Dynamic emission Stokes shift and liquid-like dielectric solvation of band edge carriers in lead-halide perovskites View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Yinsheng Guo, Omer Yaffe, Trevor D. Hull, Jonathan S. Owen, David R. Reichman, Louis E. Brus

ABSTRACT

Lead-halide perovskites have emerged as promising materials for photovoltaic and optoelectronic applications. Their significantly anharmonic lattice motion, in contrast to conventional harmonic semiconductors, presents a conceptual challenge in understanding the genesis of their exceptional optoelectronic properties. Here we report a strongly temperature dependent luminescence Stokes shift in the electronic spectra of both hybrid and inorganic lead-bromide perovskite single crystals. This behavior stands in stark contrast to that exhibited by more conventional crystalline semiconductors. We correlate the electronic spectra with the anti-Stokes and Stokes Raman vibrational spectra. Dielectric solvation theories, originally developed for excited molecules dissolved in polar liquids, reproduce our experimental observations. Our approach, which invokes a classical Debye-like relaxation process, captures the dielectric response originating from the incipient anharmonicity of the LO phonon at about 20 meV (160 cm-1) in the lead-bromide framework. We reconcile this liquid-like model incorporating thermally-activated dielectric solvation with more standard solid-state theories of the emission Stokes shift in crystalline semiconductors. More... »

PAGES

1175

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-019-09057-5

DOI

http://dx.doi.org/10.1038/s41467-019-09057-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112706415

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30862815


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Columbia University", 
          "id": "https://www.grid.ac/institutes/grid.21729.3f", 
          "name": [
            "Department of Chemistry, Columbia University, 10027, New York, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Guo", 
        "givenName": "Yinsheng", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Weizmann Institute of Science", 
          "id": "https://www.grid.ac/institutes/grid.13992.30", 
          "name": [
            "Department of Materials and Interfaces, Weizmann Institute of Science, 76100, Rehovot, Israel"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yaffe", 
        "givenName": "Omer", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Columbia University", 
          "id": "https://www.grid.ac/institutes/grid.21729.3f", 
          "name": [
            "Department of Chemistry, Columbia University, 10027, New York, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hull", 
        "givenName": "Trevor D.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Columbia University", 
          "id": "https://www.grid.ac/institutes/grid.21729.3f", 
          "name": [
            "Department of Chemistry, Columbia University, 10027, New York, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Owen", 
        "givenName": "Jonathan S.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Columbia University", 
          "id": "https://www.grid.ac/institutes/grid.21729.3f", 
          "name": [
            "Department of Chemistry, Columbia University, 10027, New York, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Reichman", 
        "givenName": "David R.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Columbia University", 
          "id": "https://www.grid.ac/institutes/grid.21729.3f", 
          "name": [
            "Department of Chemistry, Columbia University, 10027, New York, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brus", 
        "givenName": "Louis E.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0009-2614(89)87399-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002100156"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1006814379", 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1006814379", 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.4890246", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007845668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.28.690", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008130045"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/natrevmats.2015.7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013930670", 
          "https://doi.org/10.1038/natrevmats.2015.7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6mh00275g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014243260"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.4949760", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016352523"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2015.90", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016821296", 
          "https://doi.org/10.1038/nnano.2015.90"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3697(92)90121-s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020307803"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3697(92)90121-s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020307803"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.jpclett.5b02462", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024000956"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5ta01125f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030056114"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/19/25/255208", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030362100"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5cp02093j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033782718"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6cp03474h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039808768"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.aaf9570", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041832687"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms11755", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045020501", 
          "https://doi.org/10.1038/ncomms11755"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.nanolett.5b01854", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045102337"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0301-0104(84)80014-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053149181"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0034-4885/31/1/303", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053647478"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acsnano.6b02734", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055137948"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00237a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055716614"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp067273m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056069269"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp067273m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056069269"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp106271n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056078353"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp106271n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056078353"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp960887e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056121859"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp960887e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056121859"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1533093", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057717257"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1708150", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057777040"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.453467", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058031483"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.454929", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058032941"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.459596", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058037607"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.4858195", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058087963"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.88755", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058128895"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0022-3719/10/17/022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058956391"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.76.155314", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060622683"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.76.155314", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060622683"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.90.195201", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060644912"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.90.195201", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060644912"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.91.144107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060645650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.91.144107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060645650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.70.323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060806929"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.70.323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060806929"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/revmodphys.46.83", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060838780"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/revmodphys.46.83", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060838780"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/revmodphys.65.599", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060839297"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/revmodphys.65.599", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060839297"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1143/jjap.7.243", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1063090188"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1364/josa.55.001205", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065149554"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1364/ol.40.002580", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065237658"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.118.136001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084199286"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.118.136001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084199286"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aenm.201700600", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085591553"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.1702429114", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085898442"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.nanolett.7b02248", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090392967"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.96.035305", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090783977"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.96.035305", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090783977"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/sciadv.1602388", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090902256"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/sciadv.1701217", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1091163994"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevmaterials.1.042401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092017180"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevmaterials.1.042401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092017180"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acsenergylett.7b00790", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092023217"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.96.195202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092583001"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.96.195202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092583001"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.96.195203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092583002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.96.195203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092583002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.jpclett.7b02979", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100163692"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41467-017-02670-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100351826", 
          "https://doi.org/10.1038/s41467-017-02670-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41563-018-0068-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103565811", 
          "https://doi.org/10.1038/s41563-018-0068-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41563-018-0070-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103565813", 
          "https://doi.org/10.1038/s41563-018-0070-0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41467-018-04367-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103956843", 
          "https://doi.org/10.1038/s41467-018-04367-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.nanolett.8b04276", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1107983025"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-12", 
    "datePublishedReg": "2019-12-01", 
    "description": "Lead-halide perovskites have emerged as promising materials for photovoltaic and optoelectronic applications. Their significantly anharmonic lattice motion, in contrast to conventional harmonic semiconductors, presents a conceptual challenge in understanding the genesis of their exceptional optoelectronic properties. Here we report a strongly temperature dependent luminescence Stokes shift in the electronic spectra of both hybrid and inorganic lead-bromide perovskite single crystals. This behavior stands in stark contrast to that exhibited by more conventional crystalline semiconductors. We correlate the electronic spectra with the anti-Stokes and Stokes Raman vibrational spectra. Dielectric solvation theories, originally developed for excited molecules dissolved in polar liquids, reproduce our experimental observations. Our approach, which invokes a classical Debye-like relaxation process, captures the dielectric response originating from the incipient anharmonicity of the LO phonon at about 20\u2009meV (160\u2009cm-1) in the lead-bromide framework. We reconcile this liquid-like model incorporating thermally-activated dielectric solvation with more standard solid-state theories of the emission Stokes shift in crystalline semiconductors.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/s41467-019-09057-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.3852388", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.3935364", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.3794000", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1043282", 
        "issn": [
          "2041-1723"
        ], 
        "name": "Nature Communications", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "10"
      }
    ], 
    "name": "Dynamic emission Stokes shift and liquid-like dielectric solvation of band edge carriers in lead-halide perovskites", 
    "pagination": "1175", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5a009d2d80d0d07ca387c288807b45c631bc1916c61d9d9b8ee8ba24dc781ba5"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "30862815"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101528555"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/s41467-019-09057-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112706415"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/s41467-019-09057-5", 
      "https://app.dimensions.ai/details/publication/pub.1112706415"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000368_0000000368/records_78959_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/s41467-019-09057-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09057-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09057-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09057-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-09057-5'


 

This table displays all metadata directly associated to this object as RDF triples.

286 TRIPLES      21 PREDICATES      87 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/s41467-019-09057-5 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N2901003564d941a5bcbc677aa922859c
4 schema:citation sg:pub.10.1038/natrevmats.2015.7
5 sg:pub.10.1038/ncomms11755
6 sg:pub.10.1038/nnano.2015.90
7 sg:pub.10.1038/s41467-017-02670-2
8 sg:pub.10.1038/s41467-018-04367-6
9 sg:pub.10.1038/s41563-018-0068-7
10 sg:pub.10.1038/s41563-018-0070-0
11 https://app.dimensions.ai/details/publication/pub.1006814379
12 https://doi.org/10.1002/aenm.201700600
13 https://doi.org/10.1016/0022-3697(92)90121-s
14 https://doi.org/10.1016/0301-0104(84)80014-2
15 https://doi.org/10.1016/s0009-2614(89)87399-3
16 https://doi.org/10.1021/acs.jpclett.5b02462
17 https://doi.org/10.1021/acs.jpclett.7b02979
18 https://doi.org/10.1021/acs.nanolett.5b01854
19 https://doi.org/10.1021/acs.nanolett.7b02248
20 https://doi.org/10.1021/acs.nanolett.8b04276
21 https://doi.org/10.1021/acsenergylett.7b00790
22 https://doi.org/10.1021/acsnano.6b02734
23 https://doi.org/10.1021/ja00237a013
24 https://doi.org/10.1021/jp067273m
25 https://doi.org/10.1021/jp106271n
26 https://doi.org/10.1021/jp960887e
27 https://doi.org/10.1039/c5cp02093j
28 https://doi.org/10.1039/c5ta01125f
29 https://doi.org/10.1039/c6cp03474h
30 https://doi.org/10.1039/c6mh00275g
31 https://doi.org/10.1063/1.1533093
32 https://doi.org/10.1063/1.1708150
33 https://doi.org/10.1063/1.453467
34 https://doi.org/10.1063/1.454929
35 https://doi.org/10.1063/1.459596
36 https://doi.org/10.1063/1.4858195
37 https://doi.org/10.1063/1.4890246
38 https://doi.org/10.1063/1.4949760
39 https://doi.org/10.1063/1.88755
40 https://doi.org/10.1073/pnas.1702429114
41 https://doi.org/10.1088/0022-3719/10/17/022
42 https://doi.org/10.1088/0034-4885/31/1/303
43 https://doi.org/10.1088/0953-8984/19/25/255208
44 https://doi.org/10.1103/physrevb.76.155314
45 https://doi.org/10.1103/physrevb.90.195201
46 https://doi.org/10.1103/physrevb.91.144107
47 https://doi.org/10.1103/physrevb.96.035305
48 https://doi.org/10.1103/physrevb.96.195202
49 https://doi.org/10.1103/physrevb.96.195203
50 https://doi.org/10.1103/physrevlett.118.136001
51 https://doi.org/10.1103/physrevlett.70.323
52 https://doi.org/10.1103/physrevmaterials.1.042401
53 https://doi.org/10.1103/revmodphys.46.83
54 https://doi.org/10.1103/revmodphys.65.599
55 https://doi.org/10.1126/sciadv.1602388
56 https://doi.org/10.1126/sciadv.1701217
57 https://doi.org/10.1126/science.aaf9570
58 https://doi.org/10.1143/jjap.7.243
59 https://doi.org/10.1246/bcsj.28.690
60 https://doi.org/10.1364/josa.55.001205
61 https://doi.org/10.1364/ol.40.002580
62 schema:datePublished 2019-12
63 schema:datePublishedReg 2019-12-01
64 schema:description Lead-halide perovskites have emerged as promising materials for photovoltaic and optoelectronic applications. Their significantly anharmonic lattice motion, in contrast to conventional harmonic semiconductors, presents a conceptual challenge in understanding the genesis of their exceptional optoelectronic properties. Here we report a strongly temperature dependent luminescence Stokes shift in the electronic spectra of both hybrid and inorganic lead-bromide perovskite single crystals. This behavior stands in stark contrast to that exhibited by more conventional crystalline semiconductors. We correlate the electronic spectra with the anti-Stokes and Stokes Raman vibrational spectra. Dielectric solvation theories, originally developed for excited molecules dissolved in polar liquids, reproduce our experimental observations. Our approach, which invokes a classical Debye-like relaxation process, captures the dielectric response originating from the incipient anharmonicity of the LO phonon at about 20 meV (160 cm<sup>-1</sup>) in the lead-bromide framework. We reconcile this liquid-like model incorporating thermally-activated dielectric solvation with more standard solid-state theories of the emission Stokes shift in crystalline semiconductors.
65 schema:genre research_article
66 schema:inLanguage en
67 schema:isAccessibleForFree true
68 schema:isPartOf N63f390bc882546f19ebae4c28913a40c
69 Nf47d75eb0e2c48d58ac7abf927518b9e
70 sg:journal.1043282
71 schema:name Dynamic emission Stokes shift and liquid-like dielectric solvation of band edge carriers in lead-halide perovskites
72 schema:pagination 1175
73 schema:productId N994cca7138c64d20a47df313896cfa43
74 Na40bfa562f1f495fa67072e63c94222c
75 Nb5194fda589045e3a35591117557090a
76 Nc22ef4d4690541b7bce72de4a65a0fbc
77 Nc3266968fbf74174b590aae6ab1fc03b
78 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112706415
79 https://doi.org/10.1038/s41467-019-09057-5
80 schema:sdDatePublished 2019-04-11T13:19
81 schema:sdLicense https://scigraph.springernature.com/explorer/license/
82 schema:sdPublisher Ne76cc828b6f64ead83b0b98d00c46596
83 schema:url https://www.nature.com/articles/s41467-019-09057-5
84 sgo:license sg:explorer/license/
85 sgo:sdDataset articles
86 rdf:type schema:ScholarlyArticle
87 N0342dadea3744a05a1c7644cfc554ffa schema:affiliation https://www.grid.ac/institutes/grid.21729.3f
88 schema:familyName Brus
89 schema:givenName Louis E.
90 rdf:type schema:Person
91 N2102daf5438f4a2381b2a874d09ce1c2 schema:affiliation https://www.grid.ac/institutes/grid.21729.3f
92 schema:familyName Hull
93 schema:givenName Trevor D.
94 rdf:type schema:Person
95 N2901003564d941a5bcbc677aa922859c rdf:first Nd10624c0b34c4fbd8f3d209d9b95347a
96 rdf:rest Nc6fcb784fab942b59d6d0feb74b47909
97 N44e1e5e2870e4daf9e79309a332eedb1 rdf:first N87d8dda589564e248631e8d29e1bc578
98 rdf:rest N5d59847bc8f64153acb938fedf2dff68
99 N46c8d4d59dc94f7f8b39bc9b35d0b078 rdf:first N2102daf5438f4a2381b2a874d09ce1c2
100 rdf:rest N634461fcced241edbb64d37b267e6055
101 N53cc8b062ec94429930c3e3e6fb94579 schema:affiliation https://www.grid.ac/institutes/grid.13992.30
102 schema:familyName Yaffe
103 schema:givenName Omer
104 rdf:type schema:Person
105 N5d59847bc8f64153acb938fedf2dff68 rdf:first N0342dadea3744a05a1c7644cfc554ffa
106 rdf:rest rdf:nil
107 N634461fcced241edbb64d37b267e6055 rdf:first N833ba6a545c14ff3b6e29068ca02eab7
108 rdf:rest N44e1e5e2870e4daf9e79309a332eedb1
109 N63f390bc882546f19ebae4c28913a40c schema:volumeNumber 10
110 rdf:type schema:PublicationVolume
111 N833ba6a545c14ff3b6e29068ca02eab7 schema:affiliation https://www.grid.ac/institutes/grid.21729.3f
112 schema:familyName Owen
113 schema:givenName Jonathan S.
114 rdf:type schema:Person
115 N87d8dda589564e248631e8d29e1bc578 schema:affiliation https://www.grid.ac/institutes/grid.21729.3f
116 schema:familyName Reichman
117 schema:givenName David R.
118 rdf:type schema:Person
119 N994cca7138c64d20a47df313896cfa43 schema:name doi
120 schema:value 10.1038/s41467-019-09057-5
121 rdf:type schema:PropertyValue
122 Na40bfa562f1f495fa67072e63c94222c schema:name pubmed_id
123 schema:value 30862815
124 rdf:type schema:PropertyValue
125 Nb5194fda589045e3a35591117557090a schema:name readcube_id
126 schema:value 5a009d2d80d0d07ca387c288807b45c631bc1916c61d9d9b8ee8ba24dc781ba5
127 rdf:type schema:PropertyValue
128 Nc22ef4d4690541b7bce72de4a65a0fbc schema:name dimensions_id
129 schema:value pub.1112706415
130 rdf:type schema:PropertyValue
131 Nc3266968fbf74174b590aae6ab1fc03b schema:name nlm_unique_id
132 schema:value 101528555
133 rdf:type schema:PropertyValue
134 Nc6fcb784fab942b59d6d0feb74b47909 rdf:first N53cc8b062ec94429930c3e3e6fb94579
135 rdf:rest N46c8d4d59dc94f7f8b39bc9b35d0b078
136 Nd10624c0b34c4fbd8f3d209d9b95347a schema:affiliation https://www.grid.ac/institutes/grid.21729.3f
137 schema:familyName Guo
138 schema:givenName Yinsheng
139 rdf:type schema:Person
140 Ne76cc828b6f64ead83b0b98d00c46596 schema:name Springer Nature - SN SciGraph project
141 rdf:type schema:Organization
142 Nf47d75eb0e2c48d58ac7abf927518b9e schema:issueNumber 1
143 rdf:type schema:PublicationIssue
144 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
145 schema:name Engineering
146 rdf:type schema:DefinedTerm
147 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
148 schema:name Materials Engineering
149 rdf:type schema:DefinedTerm
150 sg:grant.3794000 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-09057-5
151 rdf:type schema:MonetaryGrant
152 sg:grant.3852388 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-09057-5
153 rdf:type schema:MonetaryGrant
154 sg:grant.3935364 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-09057-5
155 rdf:type schema:MonetaryGrant
156 sg:journal.1043282 schema:issn 2041-1723
157 schema:name Nature Communications
158 rdf:type schema:Periodical
159 sg:pub.10.1038/natrevmats.2015.7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013930670
160 https://doi.org/10.1038/natrevmats.2015.7
161 rdf:type schema:CreativeWork
162 sg:pub.10.1038/ncomms11755 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045020501
163 https://doi.org/10.1038/ncomms11755
164 rdf:type schema:CreativeWork
165 sg:pub.10.1038/nnano.2015.90 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016821296
166 https://doi.org/10.1038/nnano.2015.90
167 rdf:type schema:CreativeWork
168 sg:pub.10.1038/s41467-017-02670-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100351826
169 https://doi.org/10.1038/s41467-017-02670-2
170 rdf:type schema:CreativeWork
171 sg:pub.10.1038/s41467-018-04367-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103956843
172 https://doi.org/10.1038/s41467-018-04367-6
173 rdf:type schema:CreativeWork
174 sg:pub.10.1038/s41563-018-0068-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103565811
175 https://doi.org/10.1038/s41563-018-0068-7
176 rdf:type schema:CreativeWork
177 sg:pub.10.1038/s41563-018-0070-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103565813
178 https://doi.org/10.1038/s41563-018-0070-0
179 rdf:type schema:CreativeWork
180 https://app.dimensions.ai/details/publication/pub.1006814379 schema:CreativeWork
181 https://doi.org/10.1002/aenm.201700600 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085591553
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1016/0022-3697(92)90121-s schema:sameAs https://app.dimensions.ai/details/publication/pub.1020307803
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1016/0301-0104(84)80014-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053149181
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1016/s0009-2614(89)87399-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002100156
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1021/acs.jpclett.5b02462 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024000956
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1021/acs.jpclett.7b02979 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100163692
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1021/acs.nanolett.5b01854 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045102337
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1021/acs.nanolett.7b02248 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090392967
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1021/acs.nanolett.8b04276 schema:sameAs https://app.dimensions.ai/details/publication/pub.1107983025
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1021/acsenergylett.7b00790 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092023217
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1021/acsnano.6b02734 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055137948
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1021/ja00237a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055716614
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1021/jp067273m schema:sameAs https://app.dimensions.ai/details/publication/pub.1056069269
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1021/jp106271n schema:sameAs https://app.dimensions.ai/details/publication/pub.1056078353
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1021/jp960887e schema:sameAs https://app.dimensions.ai/details/publication/pub.1056121859
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1039/c5cp02093j schema:sameAs https://app.dimensions.ai/details/publication/pub.1033782718
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1039/c5ta01125f schema:sameAs https://app.dimensions.ai/details/publication/pub.1030056114
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1039/c6cp03474h schema:sameAs https://app.dimensions.ai/details/publication/pub.1039808768
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1039/c6mh00275g schema:sameAs https://app.dimensions.ai/details/publication/pub.1014243260
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1063/1.1533093 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057717257
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1063/1.1708150 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057777040
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1063/1.453467 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058031483
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1063/1.454929 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058032941
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1063/1.459596 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058037607
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1063/1.4858195 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058087963
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1063/1.4890246 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007845668
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1063/1.4949760 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016352523
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1063/1.88755 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058128895
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1073/pnas.1702429114 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085898442
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1088/0022-3719/10/17/022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058956391
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1088/0034-4885/31/1/303 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053647478
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1088/0953-8984/19/25/255208 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030362100
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1103/physrevb.76.155314 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060622683
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1103/physrevb.90.195201 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060644912
248 rdf:type schema:CreativeWork
249 https://doi.org/10.1103/physrevb.91.144107 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060645650
250 rdf:type schema:CreativeWork
251 https://doi.org/10.1103/physrevb.96.035305 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090783977
252 rdf:type schema:CreativeWork
253 https://doi.org/10.1103/physrevb.96.195202 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092583001
254 rdf:type schema:CreativeWork
255 https://doi.org/10.1103/physrevb.96.195203 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092583002
256 rdf:type schema:CreativeWork
257 https://doi.org/10.1103/physrevlett.118.136001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084199286
258 rdf:type schema:CreativeWork
259 https://doi.org/10.1103/physrevlett.70.323 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060806929
260 rdf:type schema:CreativeWork
261 https://doi.org/10.1103/physrevmaterials.1.042401 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092017180
262 rdf:type schema:CreativeWork
263 https://doi.org/10.1103/revmodphys.46.83 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060838780
264 rdf:type schema:CreativeWork
265 https://doi.org/10.1103/revmodphys.65.599 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060839297
266 rdf:type schema:CreativeWork
267 https://doi.org/10.1126/sciadv.1602388 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090902256
268 rdf:type schema:CreativeWork
269 https://doi.org/10.1126/sciadv.1701217 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091163994
270 rdf:type schema:CreativeWork
271 https://doi.org/10.1126/science.aaf9570 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041832687
272 rdf:type schema:CreativeWork
273 https://doi.org/10.1143/jjap.7.243 schema:sameAs https://app.dimensions.ai/details/publication/pub.1063090188
274 rdf:type schema:CreativeWork
275 https://doi.org/10.1246/bcsj.28.690 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008130045
276 rdf:type schema:CreativeWork
277 https://doi.org/10.1364/josa.55.001205 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065149554
278 rdf:type schema:CreativeWork
279 https://doi.org/10.1364/ol.40.002580 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065237658
280 rdf:type schema:CreativeWork
281 https://www.grid.ac/institutes/grid.13992.30 schema:alternateName Weizmann Institute of Science
282 schema:name Department of Materials and Interfaces, Weizmann Institute of Science, 76100, Rehovot, Israel
283 rdf:type schema:Organization
284 https://www.grid.ac/institutes/grid.21729.3f schema:alternateName Columbia University
285 schema:name Department of Chemistry, Columbia University, 10027, New York, NY, USA
286 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...