Quantitative production of butenes from biomass-derived γ-valerolactone catalysed by hetero-atomic MFI zeolite View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12-16

AUTHORS

Longfei Lin, Alena M. Sheveleva, Ivan da Silva, Christopher M. A. Parlett, Zhimou Tang, Yueming Liu, Mengtian Fan, Xue Han, Joseph H. Carter, Floriana Tuna, Eric J. L. McInnes, Yongqiang Cheng, Luke L. Daemen, Svemir Rudić, Anibal J. Ramirez-Cuesta, Chiu C. Tang, Sihai Yang

ABSTRACT

The efficient production of light olefins from renewable biomass is a vital and challenging target to achieve future sustainable chemical processes. Here we report a hetero-atomic MFI-type zeolite (NbAlS-1), over which aqueous solutions of γ-valerolactone (GVL), obtained from biomass-derived carbohydrates, can be quantitatively converted into butenes with a yield of >99% at ambient pressure under continuous flow conditions. NbAlS-1 incorporates simultaneously niobium(v) and aluminium(iii) centres into the framework and thus has a desirable distribution of Lewis and Brønsted acid sites with optimal strength. Synchrotron X-ray diffraction and absorption spectroscopy show that there is cooperativity between Nb(v) and the Brønsted acid sites on the confined adsorption of GVL, whereas the catalytic mechanism for the conversion of the confined GVL into butenes is revealed by in situ inelastic neutron scattering, coupled with modelling. This study offers a prospect for the sustainable production of butene as a platform chemical for the manufacture of renewable materials. More... »

PAGES

86-93

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41563-019-0562-6

DOI

http://dx.doi.org/10.1038/s41563-019-0562-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1123433771

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/31844281


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22 schema:description The efficient production of light olefins from renewable biomass is a vital and challenging target to achieve future sustainable chemical processes. Here we report a hetero-atomic MFI-type zeolite (NbAlS-1), over which aqueous solutions of γ-valerolactone (GVL), obtained from biomass-derived carbohydrates, can be quantitatively converted into butenes with a yield of >99% at ambient pressure under continuous flow conditions. NbAlS-1 incorporates simultaneously niobium(v) and aluminium(iii) centres into the framework and thus has a desirable distribution of Lewis and Brønsted acid sites with optimal strength. Synchrotron X-ray diffraction and absorption spectroscopy show that there is cooperativity between Nb(v) and the Brønsted acid sites on the confined adsorption of GVL, whereas the catalytic mechanism for the conversion of the confined GVL into butenes is revealed by in situ inelastic neutron scattering, coupled with modelling. This study offers a prospect for the sustainable production of butene as a platform chemical for the manufacture of renewable materials.
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29 schema:keywords Brønsted acid sites
30 GVL
31 Lewis
32 MFI zeolites
33 MFI-type zeolites
34 NbAlS-1
35 absorption spectroscopy
36 acid sites
37 adsorption
38 ambient pressure
39 aqueous solution
40 biomass
41 biomass-derived carbohydrates
42 butene
43 carbohydrates
44 catalytic mechanism
45 challenging target
46 chemical processes
47 chemicals
48 conditions
49 confined adsorption
50 continuous flow conditions
51 conversion
52 cooperativity
53 desirable distribution
54 diffraction
55 distribution
56 efficient production
57 flow conditions
58 framework
59 future sustainable chemical processes
60 hetero-atomic MFI zeolite
61 hetero-atomic MFI-type zeolite
62 inelastic neutron scattering
63 light olefins
64 manufacture
65 materials
66 mechanism
67 modelling
68 neutron scattering
69 olefins
70 optimal strength
71 platform chemicals
72 pressure
73 process
74 production
75 prospects
76 quantitative production
77 ray diffraction
78 renewable biomass
79 renewable materials
80 scattering
81 sites
82 situ inelastic neutron scattering
83 solution
84 spectroscopy
85 strength
86 study
87 sustainable chemical processes
88 sustainable production
89 synchrotron X
90 target
91 valerolactone
92 yield
93 zeolite
94 schema:name Quantitative production of butenes from biomass-derived γ-valerolactone catalysed by hetero-atomic MFI zeolite
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