Ontology type: schema:ScholarlyArticle Open Access: True
2020-11-30
AUTHORSMatteo Ceppatelli, Demetrio Scelta, Manuel Serrano-Ruiz, Kamil Dziubek, Gaston Garbarino, Jeroen Jacobs, Mohamed Mezouar, Roberto Bini, Maurizio Peruzzini
ABSTRACTHigh pressure reactivity of phosphorus and hydrogen is relevant to fundamental chemistry, energy conversion and storage, and materials science. Here we report the synthesis of (PH3)2H2, a crystalline van der Waals (vdW) compound (I4cm) made of PH3 and H2 molecules, in a Diamond Anvil Cell by direct catalyst-free high pressure (1.2 GPa) and high temperature (T ≲ 1000 K) chemical reaction of black phosphorus and liquid hydrogen, followed by room T compression above 3.5 GPa. Group 15 elements were previously not known to form H2-containing vdW compounds of their molecular hydrides. The observation of (PH3)2H2, identified by synchrotron X-ray diffraction and vibrational spectroscopy (FTIR, Raman), therefore represents the discovery of a previously missing tile, specifically corresponding to P for pnictogens, in the ability of non-metallic elements to form such compounds. Significant chemical implications encompass reactivity of the elements under extreme conditions, with the observation of the P analogue of the Haber-Bosch reaction for N, fundamental bond theory, and predicted high pressure superconductivity in P-H systems. More... »
PAGES6125
http://scigraph.springernature.com/pub.10.1038/s41467-020-19745-2
DOIhttp://dx.doi.org/10.1038/s41467-020-19745-2
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1132950310
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/33257669
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Organic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0307",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Theoretical and Computational Chemistry",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy",
"id": "http://www.grid.ac/institutes/None",
"name": [
"LENS, European Laboratory for Non-linear Spectroscopy, Via N. Carrara 1, I-50019 Firenze, Sesto Fiorentino Italy",
"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy"
],
"type": "Organization"
},
"familyName": "Ceppatelli",
"givenName": "Matteo",
"id": "sg:person.013005620471.31",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013005620471.31"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy",
"id": "http://www.grid.ac/institutes/None",
"name": [
"LENS, European Laboratory for Non-linear Spectroscopy, Via N. Carrara 1, I-50019 Firenze, Sesto Fiorentino Italy",
"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy"
],
"type": "Organization"
},
"familyName": "Scelta",
"givenName": "Demetrio",
"id": "sg:person.014225666065.36",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014225666065.36"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy",
"id": "http://www.grid.ac/institutes/None",
"name": [
"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy"
],
"type": "Organization"
},
"familyName": "Serrano-Ruiz",
"givenName": "Manuel",
"id": "sg:person.01235574165.24",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01235574165.24"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy",
"id": "http://www.grid.ac/institutes/None",
"name": [
"LENS, European Laboratory for Non-linear Spectroscopy, Via N. Carrara 1, I-50019 Firenze, Sesto Fiorentino Italy",
"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy"
],
"type": "Organization"
},
"familyName": "Dziubek",
"givenName": "Kamil",
"id": "sg:person.011113360441.04",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011113360441.04"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ESRF, European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France",
"id": "http://www.grid.ac/institutes/grid.5398.7",
"name": [
"ESRF, European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France"
],
"type": "Organization"
},
"familyName": "Garbarino",
"givenName": "Gaston",
"id": "sg:person.01032202732.99",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01032202732.99"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ESRF, European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France",
"id": "http://www.grid.ac/institutes/grid.5398.7",
"name": [
"ESRF, European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France"
],
"type": "Organization"
},
"familyName": "Jacobs",
"givenName": "Jeroen",
"id": "sg:person.012735765645.35",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012735765645.35"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ESRF, European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France",
"id": "http://www.grid.ac/institutes/grid.5398.7",
"name": [
"ESRF, European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France"
],
"type": "Organization"
},
"familyName": "Mezouar",
"givenName": "Mohamed",
"id": "sg:person.01365516615.44",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365516615.44"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Dipartimento di Chimica \u201cUgo Schiff\u201d dell\u2019Universit\u00e0 degli Studi di Firenze, Via della Lastruccia 3, I-50019 Firenze, Sesto Fiorentino Italy",
"id": "http://www.grid.ac/institutes/grid.8404.8",
"name": [
"LENS, European Laboratory for Non-linear Spectroscopy, Via N. Carrara 1, I-50019 Firenze, Sesto Fiorentino Italy",
"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy",
"Dipartimento di Chimica \u201cUgo Schiff\u201d dell\u2019Universit\u00e0 degli Studi di Firenze, Via della Lastruccia 3, I-50019 Firenze, Sesto Fiorentino Italy"
],
"type": "Organization"
},
"familyName": "Bini",
"givenName": "Roberto",
"id": "sg:person.0712171160.10",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0712171160.10"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy",
"id": "http://www.grid.ac/institutes/None",
"name": [
"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Firenze, Sesto Fiorentino Italy"
],
"type": "Organization"
},
"familyName": "Peruzzini",
"givenName": "Maurizio",
"id": "sg:person.0652330166.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0652330166.48"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1038/378044a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015557648",
"https://doi.org/10.1038/378044a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/s41586-020-2801-z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1131668579",
"https://doi.org/10.1038/s41586-020-2801-z"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/srep34896",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009656089",
"https://doi.org/10.1038/srep34896"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature05174",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044355087",
"https://doi.org/10.1038/nature05174"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.445",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1049241698",
"https://doi.org/10.1038/nchem.445"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature14964",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029296188",
"https://doi.org/10.1038/nature14964"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/s41550-020-1174-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1130820552",
"https://doi.org/10.1038/s41550-020-1174-4"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02496237",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019479926",
"https://doi.org/10.1007/bf02496237"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.2505",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045575082",
"https://doi.org/10.1038/nchem.2505"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1022495220338",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051320921",
"https://doi.org/10.1023/a:1022495220338"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature02968",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024735914",
"https://doi.org/10.1038/nature02968"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/srep04989",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043285910",
"https://doi.org/10.1038/srep04989"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.2528",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043954577",
"https://doi.org/10.1038/nchem.2528"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature04879",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026133119",
"https://doi.org/10.1038/nature04879"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nmat1147",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1003491205",
"https://doi.org/10.1038/nmat1147"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/358046a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044563288",
"https://doi.org/10.1038/358046a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.2716",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1083691566",
"https://doi.org/10.1038/nchem.2716"
],
"type": "CreativeWork"
}
],
"datePublished": "2020-11-30",
"datePublishedReg": "2020-11-30",
"description": "High pressure reactivity of phosphorus and hydrogen is relevant to fundamental chemistry, energy conversion and storage, and materials science. Here we report the synthesis of (PH3)2H2, a crystalline van der Waals (vdW) compound (I4cm) made of PH3 and H2 molecules, in a Diamond Anvil Cell by direct catalyst-free high pressure (1.2\u00a0GPa) and high temperature (T\u00a0\u2272\u00a01000\u00a0K) chemical reaction of black phosphorus and liquid hydrogen, followed by room T compression above 3.5\u00a0GPa. Group 15 elements were previously not known to form H2-containing vdW compounds of their molecular hydrides. The observation of (PH3)2H2, identified by synchrotron X-ray diffraction and vibrational spectroscopy (FTIR, Raman), therefore represents the discovery of a previously missing tile, specifically corresponding to P for pnictogens, in the ability of non-metallic elements to form such compounds. Significant chemical implications encompass reactivity of the elements under extreme conditions, with the observation of the P analogue of the Haber-Bosch reaction for N, fundamental bond theory, and predicted high pressure superconductivity in P-H systems.",
"genre": "article",
"id": "sg:pub.10.1038/s41467-020-19745-2",
"inLanguage": "en",
"isAccessibleForFree": true,
"isFundedItemOf": [
{
"id": "sg:grant.4273746",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1043282",
"issn": [
"2041-1723"
],
"name": "Nature Communications",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "11"
}
],
"keywords": [
"high-pressure reactivity",
"van der Waals compound",
"Haber-Bosch reaction",
"group 15 elements",
"high-temperature chemical reactions",
"non-metallic elements",
"fundamental chemistry",
"vibrational spectroscopy",
"high-pressure synthesis",
"bond theory",
"chemical reactions",
"ray diffraction",
"molecular hydrides",
"such compounds",
"materials science",
"pressure synthesis",
"energy conversion",
"compounds",
"synchrotron X",
"high-pressure superconductivity",
"black phosphorus",
"synthesis",
"hydrogen",
"reactivity",
"reaction",
"diamond anvil cell",
"phosphine",
"chemistry",
"pnictogen",
"spectroscopy",
"hydride",
"liquid hydrogen",
"diffraction",
"high pressure",
"molecules",
"anvil cell",
"extreme conditions",
"pH",
"conversion",
"discovery",
"analogues",
"phosphorus",
"superconductivity",
"storage",
"GPa",
"elements",
"tiles",
"conditions",
"ability",
"theory",
"observations",
"system",
"pressure",
"cells",
"science",
"compression",
"pressure reactivity",
"crystalline van der Waals (vdW) compound",
"der Waals (vdW) compound",
"Waals (vdW) compound",
"direct catalyst-free high pressure",
"catalyst-free high pressure",
"temperature (T\u00a0\u2272\u00a01000\u00a0K) chemical reaction",
"room T compression",
"T compression",
"vdW compounds",
"missing tile",
"Significant chemical implications encompass reactivity",
"chemical implications encompass reactivity",
"implications encompass reactivity",
"encompass reactivity",
"fundamental bond theory",
"pressure superconductivity"
],
"name": "High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile",
"pagination": "6125",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1132950310"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1038/s41467-020-19745-2"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"33257669"
]
}
],
"sameAs": [
"https://doi.org/10.1038/s41467-020-19745-2",
"https://app.dimensions.ai/details/publication/pub.1132950310"
],
"sdDataset": "articles",
"sdDatePublished": "2022-01-01T18:58",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_849.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1038/s41467-020-19745-2"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-020-19745-2'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-020-19745-2'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-020-19745-2'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-020-19745-2'
This table displays all metadata directly associated to this object as RDF triples.
281 TRIPLES
22 PREDICATES
119 URIs
91 LITERALS
7 BLANK NODES