Synthesis of metal-doped nanoplastics and their utility to investigate fate and behaviour in complex environmental systems View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-04

AUTHORS

Denise M. Mitrano, Anna Beltzung, Stefan Frehland, Michael Schmiedgruber, Alberto Cingolani, Felix Schmidt

ABSTRACT

Research on the distribution and effects of particulate plastic has intensified in recent years and yet, due to analytical challenges, our understanding of nanoplastic occurrence and behaviour has remained comparatively elusive. However, process studies could greatly aid in defining key parameters for nanoplastic interactions within and transfers between technical and environmental compartments. Here we provide a method to synthesize nanoplastic particles doped with a chemically entrapped metal used as a tracer, which provides a robust way to detect nanoplastics more easily, accurately and quantitatively in complex media. We show the utility of this approach in batch studies that simulate the activated sludge process of a municipal waste water treatment plant and so better understand the fate of nanoplastics in urban environments. We found that the majority of particles were associated with the sludge (>98%), with an average recovery of over 93% of the spiked material achieved. We believe that this approach can be developed further to study the fate, transport, mechanistic behaviour and biological uptake of nanoplastics in a variety of systems on different scales. More... »

PAGES

1-7

References to SciGraph publications

  • 2015. Nanoplastics in the Aquatic Environment. Critical Review in MARINE ANTHROPOGENIC LITTER
  • 2015-03. Fabric Softener Technology: A Review in JOURNAL OF SURFACTANTS AND DETERGENTS
  • 2017-11. Asymmetrical flow field flow fractionation methods to characterize submicron particles: application to carbon-based aggregates and nanoplastics in ANALYTICAL AND BIOANALYTICAL CHEMISTRY
  • 2006. Biological Effects of Palladium in PALLADIUM EMISSIONS IN THE ENVIRONMENT
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/s41565-018-0360-3

    DOI

    http://dx.doi.org/10.1038/s41565-018-0360-3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1111917223

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/30718833


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0907", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Environmental Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "name": [
                "Process Engineering, Eawag \u2014 Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Mitrano", 
            "givenName": "Denise M.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Swiss Federal Institute of Technology in Zurich", 
              "id": "https://www.grid.ac/institutes/grid.5801.c", 
              "name": [
                "Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zurich, Zurich, Switzerland"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Beltzung", 
            "givenName": "Anna", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Process Engineering, Eawag \u2014 Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Frehland", 
            "givenName": "Stefan", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Process Engineering, Eawag \u2014 Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Schmiedgruber", 
            "givenName": "Michael", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Swiss Federal Institute of Technology in Zurich", 
              "id": "https://www.grid.ac/institutes/grid.5801.c", 
              "name": [
                "Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zurich, Zurich, Switzerland"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Cingolani", 
            "givenName": "Alberto", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Process Engineering, Eawag \u2014 Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Schmidt", 
            "givenName": "Felix", 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/j.chemosphere.2015.11.078", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1002173840"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c1em10017c", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1003655782"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/0471440264.pst011", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004288667"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es504525u", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006479184"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.envpol.2016.10.001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006511759"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b821363a", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010984960"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b821363a", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010984960"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/app.44764", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012684092"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.progpolymsci.2009.12.001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013690516"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.nbt.2014.09.001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015883326"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.nbt.2014.09.001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015883326"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-319-16510-3_12", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024677986", 
              "https://doi.org/10.1007/978-3-319-16510-3_12"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.watres.2016.01.002", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027591503"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.watres.2016.01.002", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027591503"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.envpol.2015.03.035", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028698557"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11743-014-1658-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028845040", 
              "https://doi.org/10.1007/s11743-014-1658-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c6ay02558g", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035646390"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.marpolbul.2014.06.032", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038220160"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.marpolbul.2014.06.032", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038220160"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c6en00008h", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039199453"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/3-540-29220-9_31", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039997020", 
              "https://doi.org/10.1007/3-540-29220-9_31"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0079-6700(02)00066-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040705002"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0079-6700(02)00066-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040705002"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.marpolbul.2013.10.007", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045256560"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/etc.3076", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048100653"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.scitotenv.2016.05.041", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048869934"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.5b03909", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055088249"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.5b05416", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055088571"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es1041892", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055502689"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es1041892", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055502689"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es2031505", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055503744"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es501757s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055507962"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es503610r", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055508378"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es903784e", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055517393"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/es903784e", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055517393"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ez5003506", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055523227"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja203080p", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055849936"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja203080p", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055849936"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/la702227d", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1056161603"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/la702227d", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1056161603"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1089/ees.2013.0472", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1059254818"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.chemosphere.2017.02.010", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1083527861"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.6b05702", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1083533445"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c7cp00080d", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1085582027"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.envpol.2017.05.048", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1085592917"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.envpol.2017.05.048", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1085592917"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsami.7b06569", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1086385554"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.7b01731", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1090392452"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00216-017-0629-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1091915874", 
              "https://doi.org/10.1007/s00216-017-0629-7"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.7b02219", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1092068958"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.7b04612", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1092249630"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3390/ijerph14101265", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1092311229"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.7b03667", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1092866088"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.est.7b05559", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1099740088"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.envpol.2018.01.024", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1100470591"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c7en01119a", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1100894571"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/09644016.2018.1449090", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101512917"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.watres.2018.03.051", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101747674"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.watres.2018.03.051", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101747674"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.polymer.2018.04.065", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1103656248"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/b978-0-12-813747-5.00013-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1104238477"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c8en00186c", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1104260273"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2019-04", 
        "datePublishedReg": "2019-04-01", 
        "description": "Research on the distribution and effects of particulate plastic has intensified in recent years and yet, due to analytical challenges, our understanding of nanoplastic occurrence and behaviour has remained comparatively elusive. However, process studies could greatly aid in defining key parameters for nanoplastic interactions within and transfers between technical and environmental compartments. Here we provide a method to synthesize nanoplastic particles doped with a chemically entrapped metal used as a tracer, which provides a robust way to detect nanoplastics more easily, accurately and quantitatively in complex media. We show the utility of this approach in batch studies that simulate the activated sludge process of a municipal waste water treatment plant and so better understand the fate of nanoplastics in urban environments. We found that the majority of particles were associated with the sludge (>98%), with an average recovery of over 93% of the spiked material achieved. We believe that this approach can be developed further to study the fate, transport, mechanistic behaviour and biological uptake of nanoplastics in a variety of systems on different scales.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1038/s41565-018-0360-3", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1037429", 
            "issn": [
              "1748-3387", 
              "1748-3395"
            ], 
            "name": "Nature Nanotechnology", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "4", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "14"
          }
        ], 
        "name": "Synthesis of metal-doped nanoplastics and their utility to investigate fate and behaviour in complex environmental systems", 
        "pagination": "1-7", 
        "productId": [
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1038/s41565-018-0360-3"
            ]
          }, 
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "d5b8672814378d7d4755388b4ff5e448ef440bcf1720996ed59039bd2d1f6827"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1111917223"
            ]
          }, 
          {
            "name": "nlm_unique_id", 
            "type": "PropertyValue", 
            "value": [
              "101283273"
            ]
          }, 
          {
            "name": "pubmed_id", 
            "type": "PropertyValue", 
            "value": [
              "30718833"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1038/s41565-018-0360-3", 
          "https://app.dimensions.ai/details/publication/pub.1111917223"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-15T08:51", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000374_0000000374/records_119738_00000001.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://www.nature.com/articles/s41565-018-0360-3"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41565-018-0360-3'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41565-018-0360-3'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41565-018-0360-3'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41565-018-0360-3'


     

    This table displays all metadata directly associated to this object as RDF triples.

    263 TRIPLES      21 PREDICATES      80 URIs      21 LITERALS      9 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1038/s41565-018-0360-3 schema:about anzsrc-for:09
    2 anzsrc-for:0907
    3 schema:author Ndc96d535fb954659a8f41f473fcaeb53
    4 schema:citation sg:pub.10.1007/3-540-29220-9_31
    5 sg:pub.10.1007/978-3-319-16510-3_12
    6 sg:pub.10.1007/s00216-017-0629-7
    7 sg:pub.10.1007/s11743-014-1658-2
    8 https://doi.org/10.1002/0471440264.pst011
    9 https://doi.org/10.1002/app.44764
    10 https://doi.org/10.1002/etc.3076
    11 https://doi.org/10.1016/b978-0-12-813747-5.00013-8
    12 https://doi.org/10.1016/j.chemosphere.2015.11.078
    13 https://doi.org/10.1016/j.chemosphere.2017.02.010
    14 https://doi.org/10.1016/j.envpol.2015.03.035
    15 https://doi.org/10.1016/j.envpol.2016.10.001
    16 https://doi.org/10.1016/j.envpol.2017.05.048
    17 https://doi.org/10.1016/j.envpol.2018.01.024
    18 https://doi.org/10.1016/j.marpolbul.2013.10.007
    19 https://doi.org/10.1016/j.marpolbul.2014.06.032
    20 https://doi.org/10.1016/j.nbt.2014.09.001
    21 https://doi.org/10.1016/j.polymer.2018.04.065
    22 https://doi.org/10.1016/j.progpolymsci.2009.12.001
    23 https://doi.org/10.1016/j.scitotenv.2016.05.041
    24 https://doi.org/10.1016/j.watres.2016.01.002
    25 https://doi.org/10.1016/j.watres.2018.03.051
    26 https://doi.org/10.1016/s0079-6700(02)00066-7
    27 https://doi.org/10.1021/acs.est.5b03909
    28 https://doi.org/10.1021/acs.est.5b05416
    29 https://doi.org/10.1021/acs.est.6b05702
    30 https://doi.org/10.1021/acs.est.7b01731
    31 https://doi.org/10.1021/acs.est.7b02219
    32 https://doi.org/10.1021/acs.est.7b03667
    33 https://doi.org/10.1021/acs.est.7b04612
    34 https://doi.org/10.1021/acs.est.7b05559
    35 https://doi.org/10.1021/acsami.7b06569
    36 https://doi.org/10.1021/es1041892
    37 https://doi.org/10.1021/es2031505
    38 https://doi.org/10.1021/es501757s
    39 https://doi.org/10.1021/es503610r
    40 https://doi.org/10.1021/es504525u
    41 https://doi.org/10.1021/es903784e
    42 https://doi.org/10.1021/ez5003506
    43 https://doi.org/10.1021/ja203080p
    44 https://doi.org/10.1021/la702227d
    45 https://doi.org/10.1039/b821363a
    46 https://doi.org/10.1039/c1em10017c
    47 https://doi.org/10.1039/c6ay02558g
    48 https://doi.org/10.1039/c6en00008h
    49 https://doi.org/10.1039/c7cp00080d
    50 https://doi.org/10.1039/c7en01119a
    51 https://doi.org/10.1039/c8en00186c
    52 https://doi.org/10.1080/09644016.2018.1449090
    53 https://doi.org/10.1089/ees.2013.0472
    54 https://doi.org/10.3390/ijerph14101265
    55 schema:datePublished 2019-04
    56 schema:datePublishedReg 2019-04-01
    57 schema:description Research on the distribution and effects of particulate plastic has intensified in recent years and yet, due to analytical challenges, our understanding of nanoplastic occurrence and behaviour has remained comparatively elusive. However, process studies could greatly aid in defining key parameters for nanoplastic interactions within and transfers between technical and environmental compartments. Here we provide a method to synthesize nanoplastic particles doped with a chemically entrapped metal used as a tracer, which provides a robust way to detect nanoplastics more easily, accurately and quantitatively in complex media. We show the utility of this approach in batch studies that simulate the activated sludge process of a municipal waste water treatment plant and so better understand the fate of nanoplastics in urban environments. We found that the majority of particles were associated with the sludge (>98%), with an average recovery of over 93% of the spiked material achieved. We believe that this approach can be developed further to study the fate, transport, mechanistic behaviour and biological uptake of nanoplastics in a variety of systems on different scales.
    58 schema:genre research_article
    59 schema:inLanguage en
    60 schema:isAccessibleForFree false
    61 schema:isPartOf Nd99d3c4f8ecd45aabf874c755152ae33
    62 Nde8c8481d2df4bda8d673963508f4069
    63 sg:journal.1037429
    64 schema:name Synthesis of metal-doped nanoplastics and their utility to investigate fate and behaviour in complex environmental systems
    65 schema:pagination 1-7
    66 schema:productId N63d1f3088b224e3c806e03c6c7ef3626
    67 N7f896016ec994f8094a206417b913c47
    68 Nac264213e91246f496f1fdccdc098a21
    69 Nc0452df7f771465aa51a7000d63b65d9
    70 Nd611b49eb21b4e7f9574fa032f1851f0
    71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1111917223
    72 https://doi.org/10.1038/s41565-018-0360-3
    73 schema:sdDatePublished 2019-04-15T08:51
    74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    75 schema:sdPublisher Nb877ed5c4b884353b19def0ea0046300
    76 schema:url https://www.nature.com/articles/s41565-018-0360-3
    77 sgo:license sg:explorer/license/
    78 sgo:sdDataset articles
    79 rdf:type schema:ScholarlyArticle
    80 N02a244096638404bb8ee6d5100ae3682 rdf:first Nfeadfa579f674647a282e5de766faf32
    81 rdf:rest rdf:nil
    82 N0ad97b993bc944c3a2a1c4d1440e036b schema:name Process Engineering, Eawag — Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland
    83 rdf:type schema:Organization
    84 N0f5a21eb54ed4499a76f46bb31862caf schema:affiliation N64a03885e609459fb7ac9a1138fa4b6b
    85 schema:familyName Schmiedgruber
    86 schema:givenName Michael
    87 rdf:type schema:Person
    88 N58bff37e73894d75b9ef9235eb616301 schema:affiliation N681e6cf08fdb402e8ccf859ffb7992c0
    89 schema:familyName Frehland
    90 schema:givenName Stefan
    91 rdf:type schema:Person
    92 N62dbdc4797af413eae70ceaa75ae0c3b schema:affiliation N6ab806aa74c64f5da85da2b2fa325641
    93 schema:familyName Mitrano
    94 schema:givenName Denise M.
    95 rdf:type schema:Person
    96 N63d1f3088b224e3c806e03c6c7ef3626 schema:name doi
    97 schema:value 10.1038/s41565-018-0360-3
    98 rdf:type schema:PropertyValue
    99 N648c9bbb8b2d4ff6a78231145bfc3f16 rdf:first N977a43bbd2dc4cdc93d1de51a4d9a9a0
    100 rdf:rest N02a244096638404bb8ee6d5100ae3682
    101 N64a03885e609459fb7ac9a1138fa4b6b schema:name Process Engineering, Eawag — Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland
    102 rdf:type schema:Organization
    103 N681e6cf08fdb402e8ccf859ffb7992c0 schema:name Process Engineering, Eawag — Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland
    104 rdf:type schema:Organization
    105 N6ab806aa74c64f5da85da2b2fa325641 schema:name Process Engineering, Eawag — Swiss Federal Institute of Aquatic Science and Technology, Process Engineering, Dubendorf, Switzerland
    106 rdf:type schema:Organization
    107 N7f896016ec994f8094a206417b913c47 schema:name pubmed_id
    108 schema:value 30718833
    109 rdf:type schema:PropertyValue
    110 N80a862a922894fc28eafa45ab2c22985 rdf:first Nd011bb2287ee43fe8bb2604150b98c77
    111 rdf:rest N88cadc3ab3274061b2a347a97bd38f6a
    112 N88cadc3ab3274061b2a347a97bd38f6a rdf:first N58bff37e73894d75b9ef9235eb616301
    113 rdf:rest Na3e747830a4e48d58c2e916e521cbc3f
    114 N977a43bbd2dc4cdc93d1de51a4d9a9a0 schema:affiliation https://www.grid.ac/institutes/grid.5801.c
    115 schema:familyName Cingolani
    116 schema:givenName Alberto
    117 rdf:type schema:Person
    118 Na3e747830a4e48d58c2e916e521cbc3f rdf:first N0f5a21eb54ed4499a76f46bb31862caf
    119 rdf:rest N648c9bbb8b2d4ff6a78231145bfc3f16
    120 Nac264213e91246f496f1fdccdc098a21 schema:name nlm_unique_id
    121 schema:value 101283273
    122 rdf:type schema:PropertyValue
    123 Nb877ed5c4b884353b19def0ea0046300 schema:name Springer Nature - SN SciGraph project
    124 rdf:type schema:Organization
    125 Nc0452df7f771465aa51a7000d63b65d9 schema:name readcube_id
    126 schema:value d5b8672814378d7d4755388b4ff5e448ef440bcf1720996ed59039bd2d1f6827
    127 rdf:type schema:PropertyValue
    128 Nd011bb2287ee43fe8bb2604150b98c77 schema:affiliation https://www.grid.ac/institutes/grid.5801.c
    129 schema:familyName Beltzung
    130 schema:givenName Anna
    131 rdf:type schema:Person
    132 Nd611b49eb21b4e7f9574fa032f1851f0 schema:name dimensions_id
    133 schema:value pub.1111917223
    134 rdf:type schema:PropertyValue
    135 Nd99d3c4f8ecd45aabf874c755152ae33 schema:issueNumber 4
    136 rdf:type schema:PublicationIssue
    137 Ndc96d535fb954659a8f41f473fcaeb53 rdf:first N62dbdc4797af413eae70ceaa75ae0c3b
    138 rdf:rest N80a862a922894fc28eafa45ab2c22985
    139 Nde8c8481d2df4bda8d673963508f4069 schema:volumeNumber 14
    140 rdf:type schema:PublicationVolume
    141 Nfeadfa579f674647a282e5de766faf32 schema:affiliation N0ad97b993bc944c3a2a1c4d1440e036b
    142 schema:familyName Schmidt
    143 schema:givenName Felix
    144 rdf:type schema:Person
    145 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    146 schema:name Engineering
    147 rdf:type schema:DefinedTerm
    148 anzsrc-for:0907 schema:inDefinedTermSet anzsrc-for:
    149 schema:name Environmental Engineering
    150 rdf:type schema:DefinedTerm
    151 sg:journal.1037429 schema:issn 1748-3387
    152 1748-3395
    153 schema:name Nature Nanotechnology
    154 rdf:type schema:Periodical
    155 sg:pub.10.1007/3-540-29220-9_31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039997020
    156 https://doi.org/10.1007/3-540-29220-9_31
    157 rdf:type schema:CreativeWork
    158 sg:pub.10.1007/978-3-319-16510-3_12 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024677986
    159 https://doi.org/10.1007/978-3-319-16510-3_12
    160 rdf:type schema:CreativeWork
    161 sg:pub.10.1007/s00216-017-0629-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091915874
    162 https://doi.org/10.1007/s00216-017-0629-7
    163 rdf:type schema:CreativeWork
    164 sg:pub.10.1007/s11743-014-1658-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028845040
    165 https://doi.org/10.1007/s11743-014-1658-2
    166 rdf:type schema:CreativeWork
    167 https://doi.org/10.1002/0471440264.pst011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004288667
    168 rdf:type schema:CreativeWork
    169 https://doi.org/10.1002/app.44764 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012684092
    170 rdf:type schema:CreativeWork
    171 https://doi.org/10.1002/etc.3076 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048100653
    172 rdf:type schema:CreativeWork
    173 https://doi.org/10.1016/b978-0-12-813747-5.00013-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104238477
    174 rdf:type schema:CreativeWork
    175 https://doi.org/10.1016/j.chemosphere.2015.11.078 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002173840
    176 rdf:type schema:CreativeWork
    177 https://doi.org/10.1016/j.chemosphere.2017.02.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083527861
    178 rdf:type schema:CreativeWork
    179 https://doi.org/10.1016/j.envpol.2015.03.035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028698557
    180 rdf:type schema:CreativeWork
    181 https://doi.org/10.1016/j.envpol.2016.10.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006511759
    182 rdf:type schema:CreativeWork
    183 https://doi.org/10.1016/j.envpol.2017.05.048 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085592917
    184 rdf:type schema:CreativeWork
    185 https://doi.org/10.1016/j.envpol.2018.01.024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100470591
    186 rdf:type schema:CreativeWork
    187 https://doi.org/10.1016/j.marpolbul.2013.10.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045256560
    188 rdf:type schema:CreativeWork
    189 https://doi.org/10.1016/j.marpolbul.2014.06.032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038220160
    190 rdf:type schema:CreativeWork
    191 https://doi.org/10.1016/j.nbt.2014.09.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015883326
    192 rdf:type schema:CreativeWork
    193 https://doi.org/10.1016/j.polymer.2018.04.065 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103656248
    194 rdf:type schema:CreativeWork
    195 https://doi.org/10.1016/j.progpolymsci.2009.12.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013690516
    196 rdf:type schema:CreativeWork
    197 https://doi.org/10.1016/j.scitotenv.2016.05.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048869934
    198 rdf:type schema:CreativeWork
    199 https://doi.org/10.1016/j.watres.2016.01.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027591503
    200 rdf:type schema:CreativeWork
    201 https://doi.org/10.1016/j.watres.2018.03.051 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101747674
    202 rdf:type schema:CreativeWork
    203 https://doi.org/10.1016/s0079-6700(02)00066-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040705002
    204 rdf:type schema:CreativeWork
    205 https://doi.org/10.1021/acs.est.5b03909 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055088249
    206 rdf:type schema:CreativeWork
    207 https://doi.org/10.1021/acs.est.5b05416 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055088571
    208 rdf:type schema:CreativeWork
    209 https://doi.org/10.1021/acs.est.6b05702 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083533445
    210 rdf:type schema:CreativeWork
    211 https://doi.org/10.1021/acs.est.7b01731 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090392452
    212 rdf:type schema:CreativeWork
    213 https://doi.org/10.1021/acs.est.7b02219 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092068958
    214 rdf:type schema:CreativeWork
    215 https://doi.org/10.1021/acs.est.7b03667 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092866088
    216 rdf:type schema:CreativeWork
    217 https://doi.org/10.1021/acs.est.7b04612 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092249630
    218 rdf:type schema:CreativeWork
    219 https://doi.org/10.1021/acs.est.7b05559 schema:sameAs https://app.dimensions.ai/details/publication/pub.1099740088
    220 rdf:type schema:CreativeWork
    221 https://doi.org/10.1021/acsami.7b06569 schema:sameAs https://app.dimensions.ai/details/publication/pub.1086385554
    222 rdf:type schema:CreativeWork
    223 https://doi.org/10.1021/es1041892 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055502689
    224 rdf:type schema:CreativeWork
    225 https://doi.org/10.1021/es2031505 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055503744
    226 rdf:type schema:CreativeWork
    227 https://doi.org/10.1021/es501757s schema:sameAs https://app.dimensions.ai/details/publication/pub.1055507962
    228 rdf:type schema:CreativeWork
    229 https://doi.org/10.1021/es503610r schema:sameAs https://app.dimensions.ai/details/publication/pub.1055508378
    230 rdf:type schema:CreativeWork
    231 https://doi.org/10.1021/es504525u schema:sameAs https://app.dimensions.ai/details/publication/pub.1006479184
    232 rdf:type schema:CreativeWork
    233 https://doi.org/10.1021/es903784e schema:sameAs https://app.dimensions.ai/details/publication/pub.1055517393
    234 rdf:type schema:CreativeWork
    235 https://doi.org/10.1021/ez5003506 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055523227
    236 rdf:type schema:CreativeWork
    237 https://doi.org/10.1021/ja203080p schema:sameAs https://app.dimensions.ai/details/publication/pub.1055849936
    238 rdf:type schema:CreativeWork
    239 https://doi.org/10.1021/la702227d schema:sameAs https://app.dimensions.ai/details/publication/pub.1056161603
    240 rdf:type schema:CreativeWork
    241 https://doi.org/10.1039/b821363a schema:sameAs https://app.dimensions.ai/details/publication/pub.1010984960
    242 rdf:type schema:CreativeWork
    243 https://doi.org/10.1039/c1em10017c schema:sameAs https://app.dimensions.ai/details/publication/pub.1003655782
    244 rdf:type schema:CreativeWork
    245 https://doi.org/10.1039/c6ay02558g schema:sameAs https://app.dimensions.ai/details/publication/pub.1035646390
    246 rdf:type schema:CreativeWork
    247 https://doi.org/10.1039/c6en00008h schema:sameAs https://app.dimensions.ai/details/publication/pub.1039199453
    248 rdf:type schema:CreativeWork
    249 https://doi.org/10.1039/c7cp00080d schema:sameAs https://app.dimensions.ai/details/publication/pub.1085582027
    250 rdf:type schema:CreativeWork
    251 https://doi.org/10.1039/c7en01119a schema:sameAs https://app.dimensions.ai/details/publication/pub.1100894571
    252 rdf:type schema:CreativeWork
    253 https://doi.org/10.1039/c8en00186c schema:sameAs https://app.dimensions.ai/details/publication/pub.1104260273
    254 rdf:type schema:CreativeWork
    255 https://doi.org/10.1080/09644016.2018.1449090 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101512917
    256 rdf:type schema:CreativeWork
    257 https://doi.org/10.1089/ees.2013.0472 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059254818
    258 rdf:type schema:CreativeWork
    259 https://doi.org/10.3390/ijerph14101265 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092311229
    260 rdf:type schema:CreativeWork
    261 https://www.grid.ac/institutes/grid.5801.c schema:alternateName Swiss Federal Institute of Technology in Zurich
    262 schema:name Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zurich, Zurich, Switzerland
    263 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...