Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-03

AUTHORS

Genfeng Feng, Mingxing Zhang, Dong Shao, Xinyi Wang, Shuao Wang, Laurent Maron, Congqing Zhu

ABSTRACT

Heterometallic clusters are important in catalysis and small-molecule activation because of the multimetallic synergistic effects from different metals. However, multimetallic species that contain uranium-metal bonds remain very scarce due to the difficulties in their synthesis. Here we present a straightforward strategy to construct a series of heterometallic clusters with multiple uranium-metal bonds. These complexes were created by facile reactions of a uranium precursor with Ni(COD)2 (COD, cyclooctadiene). The multimetallic clusters' cores are supported by a heptadentate N4P3 scaffold. Theoretical investigations indicate the formation of uranium-nickel bonds in a U2Ni2 and a U2Ni3 species, but also show that they exhibit a uranium-uranium interaction; thus, the electronic configuration of uranium in these species is U(III)-5f26d1. This study provides further understanding of the bonding between f-block elements and transition metals, which may allow the construction of d-f heterometallic clusters and the investigation of their potential applications. More... »

PAGES

248-253

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41557-018-0195-4

DOI

http://dx.doi.org/10.1038/s41557-018-0195-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111674281

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30692660


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Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

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