Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Xiaojuan Zhu, Qishui Guo, Yafei Sun, Shangjun Chen, Jian-Qiang Wang, Mengmeng Wu, Wenzhao Fu, Yanqiang Tang, Xuezhi Duan, De Chen, Ying Wan

ABSTRACT

Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here, we adopt an adsorbate mediated thermal reduction approach to yield monodispersed AuPd catalysts with continuous change of the Pd-Au coordination numbers embedded in a mesoporous carbonaceous matrix. The structure of nanoalloys is well-defined, allowing for a direct determination of the structure-property relationship. The results show that the Pd single atom and dimer are the active sites for the base-free oxidation of primary alcohols. Remarkably, the d-orbital charge on the surface of Pd serves as a descriptor to the adsorbate states and hence the catalytic performance. The maximum d-charge gain occurred in a composition with 33-50 at% Pd corresponds to up to 9 times enhancement in the reaction rate compared to the neat Pd. The findings not only open an avenue towards the rational design of catalysts but also enable the identification of key steps involved in the catalytic reactions. More... »

PAGES

1428

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-019-09421-5

DOI

http://dx.doi.org/10.1038/s41467-019-09421-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1113059672

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30926804


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Shanghai Normal University", 
          "id": "https://www.grid.ac/institutes/grid.412531.0", 
          "name": [
            "Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhu", 
        "givenName": "Xiaojuan", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Normal University", 
          "id": "https://www.grid.ac/institutes/grid.412531.0", 
          "name": [
            "Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Guo", 
        "givenName": "Qishui", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Normal University", 
          "id": "https://www.grid.ac/institutes/grid.412531.0", 
          "name": [
            "Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sun", 
        "givenName": "Yafei", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Normal University", 
          "id": "https://www.grid.ac/institutes/grid.412531.0", 
          "name": [
            "Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chen", 
        "givenName": "Shangjun", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Institute of Applied Physics", 
          "id": "https://www.grid.ac/institutes/grid.450275.1", 
          "name": [
            "Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 201204, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Jian-Qiang", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Normal University", 
          "id": "https://www.grid.ac/institutes/grid.412531.0", 
          "name": [
            "Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wu", 
        "givenName": "Mengmeng", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "East China University of Science and Technology", 
          "id": "https://www.grid.ac/institutes/grid.28056.39", 
          "name": [
            "State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 200237, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fu", 
        "givenName": "Wenzhao", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "East China University of Science and Technology", 
          "id": "https://www.grid.ac/institutes/grid.28056.39", 
          "name": [
            "State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 200237, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tang", 
        "givenName": "Yanqiang", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "East China University of Science and Technology", 
          "id": "https://www.grid.ac/institutes/grid.28056.39", 
          "name": [
            "State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 200237, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Duan", 
        "givenName": "Xuezhi", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Norwegian University of Science and Technology", 
          "id": "https://www.grid.ac/institutes/grid.5947.f", 
          "name": [
            "Department of Chemical Engineering, Norwegian University of Science and Technology, N-7491, Trondheim, Norway"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chen", 
        "givenName": "De", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Normal University", 
          "id": "https://www.grid.ac/institutes/grid.412531.0", 
          "name": [
            "Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wan", 
        "givenName": "Ying", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s11244-013-0159-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001484137", 
          "https://doi.org/10.1007/s11244-013-0159-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cplett.2008.07.029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003469985"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2007.07.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008767243"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2010.11.013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010232988"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1nr11052g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010466170"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cy00487a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013607816"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.201202802", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013647775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(68)90224-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014720465"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02880404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018828887", 
          "https://doi.org/10.1007/bf02880404"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02880404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018828887", 
          "https://doi.org/10.1007/bf02880404"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/01614947208062259", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020329647"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.121", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022136973", 
          "https://doi.org/10.1038/nchem.121"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.121", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022136973", 
          "https://doi.org/10.1038/nchem.121"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cctc.201500666", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022799963"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5cs00350d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028207240"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1120560", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028356846"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c4cy00976b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029323884"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar500426g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030042188"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcata.2009.05.059", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030528120"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.201001330", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030879435"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b518069d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030880455"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b518069d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030880455"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr0200116", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031651292"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr0200116", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031651292"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2013.07.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032287109"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cs35160a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035965317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2011.04.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037983369"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1995.1110", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038498789"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat3143", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042490431", 
          "https://doi.org/10.1038/nmat3143"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201405232", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044050092"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201108706", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049169475"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2011.11.007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052131971"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201002641", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053659973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr040090g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053830231"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr040090g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053830231"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acscatal.6b03293", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055134815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar300356m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055150346"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs200040a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055421687"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs300252g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055421997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs500388x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055422708"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs501896c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055423081"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100016a053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055649235"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100852a052", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055682399"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja403822d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055854650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja971039f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055867481"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja971039f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055867481"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp4061686", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056096307"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp808362m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056111261"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp808362m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056111261"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp9037182", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056115251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp9037182", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056115251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la5001304", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056159249"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn302299e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056224514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1737365", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057802354"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0305-4608/4/12/015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059084589"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.24.1725", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060529235"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.24.1725", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060529235"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.36.2972", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060543638"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.36.2972", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060543638"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.4.4139", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060550866"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.4.4139", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060550866"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.43.4659", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060557613"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.43.4659", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060557613"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.47.4873", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060566188"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.47.4873", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060566188"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.52.16443", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060577815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.52.16443", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060577815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.56.5822", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060586399"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.56.5822", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060586399"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.72.064203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060614626"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.72.064203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060614626"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.89.115114", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060643013"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.89.115114", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060643013"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1195055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062462734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acscatal.6b02720", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083550032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.jpcc.7b00139", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084123393"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jacs.7b01632", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084864440"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jacs.7b01471", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085466682"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.aan6515", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1091615551"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2017.10.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092545197"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2915", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100239794", 
          "https://doi.org/10.1038/nchem.2915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2915", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100239794", 
          "https://doi.org/10.1038/nchem.2915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2915", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100239794", 
          "https://doi.org/10.1038/nchem.2915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2915", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100239794", 
          "https://doi.org/10.1038/nchem.2915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41929-018-0028-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101324983", 
          "https://doi.org/10.1038/s41929-018-0028-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41929-018-0028-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101324983", 
          "https://doi.org/10.1038/s41929-018-0028-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41929-018-0028-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101324983", 
          "https://doi.org/10.1038/s41929-018-0028-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.chemrev.7b00776", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103277743"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41929-018-0090-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1104468866", 
          "https://doi.org/10.1038/s41929-018-0090-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41467-018-04845-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1104570282", 
          "https://doi.org/10.1038/s41467-018-04845-x"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-12", 
    "datePublishedReg": "2019-12-01", 
    "description": "Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here, we adopt an adsorbate mediated thermal reduction approach to yield monodispersed AuPd catalysts with continuous change of the Pd-Au coordination numbers embedded in a mesoporous carbonaceous matrix. The structure of nanoalloys is well-defined, allowing for a direct determination of the structure-property relationship. The results show that the Pd single atom and dimer are the active sites for the base-free oxidation of primary alcohols. Remarkably, the d-orbital charge on the surface of Pd serves as a descriptor to the adsorbate states and hence the catalytic performance. The maximum d-charge gain occurred in a composition with 33-50 at% Pd corresponds to up to 9 times enhancement in the reaction rate compared to the neat Pd. The findings not only open an avenue towards the rational design of catalysts but also enable the identification of key steps involved in the catalytic reactions.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/s41467-019-09421-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1043282", 
        "issn": [
          "2041-1723"
        ], 
        "name": "Nature Communications", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "10"
      }
    ], 
    "name": "Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity", 
    "pagination": "1428", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/s41467-019-09421-5"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "d2e762da4afaa5255bec431c185c90f2e74818fff2a536dd3f1e56a5dce48972"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1113059672"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101528555"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "30926804"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/s41467-019-09421-5", 
      "https://app.dimensions.ai/details/publication/pub.1113059672"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T09:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000376_0000000376/records_56196_00000006.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/s41467-019-09421-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09421-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09421-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09421-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09421-5'


 

This table displays all metadata directly associated to this object as RDF triples.

348 TRIPLES      21 PREDICATES      97 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/s41467-019-09421-5 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nbb1e656da49848f59559a93129fba680
4 schema:citation sg:pub.10.1007/bf02880404
5 sg:pub.10.1007/s11244-013-0159-2
6 sg:pub.10.1038/nchem.121
7 sg:pub.10.1038/nchem.2915
8 sg:pub.10.1038/nmat3143
9 sg:pub.10.1038/s41467-018-04845-x
10 sg:pub.10.1038/s41929-018-0028-2
11 sg:pub.10.1038/s41929-018-0090-9
12 https://doi.org/10.1002/adfm.201002641
13 https://doi.org/10.1002/anie.201108706
14 https://doi.org/10.1002/anie.201405232
15 https://doi.org/10.1002/cctc.201500666
16 https://doi.org/10.1002/chem.201001330
17 https://doi.org/10.1002/chem.201202802
18 https://doi.org/10.1006/jcat.1995.1110
19 https://doi.org/10.1016/0021-9517(68)90224-8
20 https://doi.org/10.1016/j.apcata.2009.05.059
21 https://doi.org/10.1016/j.cplett.2008.07.029
22 https://doi.org/10.1016/j.jcat.2007.07.005
23 https://doi.org/10.1016/j.jcat.2010.11.013
24 https://doi.org/10.1016/j.jcat.2011.04.008
25 https://doi.org/10.1016/j.jcat.2011.11.007
26 https://doi.org/10.1016/j.jcat.2013.07.012
27 https://doi.org/10.1016/j.jcat.2017.10.016
28 https://doi.org/10.1021/acs.chemrev.7b00776
29 https://doi.org/10.1021/acs.jpcc.7b00139
30 https://doi.org/10.1021/acscatal.6b02720
31 https://doi.org/10.1021/acscatal.6b03293
32 https://doi.org/10.1021/ar300356m
33 https://doi.org/10.1021/ar500426g
34 https://doi.org/10.1021/cr0200116
35 https://doi.org/10.1021/cr040090g
36 https://doi.org/10.1021/cs200040a
37 https://doi.org/10.1021/cs300252g
38 https://doi.org/10.1021/cs500388x
39 https://doi.org/10.1021/cs501896c
40 https://doi.org/10.1021/j100016a053
41 https://doi.org/10.1021/j100852a052
42 https://doi.org/10.1021/ja403822d
43 https://doi.org/10.1021/ja971039f
44 https://doi.org/10.1021/jacs.7b01471
45 https://doi.org/10.1021/jacs.7b01632
46 https://doi.org/10.1021/jp4061686
47 https://doi.org/10.1021/jp808362m
48 https://doi.org/10.1021/jp9037182
49 https://doi.org/10.1021/la5001304
50 https://doi.org/10.1021/nn302299e
51 https://doi.org/10.1039/b518069d
52 https://doi.org/10.1039/c1nr11052g
53 https://doi.org/10.1039/c2cs35160a
54 https://doi.org/10.1039/c2cy00487a
55 https://doi.org/10.1039/c4cy00976b
56 https://doi.org/10.1039/c5cs00350d
57 https://doi.org/10.1063/1.1737365
58 https://doi.org/10.1080/01614947208062259
59 https://doi.org/10.1088/0305-4608/4/12/015
60 https://doi.org/10.1103/physrevb.24.1725
61 https://doi.org/10.1103/physrevb.36.2972
62 https://doi.org/10.1103/physrevb.4.4139
63 https://doi.org/10.1103/physrevb.43.4659
64 https://doi.org/10.1103/physrevb.47.4873
65 https://doi.org/10.1103/physrevb.52.16443
66 https://doi.org/10.1103/physrevb.56.5822
67 https://doi.org/10.1103/physrevb.72.064203
68 https://doi.org/10.1103/physrevb.89.115114
69 https://doi.org/10.1126/science.1120560
70 https://doi.org/10.1126/science.1195055
71 https://doi.org/10.1126/science.aan6515
72 schema:datePublished 2019-12
73 schema:datePublishedReg 2019-12-01
74 schema:description Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here, we adopt an adsorbate mediated thermal reduction approach to yield monodispersed AuPd catalysts with continuous change of the Pd-Au coordination numbers embedded in a mesoporous carbonaceous matrix. The structure of nanoalloys is well-defined, allowing for a direct determination of the structure-property relationship. The results show that the Pd single atom and dimer are the active sites for the base-free oxidation of primary alcohols. Remarkably, the d-orbital charge on the surface of Pd serves as a descriptor to the adsorbate states and hence the catalytic performance. The maximum d-charge gain occurred in a composition with 33-50 at% Pd corresponds to up to 9 times enhancement in the reaction rate compared to the neat Pd. The findings not only open an avenue towards the rational design of catalysts but also enable the identification of key steps involved in the catalytic reactions.
75 schema:genre research_article
76 schema:inLanguage en
77 schema:isAccessibleForFree true
78 schema:isPartOf N8220a79d5f8d465594f81e2aa6509946
79 Nc85b2a45e481410c80c238b20dfe99bf
80 sg:journal.1043282
81 schema:name Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
82 schema:pagination 1428
83 schema:productId N2895c572aa294785859daa9d7ff96a6d
84 N5e1bbdc125c74c06892685e8d92c08aa
85 Na8fd7abe49d14fdeb1e816122399cbfc
86 Nd2e8b3c7708d4373ae70e75d6560ecc0
87 Nd7c333b3f9b84177a5913c04621592d0
88 schema:sameAs https://app.dimensions.ai/details/publication/pub.1113059672
89 https://doi.org/10.1038/s41467-019-09421-5
90 schema:sdDatePublished 2019-04-15T09:28
91 schema:sdLicense https://scigraph.springernature.com/explorer/license/
92 schema:sdPublisher N02041e89b03a4d90bc584734903b3774
93 schema:url https://www.nature.com/articles/s41467-019-09421-5
94 sgo:license sg:explorer/license/
95 sgo:sdDataset articles
96 rdf:type schema:ScholarlyArticle
97 N013c0defb4aa4ba3a7e68fc0089f2b2b rdf:first N7a2b273698694eebaab9885c630cc20b
98 rdf:rest N7844f0022bcd4767ae21502d1a8d77ba
99 N02041e89b03a4d90bc584734903b3774 schema:name Springer Nature - SN SciGraph project
100 rdf:type schema:Organization
101 N0a77e241eb334fc8835afc1acb617dc8 schema:affiliation https://www.grid.ac/institutes/grid.28056.39
102 schema:familyName Fu
103 schema:givenName Wenzhao
104 rdf:type schema:Person
105 N119084b1bc9f4099b2fe4510e02504ef schema:affiliation https://www.grid.ac/institutes/grid.412531.0
106 schema:familyName Chen
107 schema:givenName Shangjun
108 rdf:type schema:Person
109 N1ed6e6e2773641cda83967f76a42d2f3 schema:affiliation https://www.grid.ac/institutes/grid.412531.0
110 schema:familyName Wan
111 schema:givenName Ying
112 rdf:type schema:Person
113 N1fa24f7e05054887b6911bcf5a43ab02 schema:affiliation https://www.grid.ac/institutes/grid.450275.1
114 schema:familyName Wang
115 schema:givenName Jian-Qiang
116 rdf:type schema:Person
117 N20c21131cdb546a29cb25c2303f93fb5 rdf:first N4cd79fc5ef384ef09d731051207d8a32
118 rdf:rest N391ccb0ed38641ca90225b116dce20f9
119 N2633c23c829b4a06b3865c71ffef6925 schema:affiliation https://www.grid.ac/institutes/grid.28056.39
120 schema:familyName Tang
121 schema:givenName Yanqiang
122 rdf:type schema:Person
123 N2895c572aa294785859daa9d7ff96a6d schema:name nlm_unique_id
124 schema:value 101528555
125 rdf:type schema:PropertyValue
126 N391ccb0ed38641ca90225b116dce20f9 rdf:first Nb8eed304c79c4f91a8577dd285474b2e
127 rdf:rest Ne51782e489f946ffb63d7546dce516fb
128 N3a9802b7232d414b9fd9668baadd35fa schema:affiliation https://www.grid.ac/institutes/grid.412531.0
129 schema:familyName Zhu
130 schema:givenName Xiaojuan
131 rdf:type schema:Person
132 N47e6f73cfb1e49f1a14b63f5f4b27d96 schema:affiliation https://www.grid.ac/institutes/grid.28056.39
133 schema:familyName Duan
134 schema:givenName Xuezhi
135 rdf:type schema:Person
136 N4cd79fc5ef384ef09d731051207d8a32 schema:affiliation https://www.grid.ac/institutes/grid.412531.0
137 schema:familyName Guo
138 schema:givenName Qishui
139 rdf:type schema:Person
140 N5db0a678dbf5453b9a6a91614b071d51 schema:affiliation https://www.grid.ac/institutes/grid.412531.0
141 schema:familyName Wu
142 schema:givenName Mengmeng
143 rdf:type schema:Person
144 N5e1bbdc125c74c06892685e8d92c08aa schema:name readcube_id
145 schema:value d2e762da4afaa5255bec431c185c90f2e74818fff2a536dd3f1e56a5dce48972
146 rdf:type schema:PropertyValue
147 N6da90ffa7b3e4164ab004b6f1ea94e49 rdf:first N0a77e241eb334fc8835afc1acb617dc8
148 rdf:rest Ndeecadacd5cf4441bf0d5261dd88c7fa
149 N7844f0022bcd4767ae21502d1a8d77ba rdf:first N1ed6e6e2773641cda83967f76a42d2f3
150 rdf:rest rdf:nil
151 N7a2b273698694eebaab9885c630cc20b schema:affiliation https://www.grid.ac/institutes/grid.5947.f
152 schema:familyName Chen
153 schema:givenName De
154 rdf:type schema:Person
155 N8220a79d5f8d465594f81e2aa6509946 schema:issueNumber 1
156 rdf:type schema:PublicationIssue
157 Na8fd7abe49d14fdeb1e816122399cbfc schema:name doi
158 schema:value 10.1038/s41467-019-09421-5
159 rdf:type schema:PropertyValue
160 Naaeae99477e14bd4aab78e2fe86b8262 rdf:first N47e6f73cfb1e49f1a14b63f5f4b27d96
161 rdf:rest N013c0defb4aa4ba3a7e68fc0089f2b2b
162 Naff80418a4ef42eb999353a835a51e01 rdf:first N5db0a678dbf5453b9a6a91614b071d51
163 rdf:rest N6da90ffa7b3e4164ab004b6f1ea94e49
164 Nb8eed304c79c4f91a8577dd285474b2e schema:affiliation https://www.grid.ac/institutes/grid.412531.0
165 schema:familyName Sun
166 schema:givenName Yafei
167 rdf:type schema:Person
168 Nbb1e656da49848f59559a93129fba680 rdf:first N3a9802b7232d414b9fd9668baadd35fa
169 rdf:rest N20c21131cdb546a29cb25c2303f93fb5
170 Nc85b2a45e481410c80c238b20dfe99bf schema:volumeNumber 10
171 rdf:type schema:PublicationVolume
172 Nd2e8b3c7708d4373ae70e75d6560ecc0 schema:name dimensions_id
173 schema:value pub.1113059672
174 rdf:type schema:PropertyValue
175 Nd7c333b3f9b84177a5913c04621592d0 schema:name pubmed_id
176 schema:value 30926804
177 rdf:type schema:PropertyValue
178 Ndeecadacd5cf4441bf0d5261dd88c7fa rdf:first N2633c23c829b4a06b3865c71ffef6925
179 rdf:rest Naaeae99477e14bd4aab78e2fe86b8262
180 Ne51782e489f946ffb63d7546dce516fb rdf:first N119084b1bc9f4099b2fe4510e02504ef
181 rdf:rest Nf6874177ba714e9dabd2ca3dd5b2cd99
182 Nf6874177ba714e9dabd2ca3dd5b2cd99 rdf:first N1fa24f7e05054887b6911bcf5a43ab02
183 rdf:rest Naff80418a4ef42eb999353a835a51e01
184 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
185 schema:name Chemical Sciences
186 rdf:type schema:DefinedTerm
187 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
188 schema:name Physical Chemistry (incl. Structural)
189 rdf:type schema:DefinedTerm
190 sg:journal.1043282 schema:issn 2041-1723
191 schema:name Nature Communications
192 rdf:type schema:Periodical
193 sg:pub.10.1007/bf02880404 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018828887
194 https://doi.org/10.1007/bf02880404
195 rdf:type schema:CreativeWork
196 sg:pub.10.1007/s11244-013-0159-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001484137
197 https://doi.org/10.1007/s11244-013-0159-2
198 rdf:type schema:CreativeWork
199 sg:pub.10.1038/nchem.121 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022136973
200 https://doi.org/10.1038/nchem.121
201 rdf:type schema:CreativeWork
202 sg:pub.10.1038/nchem.2915 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100239794
203 https://doi.org/10.1038/nchem.2915
204 rdf:type schema:CreativeWork
205 sg:pub.10.1038/nmat3143 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042490431
206 https://doi.org/10.1038/nmat3143
207 rdf:type schema:CreativeWork
208 sg:pub.10.1038/s41467-018-04845-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1104570282
209 https://doi.org/10.1038/s41467-018-04845-x
210 rdf:type schema:CreativeWork
211 sg:pub.10.1038/s41929-018-0028-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101324983
212 https://doi.org/10.1038/s41929-018-0028-2
213 rdf:type schema:CreativeWork
214 sg:pub.10.1038/s41929-018-0090-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104468866
215 https://doi.org/10.1038/s41929-018-0090-9
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1002/adfm.201002641 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053659973
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1002/anie.201108706 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049169475
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1002/anie.201405232 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044050092
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1002/cctc.201500666 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022799963
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1002/chem.201001330 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030879435
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1002/chem.201202802 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013647775
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1006/jcat.1995.1110 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038498789
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1016/0021-9517(68)90224-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014720465
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1016/j.apcata.2009.05.059 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030528120
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1016/j.cplett.2008.07.029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003469985
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1016/j.jcat.2007.07.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008767243
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1016/j.jcat.2010.11.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010232988
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1016/j.jcat.2011.04.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037983369
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1016/j.jcat.2011.11.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052131971
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1016/j.jcat.2013.07.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032287109
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1016/j.jcat.2017.10.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092545197
248 rdf:type schema:CreativeWork
249 https://doi.org/10.1021/acs.chemrev.7b00776 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103277743
250 rdf:type schema:CreativeWork
251 https://doi.org/10.1021/acs.jpcc.7b00139 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084123393
252 rdf:type schema:CreativeWork
253 https://doi.org/10.1021/acscatal.6b02720 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083550032
254 rdf:type schema:CreativeWork
255 https://doi.org/10.1021/acscatal.6b03293 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055134815
256 rdf:type schema:CreativeWork
257 https://doi.org/10.1021/ar300356m schema:sameAs https://app.dimensions.ai/details/publication/pub.1055150346
258 rdf:type schema:CreativeWork
259 https://doi.org/10.1021/ar500426g schema:sameAs https://app.dimensions.ai/details/publication/pub.1030042188
260 rdf:type schema:CreativeWork
261 https://doi.org/10.1021/cr0200116 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031651292
262 rdf:type schema:CreativeWork
263 https://doi.org/10.1021/cr040090g schema:sameAs https://app.dimensions.ai/details/publication/pub.1053830231
264 rdf:type schema:CreativeWork
265 https://doi.org/10.1021/cs200040a schema:sameAs https://app.dimensions.ai/details/publication/pub.1055421687
266 rdf:type schema:CreativeWork
267 https://doi.org/10.1021/cs300252g schema:sameAs https://app.dimensions.ai/details/publication/pub.1055421997
268 rdf:type schema:CreativeWork
269 https://doi.org/10.1021/cs500388x schema:sameAs https://app.dimensions.ai/details/publication/pub.1055422708
270 rdf:type schema:CreativeWork
271 https://doi.org/10.1021/cs501896c schema:sameAs https://app.dimensions.ai/details/publication/pub.1055423081
272 rdf:type schema:CreativeWork
273 https://doi.org/10.1021/j100016a053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055649235
274 rdf:type schema:CreativeWork
275 https://doi.org/10.1021/j100852a052 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055682399
276 rdf:type schema:CreativeWork
277 https://doi.org/10.1021/ja403822d schema:sameAs https://app.dimensions.ai/details/publication/pub.1055854650
278 rdf:type schema:CreativeWork
279 https://doi.org/10.1021/ja971039f schema:sameAs https://app.dimensions.ai/details/publication/pub.1055867481
280 rdf:type schema:CreativeWork
281 https://doi.org/10.1021/jacs.7b01471 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085466682
282 rdf:type schema:CreativeWork
283 https://doi.org/10.1021/jacs.7b01632 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084864440
284 rdf:type schema:CreativeWork
285 https://doi.org/10.1021/jp4061686 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056096307
286 rdf:type schema:CreativeWork
287 https://doi.org/10.1021/jp808362m schema:sameAs https://app.dimensions.ai/details/publication/pub.1056111261
288 rdf:type schema:CreativeWork
289 https://doi.org/10.1021/jp9037182 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056115251
290 rdf:type schema:CreativeWork
291 https://doi.org/10.1021/la5001304 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056159249
292 rdf:type schema:CreativeWork
293 https://doi.org/10.1021/nn302299e schema:sameAs https://app.dimensions.ai/details/publication/pub.1056224514
294 rdf:type schema:CreativeWork
295 https://doi.org/10.1039/b518069d schema:sameAs https://app.dimensions.ai/details/publication/pub.1030880455
296 rdf:type schema:CreativeWork
297 https://doi.org/10.1039/c1nr11052g schema:sameAs https://app.dimensions.ai/details/publication/pub.1010466170
298 rdf:type schema:CreativeWork
299 https://doi.org/10.1039/c2cs35160a schema:sameAs https://app.dimensions.ai/details/publication/pub.1035965317
300 rdf:type schema:CreativeWork
301 https://doi.org/10.1039/c2cy00487a schema:sameAs https://app.dimensions.ai/details/publication/pub.1013607816
302 rdf:type schema:CreativeWork
303 https://doi.org/10.1039/c4cy00976b schema:sameAs https://app.dimensions.ai/details/publication/pub.1029323884
304 rdf:type schema:CreativeWork
305 https://doi.org/10.1039/c5cs00350d schema:sameAs https://app.dimensions.ai/details/publication/pub.1028207240
306 rdf:type schema:CreativeWork
307 https://doi.org/10.1063/1.1737365 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057802354
308 rdf:type schema:CreativeWork
309 https://doi.org/10.1080/01614947208062259 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020329647
310 rdf:type schema:CreativeWork
311 https://doi.org/10.1088/0305-4608/4/12/015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059084589
312 rdf:type schema:CreativeWork
313 https://doi.org/10.1103/physrevb.24.1725 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060529235
314 rdf:type schema:CreativeWork
315 https://doi.org/10.1103/physrevb.36.2972 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060543638
316 rdf:type schema:CreativeWork
317 https://doi.org/10.1103/physrevb.4.4139 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060550866
318 rdf:type schema:CreativeWork
319 https://doi.org/10.1103/physrevb.43.4659 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060557613
320 rdf:type schema:CreativeWork
321 https://doi.org/10.1103/physrevb.47.4873 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060566188
322 rdf:type schema:CreativeWork
323 https://doi.org/10.1103/physrevb.52.16443 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060577815
324 rdf:type schema:CreativeWork
325 https://doi.org/10.1103/physrevb.56.5822 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060586399
326 rdf:type schema:CreativeWork
327 https://doi.org/10.1103/physrevb.72.064203 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060614626
328 rdf:type schema:CreativeWork
329 https://doi.org/10.1103/physrevb.89.115114 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060643013
330 rdf:type schema:CreativeWork
331 https://doi.org/10.1126/science.1120560 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028356846
332 rdf:type schema:CreativeWork
333 https://doi.org/10.1126/science.1195055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062462734
334 rdf:type schema:CreativeWork
335 https://doi.org/10.1126/science.aan6515 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091615551
336 rdf:type schema:CreativeWork
337 https://www.grid.ac/institutes/grid.28056.39 schema:alternateName East China University of Science and Technology
338 schema:name State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 200237, Shanghai, China
339 rdf:type schema:Organization
340 https://www.grid.ac/institutes/grid.412531.0 schema:alternateName Shanghai Normal University
341 schema:name Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Department of Chemistry, Shanghai Normal University, 200234, Shanghai, China
342 rdf:type schema:Organization
343 https://www.grid.ac/institutes/grid.450275.1 schema:alternateName Shanghai Institute of Applied Physics
344 schema:name Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 201204, Shanghai, China
345 rdf:type schema:Organization
346 https://www.grid.ac/institutes/grid.5947.f schema:alternateName Norwegian University of Science and Technology
347 schema:name Department of Chemical Engineering, Norwegian University of Science and Technology, N-7491, Trondheim, Norway
348 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...