Ontology type: schema:ScholarlyArticle Open Access: True
2019-07-19
AUTHORSRuguang Ma, Gaoxin Lin, Yao Zhou, Qian Liu, Tao Zhang, Guangcun Shan, Minghui Yang, Jiacheng Wang
ABSTRACTThe sluggish kinetics of Oxygen Reduction Reaction (ORR) at the cathode in proton exchange membrane fuel cells or metal-air batteries requires highly effective and stable electrocatalysts to boost the reaction. The low abundance and high price of Pt-based electrocatalysts hamper the widespread application of proton exchange membrane fuel cells and metal-air batteries. As promising alternatives, metal-free carbon materials, especially upon doping heteroatoms or creating defects demonstrated excellent ORR activity, which is as efficient as or even superior to commercial platinum on carbon. Significant progress on the development of advanced carbon materials as highly stable and durable catalysts has been achieved, but the catalytic mechanisms of these materials still remain undistinguished. In present review, we summarized the up-to-date progress in the studies of carbon materials, and emphasized on the combination of experiment and theory to clarify the underlying mechanisms of these materials. At last, we proposed the perspectives on the proper strategies of elucidating the mechanisms of carbon materials as electrocatalysts towards ORR. More... »
PAGES78
http://scigraph.springernature.com/pub.10.1038/s41524-019-0210-3
DOIhttp://dx.doi.org/10.1038/s41524-019-0210-3
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1118097797
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Macromolecular and Materials Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Materials Engineering",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, 100049, Beijing, China",
"id": "http://www.grid.ac/institutes/grid.410726.6",
"name": [
"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China",
"Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, 100049, Beijing, China"
],
"type": "Organization"
},
"familyName": "Ma",
"givenName": "Ruguang",
"id": "sg:person.011052031513.42",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011052031513.42"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Chinese Academy of Sciences, 19A Yuquan Rd, 100049, Beijing, Shijingshan District, China",
"id": "http://www.grid.ac/institutes/grid.410726.6",
"name": [
"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China",
"University of Chinese Academy of Sciences, 19A Yuquan Rd, 100049, Beijing, Shijingshan District, China"
],
"type": "Organization"
},
"familyName": "Lin",
"givenName": "Gaoxin",
"id": "sg:person.016051652302.54",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016051652302.54"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China",
"id": "http://www.grid.ac/institutes/grid.454856.e",
"name": [
"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China"
],
"type": "Organization"
},
"familyName": "Zhou",
"givenName": "Yao",
"id": "sg:person.014165601401.58",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014165601401.58"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China",
"id": "http://www.grid.ac/institutes/grid.454856.e",
"name": [
"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China"
],
"type": "Organization"
},
"familyName": "Liu",
"givenName": "Qian",
"id": "sg:person.013320366777.65",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013320366777.65"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China",
"id": "http://www.grid.ac/institutes/grid.454856.e",
"name": [
"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China"
],
"type": "Organization"
},
"familyName": "Zhang",
"givenName": "Tao",
"id": "sg:person.011436056757.16",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011436056757.16"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "School of Instrumentation Science and Opto-electronics Engineering, Beihang University, 100191, Beijing, China",
"id": "http://www.grid.ac/institutes/grid.64939.31",
"name": [
"School of Instrumentation Science and Opto-electronics Engineering, Beihang University, 100191, Beijing, China"
],
"type": "Organization"
},
"familyName": "Shan",
"givenName": "Guangcun",
"id": "sg:person.0660762314.51",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0660762314.51"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 315201, Ningbo, China",
"id": "http://www.grid.ac/institutes/grid.458492.6",
"name": [
"Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 315201, Ningbo, China"
],
"type": "Organization"
},
"familyName": "Yang",
"givenName": "Minghui",
"id": "sg:person.01175360517.08",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01175360517.08"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, 100049, Beijing, China",
"id": "http://www.grid.ac/institutes/grid.410726.6",
"name": [
"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, 200050, Shanghai, China",
"Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, 100049, Beijing, China"
],
"type": "Organization"
},
"familyName": "Wang",
"givenName": "Jiacheng",
"id": "sg:person.01000207404.23",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01000207404.23"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/s40820-017-0181-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1100076937",
"https://doi.org/10.1007/s40820-017-0181-1"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.1069",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045401156",
"https://doi.org/10.1038/nchem.1069"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature11115",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1013935373",
"https://doi.org/10.1038/nature11115"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s12274-015-0960-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007437610",
"https://doi.org/10.1007/s12274-015-0960-2"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/natrevmats.2016.64",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018712965",
"https://doi.org/10.1038/natrevmats.2016.64"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nnano.2014.184",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014287703",
"https://doi.org/10.1038/nnano.2014.184"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/srep05130",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015159108",
"https://doi.org/10.1038/srep05130"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/ncomms13285",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037876832",
"https://doi.org/10.1038/ncomms13285"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s40820-017-0157-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1091925210",
"https://doi.org/10.1007/s40820-017-0157-1"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/srep09304",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022557365",
"https://doi.org/10.1038/srep09304"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/376238a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004659378",
"https://doi.org/10.1038/376238a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/srep01810",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023371470",
"https://doi.org/10.1038/srep01810"
],
"type": "CreativeWork"
}
],
"datePublished": "2019-07-19",
"datePublishedReg": "2019-07-19",
"description": "The sluggish kinetics of Oxygen Reduction Reaction (ORR) at the cathode in proton exchange membrane fuel cells or metal-air batteries requires highly effective and stable electrocatalysts to boost the reaction. The low abundance and high price of Pt-based electrocatalysts hamper the widespread application of proton exchange membrane fuel cells and metal-air batteries. As promising alternatives, metal-free carbon materials, especially upon doping heteroatoms or creating defects demonstrated excellent ORR activity, which is as efficient as or even superior to commercial platinum on carbon. Significant progress on the development of advanced carbon materials as highly stable and durable catalysts has been achieved, but the catalytic mechanisms of these materials still remain undistinguished. In present review, we summarized the up-to-date progress in the studies of carbon materials, and emphasized on the combination of experiment and theory to clarify the underlying mechanisms of these materials. At last, we proposed the perspectives on the proper strategies of elucidating the mechanisms of carbon materials as electrocatalysts towards ORR.",
"genre": "article",
"id": "sg:pub.10.1038/s41524-019-0210-3",
"isAccessibleForFree": true,
"isFundedItemOf": [
{
"id": "sg:grant.8268586",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.8262043",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1285194",
"issn": [
"2057-3960"
],
"name": "npj Computational Materials",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "5"
}
],
"keywords": [
"oxygen reduction reaction",
"metal-air batteries",
"proton exchange membrane fuel cells",
"exchange membrane fuel cells",
"carbon materials",
"membrane fuel cells",
"metal-free carbon-based electrocatalysts",
"metal-free carbon materials",
"fuel cells",
"carbon-based electrocatalysts",
"excellent ORR activity",
"advanced carbon materials",
"oxygen reduction mechanism",
"stable electrocatalysts",
"commercial platinum",
"ORR activity",
"durable catalysts",
"reduction reaction",
"sluggish kinetics",
"electrocatalysts",
"catalytic mechanism",
"date progress",
"combination of experiments",
"reduction mechanism",
"promising alternative",
"widespread application",
"batteries",
"reaction",
"materials",
"heteroatoms",
"catalyst",
"cathode",
"platinum",
"significant progress",
"Pt",
"carbon",
"present review",
"low abundance",
"kinetics",
"applications",
"mechanism",
"progress",
"cells",
"proper strategies",
"high price",
"experiments",
"defects",
"activity",
"alternative",
"strategies",
"combination",
"review",
"development",
"theory",
"up",
"prices",
"study",
"abundance",
"perspective"
],
"name": "A review of oxygen reduction mechanisms for metal-free carbon-based electrocatalysts",
"pagination": "78",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1118097797"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1038/s41524-019-0210-3"
]
}
],
"sameAs": [
"https://doi.org/10.1038/s41524-019-0210-3",
"https://app.dimensions.ai/details/publication/pub.1118097797"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T17:07",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_817.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1038/s41524-019-0210-3"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41524-019-0210-3'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41524-019-0210-3'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41524-019-0210-3'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41524-019-0210-3'
This table displays all metadata directly associated to this object as RDF triples.
244 TRIPLES
21 PREDICATES
99 URIs
75 LITERALS
6 BLANK NODES