Quantitative production of butenes from biomass-derived γ-valerolactone catalysed by hetero-atomic MFI zeolite View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12-16

AUTHORS

Longfei Lin, Alena M. Sheveleva, Ivan da Silva, Christopher M. A. Parlett, Zhimou Tang, Yueming Liu, Mengtian Fan, Xue Han, Joseph H. Carter, Floriana Tuna, Eric J. L. McInnes, Yongqiang Cheng, Luke L. Daemen, Svemir Rudić, Anibal J. Ramirez-Cuesta, Chiu C. Tang, Sihai Yang

ABSTRACT

The efficient production of light olefins from renewable biomass is a vital and challenging target to achieve future sustainable chemical processes. Here we report a hetero-atomic MFI-type zeolite (NbAlS-1), over which aqueous solutions of γ-valerolactone (GVL), obtained from biomass-derived carbohydrates, can be quantitatively converted into butenes with a yield of >99% at ambient pressure under continuous flow conditions. NbAlS-1 incorporates simultaneously niobium(v) and aluminium(iii) centres into the framework and thus has a desirable distribution of Lewis and Brønsted acid sites with optimal strength. Synchrotron X-ray diffraction and absorption spectroscopy show that there is cooperativity between Nb(v) and the Brønsted acid sites on the confined adsorption of GVL, whereas the catalytic mechanism for the conversion of the confined GVL into butenes is revealed by in situ inelastic neutron scattering, coupled with modelling. This study offers a prospect for the sustainable production of butene as a platform chemical for the manufacture of renewable materials. More... »

PAGES

86-93

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41563-019-0562-6

DOI

http://dx.doi.org/10.1038/s41563-019-0562-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1123433771

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/31844281


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22 schema:description The efficient production of light olefins from renewable biomass is a vital and challenging target to achieve future sustainable chemical processes. Here we report a hetero-atomic MFI-type zeolite (NbAlS-1), over which aqueous solutions of γ-valerolactone (GVL), obtained from biomass-derived carbohydrates, can be quantitatively converted into butenes with a yield of >99% at ambient pressure under continuous flow conditions. NbAlS-1 incorporates simultaneously niobium(v) and aluminium(iii) centres into the framework and thus has a desirable distribution of Lewis and Brønsted acid sites with optimal strength. Synchrotron X-ray diffraction and absorption spectroscopy show that there is cooperativity between Nb(v) and the Brønsted acid sites on the confined adsorption of GVL, whereas the catalytic mechanism for the conversion of the confined GVL into butenes is revealed by in situ inelastic neutron scattering, coupled with modelling. This study offers a prospect for the sustainable production of butene as a platform chemical for the manufacture of renewable materials.
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30 GVL
31 Lewis
32 MFI zeolites
33 MFI-type zeolites
34 absorption spectroscopy
35 acid sites
36 adsorption
37 ambient pressure
38 aqueous solution
39 biomass
40 biomass-derived carbohydrates
41 butene
42 carbohydrates
43 catalytic mechanism
44 challenging target
45 chemical processes
46 chemicals
47 conditions
48 continuous flow conditions
49 conversion
50 cooperativity
51 desirable distribution
52 diffraction
53 distribution
54 efficient production
55 flow conditions
56 framework
57 inelastic neutron scattering
58 light olefins
59 manufacture
60 materials
61 mechanism
62 modelling
63 neutron scattering
64 olefins
65 optimal strength
66 platform chemicals
67 pressure
68 process
69 production
70 prospects
71 quantitative production
72 ray diffraction
73 renewable biomass
74 renewable materials
75 scattering
76 sites
77 solution
78 spectroscopy
79 strength
80 study
81 sustainable chemical processes
82 sustainable production
83 synchrotron X
84 target
85 valerolactone
86 yield
87 zeolite
88 schema:name Quantitative production of butenes from biomass-derived γ-valerolactone catalysed by hetero-atomic MFI zeolite
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