AEO7 Surfactant as an Eco-Friendly Corrosion Inhibitor for Carbon Steel in HCl solution View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Mostafa H. Sliem, Mohammed Afifi, A. Bahgat Radwan, Eman M. Fayyad, Mohamed F. Shibl, Fakiha El-Taib Heakal, Aboubakr M. Abdullah

ABSTRACT

The impact of AEO7 surfactant on the corrosion inhibition of carbon steel (C-steel) in 0.5 M HCl solution at temperatures between 20 °C and 50 °C was elucidated using weight loss and different electrochemical techniques. The kinetics and thermodynamic parameters of the corrosion and inhibition processes were reported. The corrosion inhibition efficiency (IE%) improved as the concentration of AEO7 increased. In addition, a synergistic effect was observed when a concentration of 1 × 10-3 mol L-1 or higher of potassium iodide (KI) was added to 40 µmol L-1 of the AEO7 inhibitor where the corrosion IE% increased from 87.4% to 99.2%. Also, it was found that the adsorption of AEO7 surfactant on C-steel surface followed the Freundlich isotherm. Furthermore, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements indicated that AEO7 was physically adsorbed on the steel surface. The surface topography was examined using an optical profilometer, an atomic force microscope (AFM), and a scanning electron-microscope (SEM) coupled with an energy dispersion X-ray (EDX) unit. Quantum chemical calculations based on the density functional theory were performed to understand the relationship between the corrosion IE% and the molecular structure of the AEO7 molecule. More... »

PAGES

2319

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41598-018-37254-7

DOI

http://dx.doi.org/10.1038/s41598-018-37254-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112221684

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30783184


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