Self- regeneration of Au/CeO2 based catalysts with enhanced activity and ultra-stability for acetylene hydrochlorination View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Lin Ye, Xinping Duan, Simson Wu, Tai-Sing Wu, Yuxin Zhao, Alex W. Robertson, Hung-Lung Chou, Jianwei Zheng, Tuğçe Ayvalı, Sarah Day, Chiu Tang, Yun-Liang Soo, Youzhu Yuan, Shik Chi Edman Tsang

ABSTRACT

Replacement of Hg with non-toxic Au based catalysts for industrial hydrochlorination of acetylene to vinyl chloride is urgently required. However Au catalysts suffer from progressive deactivation caused by auto-reduction of Au(I) and Au(III) active sites and irreversible aggregation of Au(0) inactive sites. Here we show from synchrotron X-ray absorption, STEM imaging and DFT modelling that the availability of ceria(110) surface renders Au(0)/Au(I) as active pairs. Thus, Au(0) is directly involved in the catalysis. Owing to the strong mediating properties of Ce(IV)/Ce(III) with one electron complementary redox coupling reactions, the ceria promotion to Au catalysts gives enhanced activity and stability. Total pre-reduction of Au species to inactive Au nanoparticles of Au/CeO2&AC when placed in a C2H2/HCl stream can also rapidly rejuvenate. This is dramatically achieved by re-dispersing the Au particles to Au(0) atoms and oxidising to Au(I) entities, whereas Au/AC does not recover from the deactivation. More... »

PAGES

914

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-019-08827-5

DOI

http://dx.doi.org/10.1038/s41467-019-08827-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112308272

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30796236


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