In situ correlation between metastable phase-transformation mechanism and kinetics in a metallic glass View Full Text


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Article Info

DATE

2021-05-14

AUTHORS

Jiri Orava, Shanoob Balachandran, Xiaoliang Han, Olga Shuleshova, Ebrahim Nurouzi, Ivan Soldatov, Steffen Oswald, Olof Gutowski, Oleh Ivashko, Ann-Christin Dippel, Martin v. Zimmermann, Yurii P. Ivanov, A. Lindsay Greer, Dierk Raabe, Michael Herbig, Ivan Kaban

ABSTRACT

A combination of complementary high-energy X-ray diffraction, containerless solidification during electromagnetic levitation and transmission electron microscopy is used to map in situ the phase evolution in a prototype Cu-Zr-Al glass during flash-annealing imposed at a rate ranging from 102 to 103 K s−1 and during cooling from the liquid state. Such a combination of experimental techniques provides hitherto inaccessible insight into the phase-transformation mechanism and its kinetics with high temporal resolution over the entire temperature range of the existence of the supercooled liquid. On flash-annealing, most of the formed phases represent transient (metastable) states – they crystallographically conform to their equilibrium phases but the compositions, revealed by atom probe tomography, are different. It is only the B2 CuZr phase which is represented by its equilibrium composition, and its growth is facilitated by a kinetic mechanism of Al partitioning; Al-rich precipitates of less than 10 nm in a diameter are revealed. In this work, the kinetic and chemical conditions of the high propensity of the glass for the B2 phase formation are formulated, and the multi-technique approach can be applied to map phase transformations in other metallic-glass-forming systems. More... »

PAGES

2839

References to SciGraph publications

  • 2015-07-29. Flash Joule heating for ductilization of metallic glasses in NATURE COMMUNICATIONS
  • 2010-05-16. Transformation-mediated ductility in CuZr-based bulk metallic glasses in NATURE MATERIALS
  • 2011-09-22. A brief overview of bulk metallic glasses in NPG ASIA MATERIALS
  • 2015-08-12. Rejuvenation of metallic glasses by non-affine thermal strain in NATURE
  • 2010-11-24. High-Accuracy X-Ray Diffraction Analysis of Phase Evolution Sequence During Devitrification of Cu50Zr50 Metallic Glass in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2019-03-08. Non-thermal crystallization process in heterogeneous metallic glass upon deep cryogenic cycling treatment in JOURNAL OF MATERIALS SCIENCE
  • 2016-06-07. Thermomechanical processing of metallic glasses: extending the range of the glassy state in NATURE REVIEWS MATERIALS
  • 2012-02-21. Oxidation resistance of the supercooled liquid in Cu50Zr50 and Cu46Zr46Al8 metallic glasses in JOURNAL OF MATERIALS RESEARCH
  • 2020-02-26. Strain-hardening and suppression of shear-banding in rejuvenated bulk metallic glass in NATURE
  • 2014-12-17. Kinetics and Mechanisms of Isothermal Devitrification in Amorphous Cu50Zr50 in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2015-04-28. Crystallization Kinetics and Phase Transformation Mechanisms in Cu56Zr44 Glassy Alloy in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2017-12-07. Tailoring crystallization phases in metallic glass nanorods via nucleus starvation in NATURE COMMUNICATIONS
  • <error retrieving object. in <ERROR RETRIEVING OBJECT
  • 2016-12-05. Properties of Cu-Based Shape-Memory Alloys Prepared by Selective Laser Melting in SHAPE MEMORY AND SUPERELASTICITY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/s41467-021-23028-9

    DOI

    http://dx.doi.org/10.1038/s41467-021-23028-9

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1138066058

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/33990573


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