029",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007968130"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature00893",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008217990",
"https://doi.org/10.1038/nature00893"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature00893",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008217990",
"https://doi.org/10.1038/nature00893"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.solidstatesciences.2004.10.002",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008992876"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ssi.2016.09.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009003606"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ssi.2016.09.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009003606"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ssi.2016.09.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009003606"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10562-015-1518-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015605248",
"https://doi.org/10.1007/s10562-015-1518-3"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10562-015-1518-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015605248",
"https://doi.org/10.1007/s10562-015-1518-3"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.2478/s11534-010-0094-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1016922450",
"https://doi.org/10.2478/s11534-010-0094-9"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.3103/s1068375512010048",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018635049",
"https://doi.org/10.3103/s1068375512010048"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.95.037601",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019086968"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.95.037601",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019086968"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.95.037601",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019086968"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.chemmater.5b00450",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019546905"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1088/1751-8113/46/9/095001",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021834619"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature06459",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023788845",
"https://doi.org/10.1038/nature06459"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1088/0953-8984/19/24/242202",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024879045"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1111/j.1365-2818.1988.tb01417.x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025068382"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature16463",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025917106",
"https://doi.org/10.1038/nature16463"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0567739476001551",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1028010813"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1080/00107518408210979",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045363769"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s11434-016-1194-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045739356",
"https://doi.org/10.1007/s11434-016-1194-8"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s11434-016-1194-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045739356",
"https://doi.org/10.1007/s11434-016-1194-8"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.4935481",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048762247"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1111/j.1151-2916.1996.tb07907.x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051827986"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c5ra24107c",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053639792"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0022-4596(02)99653-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054590472"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0022-4596(02)99653-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054590472"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.jpclett.5b02292",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055114118"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cm300571y",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055414829"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja8052249",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055859131"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja8052249",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055859131"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1347383",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057697335"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1088/0022-3719/7/20/002",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1058967295"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrev.64.178",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060452269"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrev.64.178",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060452269"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.34.1815",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060540644"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.34.1815",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060540644"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.37.2074",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060545127"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.37.2074",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060545127"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.7.3088",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060610250"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.7.3088",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060610250"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.75.224115",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060621285"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.75.224115",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060621285"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.101.237601",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060754475"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.101.237601",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060754475"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.25.167",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060773869"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.25.167",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060773869"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.nanolett.6b04875",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1084123989"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.95.064111",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1084197807"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.95.064111",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1084197807"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c7cp01347g",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1086072603"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1142/9781848167513_0003",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1088751428"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/ncomms15967",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1090279209",
"https://doi.org/10.1038/ncomms15967"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.96.104104",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1091638971"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.96.104104",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1091638971"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nphys4293",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1092061643",
"https://doi.org/10.1038/nphys4293"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nphys4293",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1092061643",
"https://doi.org/10.1038/nphys4293"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.cattod.2017.11.007",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1092636097"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.iecr.7b04399",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1099747774"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.jelechem.2018.03.040",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1101698407"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.jelechem.2018.03.040",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1101698407"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.95.214109",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1102596140"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.95.214109",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1102596140"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1149/2.0221809jes",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1104332680"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.aan2433",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1105982076"
],
"type": "CreativeWork"
}
],
"datePublished": "2019-12",
"datePublishedReg": "2019-12-01",
"description": "We have studied the atomic force microscopy (AFM), X-ray Bragg reflections, X-ray absorption spectra (XAS) of the Pd L-edge, Scanning electron microscopey (SEM) and Raman spectra, and direct magnetoelectric tensor of Pd-substituted lead titanate and lead zirconate-titanate. A primary aim is to determine the percentage of Pd+4 and Pd+2 substitutional at the Ti-sites (we find that it is almost fully substitutional). The atomic force microscopy data uniquely reveal a surprise: both threefold vertical (polarized out-of-plane) and fourfold in-plane domain vertices. This is discussed in terms of the general rules for Voronoi patterns (Dirichlet tessellations) in two and three dimensions. At high pressures Raman soft modes are observed, as in pure lead titanate, and X-ray diffraction (XRD) indicates a nearly second-order displacive phase transition. However, two or three transitions are involved: First, there are anomalies in c/a ratio and Raman spectra at low pressures (P\u2009=\u20091\u2009-\u20092\u2009GPa); and second, the c/a ratio reaches unity at ca. P\u2009=\u200910\u2009GPa, where a monoclinic (Mc) but metrically cubic transition occurs from the ambient tetragonal P4\u2009mm structure in pure PbTiO3; whereas the Raman lines (forbidden in the cubic phase) remain until ca. 17\u2009GPa, where a monoclinic-cubic transition is known in lead titanate.",
"genre": "research_article",
"id": "sg:pub.10.1038/s41598-018-38411-8",
"inLanguage": [
"en"
],
"isAccessibleForFree": true,
"isFundedItemOf": [
{
"id": "sg:grant.4843188",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.4396342",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.2781074",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.6620142",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.5509558",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1045337",
"issn": [
"2045-2322"
],
"name": "Scientific Reports",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "9"
}
],
"name": "Studies of Multiferroic Palladium Perovskites",
"pagination": "1685",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"cdf50e2f85e345a485667485e10be18d375720f5f63adb46ba2159db71ff01c2"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"30737467"
]
},
{
"name": "nlm_unique_id",
"type": "PropertyValue",
"value": [
"101563288"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1038/s41598-018-38411-8"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1112024931"
]
}
],
"sameAs": [
"https://doi.org/10.1038/s41598-018-38411-8",
"https://app.dimensions.ai/details/publication/pub.1112024931"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-11T09:05",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000336_0000000336/records_94788_00000000.jsonl",
"type": "ScholarlyArticle",
"url": "https://www.nature.com/articles/s41598-018-38411-8"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41598-018-38411-8'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41598-018-38411-8'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41598-018-38411-8'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41598-018-38411-8'
This table displays all metadata directly associated to this object as RDF triples.
357 TRIPLES
21 PREDICATES
80 URIs
21 LITERALS
9 BLANK NODES