“Green” Aqueous Synthesis and Advanced Spectral Characterization of Size-Selected Cu2ZnSnS4 Nanocrystal Inks View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2018-09-12

AUTHORS

Oleksandr Stroyuk, Alexandra Raevskaya, Oleksandr Selyshchev, Volodymyr Dzhagan, Nikolai Gaponik, Dietrich R. T. Zahn, Alexander Eychmüller

ABSTRACT

Structure, composition, and optical properties of colloidal mercaptoacetate-stabilized Cu2ZnSnS4 (CZTS) nanocrystal inks produced by a “green” method directly in aqueous solutions were characterized. A size-selective precipitation procedure using 2-propanol as a non-solvent allows separating a series of fractions of CZTS nanocrystals with an average size (bandgap) varying from 3 nm (1.72 eV) to 2 nm (2.04 eV). The size-selected CZTS nanocrystals revealed also phonon confinement, with the main phonon mode frequency varying by about 4 cm−1 between 2 nm and 3 nm NCs. More... »

PAGES

13677

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41598-018-32004-1

DOI

http://dx.doi.org/10.1038/s41598-018-32004-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106837399

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30209288


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