Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2018-09-10

AUTHORS

Kasper S. Pedersen, Panagiota Perlepe, Michael L. Aubrey, Daniel N. Woodruff, Sebastian E. Reyes-Lillo, Anders Reinholdt, Laura Voigt, Zheshen Li, Kasper Borup, Mathieu Rouzières, Dumitru Samohvalov, Fabrice Wilhelm, Andrei Rogalev, Jeffrey B. Neaton, Jeffrey R. Long, Rodolphe Clérac

ABSTRACT

The unique properties of graphene, transition-metal dichalcogenides and other two-dimensional (2D) materials have boosted interest in layered coordination solids. In particular, 2D materials that behave as both conductors and magnets could find applications in quantum magnetoelectronics and spintronics. Here, we report the synthesis of CrCl2(pyrazine)2, an air-stable layered solid, by reaction of CrCl2 with pyrazine (pyz). This compound displays a ferrimagnetic order below ∼55 K, reflecting the presence of strong magnetic interactions. Electrical conductivity measurements demonstrate that CrCl2(pyz)2 reaches a conductivity of 32 mS cm–1 at room temperature, which operates through a 2D hopping-based transport mechanism. These properties are induced by the redox-activity of the pyrazine ligand, which leads to a smearing of the Cr 3d and pyrazine π states. We suggest that the combination of redox-active ligands and reducing paramagnetic metal ions represents a general approach towards tuneable 2D materials that consist of charge-neutral layers and exhibit both long-range magnetic order and high electronic conductivity. More... »

PAGES

1056-1061

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41557-018-0107-7

DOI

http://dx.doi.org/10.1038/s41557-018-0107-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106681147

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30202103


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65 paramagnetic metal ions
66 presence
67 properties
68 pyrazine
69 pyrazine ligands
70 quantum magnetoelectronics
71 reaction
72 reaction of CrCl2
73 redox-active coordination chemistry
74 redox-active ligand
75 room temperature
76 smearing
77 solids
78 spintronics
79 state
80 strong magnetic interactions
81 synthesis
82 temperature
83 transition-metal dichalcogenides
84 transport mechanism
85 tuneable 2D materials
86 two-dimensional materials
87 unique properties
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