Refinement of pore size at sub-angstrom precision in robust metal–organic frameworks for separation of xylenes View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2020-08-27

AUTHORS

Xiaolin Li, Juehua Wang, Nannan Bai, Xinran Zhang, Xue Han, Ivan da Silva, Christopher G. Morris, Shaojun Xu, Damian M. Wilary, Yinyong Sun, Yongqiang Cheng, Claire A. Murray, Chiu C. Tang, Mark D. Frogley, Gianfelice Cinque, Tristan Lowe, Haifei Zhang, Anibal J. Ramirez-Cuesta, K. Mark Thomas, Leslie W. Bolton, Sihai Yang, Martin Schröder

ABSTRACT

The demand for xylenes is projected to increase over the coming decades. The separation of xylene isomers, particularly p- and m-xylenes, is vital for the production of numerous polymers and materials. However, current state-of-the-art separation is based upon fractional crystallisation at 220 K which is highly energy intensive. Here, we report the discrimination of xylene isomers via refinement of the pore size in a series of porous metal–organic frameworks, MFM-300, at sub-angstrom precision leading to the optimal kinetic separation of all three xylene isomers at room temperature. The exceptional performance of MFM-300 for xylene separation is confirmed by dynamic ternary breakthrough experiments. In-depth structural and vibrational investigations using synchrotron X-ray diffraction and terahertz spectroscopy define the underlying host–guest interactions that give rise to the observed selectivity (p-xylene < o-xylene < m-xylene) and separation factors of 4.6–18 for p- and m-xylenes. More... »

PAGES

4280

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-020-17640-4

DOI

http://dx.doi.org/10.1038/s41467-020-17640-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1130368094

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/32855396


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46 pore size
47 porous metal-organic framework
48 precision
49 production
50 refinement
51 rise
52 robust metal-organic framework
53 room temperature
54 selectivity
55 separation
56 separation factor
57 separation of xylenes
58 series
59 size
60 spectroscopy
61 state
62 sub-angstrom precision
63 synchrotron X-ray diffraction
64 temperature
65 terahertz spectroscopy
66 vibrational investigation
67 xylene
68 xylene isomers
69 xylene separation
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