Direct solution-phase synthesis of 1T’ WSe2 nanosheets View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Maria S. Sokolikova, Peter C. Sherrell, Pawel Palczynski, Victoria L. Bemmer, Cecilia Mattevi

ABSTRACT

Crystal phase control in layered transition metal dichalcogenides is central for exploiting their different electronic properties. Access to metastable crystal phases is limited as their direct synthesis is challenging, restricting the spectrum of reachable materials. Here, we demonstrate the solution phase synthesis of the metastable distorted octahedrally coordinated structure (1T' phase) of WSe2 nanosheets. We design a kinetically-controlled regime of colloidal synthesis to enable the formation of the metastable phase. 1T' WSe2 branched few-layered nanosheets are produced in high yield and in a reproducible and controlled manner. The 1T' phase is fully convertible into the semiconducting 2H phase upon thermal annealing at 400 °C. The 1T' WSe2 nanosheets demonstrate a metallic nature exhibited by an enhanced electrocatalytic activity for hydrogen evolution reaction as compared to the 2H WSe2 nanosheets and comparable to other 1T' phases. This synthesis design can potentially be extended to different materials providing direct access of metastable phases. More... »

PAGES

712

References to SciGraph publications

  • 2016-02-12. Structural semiconductor-to-semimetal phase transition in two-dimensional materials induced by electrostatic gating in NATURE COMMUNICATIONS
  • 2015-09. Tungsten Ditelluride: a layered semimetal in SCIENTIFIC REPORTS
  • 2018-12. Large quantum-spin-Hall gap in single-layer 1T′ WSe2 in NATURE COMMUNICATIONS
  • 2017-09. Metallic molybdenum disulfide nanosheet-based electrochemical actuators in NATURE
  • 2016-03. Catalysis with two-dimensional materials and their heterostructures in NATURE NANOTECHNOLOGY
  • 2014-12. Structural phase transitions in two-dimensional Mo- and W-dichalcogenide monolayers in NATURE COMMUNICATIONS
  • 2014-12. Few-layer molybdenum disulfide transistors and circuits for high-speed flexible electronics in NATURE COMMUNICATIONS
  • 2018-06. High phase-purity 1T′-MoS2- and 1T′-MoSe2-layered crystals in NATURE CHEMISTRY
  • 2013-09. Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution in NATURE MATERIALS
  • 2015-12. Self-assembled 2D WSe2 thin films for photoelectrochemical hydrogen production in NATURE COMMUNICATIONS
  • 2017-07. Edge conduction in monolayer WTe2 in NATURE PHYSICS
  • 2015-06. Bandgap opening in few-layered monoclinic MoTe2 in NATURE PHYSICS
  • 2018-10-15. Phase-selective synthesis of 1T′ MoS2 monolayers and heterophase bilayers in NATURE MATERIALS
  • 2005-09. Colloidal nanocrystal synthesis and the organic–inorganic interface in NATURE
  • 2017-12. High-Mobility and High-Optical Quality Atomically Thin WS2 in SCIENTIFIC REPORTS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/s41467-019-08594-3

    DOI

    http://dx.doi.org/10.1038/s41467-019-08594-3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1112068918

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/30755619


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Materials Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Imperial College London", 
              "id": "https://www.grid.ac/institutes/grid.7445.2", 
              "name": [
                "Department of Materials, Imperial College London, SW7 2AZ, London, UK"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sokolikova", 
            "givenName": "Maria S.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Imperial College London", 
              "id": "https://www.grid.ac/institutes/grid.7445.2", 
              "name": [
                "Department of Materials, Imperial College London, SW7 2AZ, London, UK"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sherrell", 
            "givenName": "Peter C.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Imperial College London", 
              "id": "https://www.grid.ac/institutes/grid.7445.2", 
              "name": [
                "Department of Materials, Imperial College London, SW7 2AZ, London, UK"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Palczynski", 
            "givenName": "Pawel", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Imperial College London", 
              "id": "https://www.grid.ac/institutes/grid.7445.2", 
              "name": [
                "Department of Materials, Imperial College London, SW7 2AZ, London, UK"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Bemmer", 
            "givenName": "Victoria L.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Imperial College London", 
              "id": "https://www.grid.ac/institutes/grid.7445.2", 
              "name": [
                "Department of Materials, Imperial College London, SW7 2AZ, London, UK"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Mattevi", 
            "givenName": "Cecilia", 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1038/ncomms10671", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004281997", 
              "https://doi.org/10.1038/ncomms10671"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/srep10013", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004529818", 
              "https://doi.org/10.1038/srep10013"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/ncomms6143", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006171529", 
              "https://doi.org/10.1038/ncomms6143"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c6cc07832j", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008471902"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/nl504200y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013112395"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c6nr04775k", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013339361"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/nl403661s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018188457"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c6ta09409k", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018526455"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c4nr02716g", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021100177"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja506261t", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023406315"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c3cc45416a", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023875048"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/ncomms8596", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024404290", 
              "https://doi.org/10.1038/ncomms8596"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/ncomms5214", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029630399", 
              "https://doi.org/10.1038/ncomms5214"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c39920001386", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030574054"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/jacs.6b03714", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031871795"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/nn503832j", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031874223"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/adma.201502134", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1033634270"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nphys3314", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034846896", 
              "https://doi.org/10.1038/nphys3314"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nature04165", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037774712", 
              "https://doi.org/10.1038/nature04165"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nature04165", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037774712", 
              "https://doi.org/10.1038/nature04165"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nature04165", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037774712", 
              "https://doi.org/10.1038/nature04165"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/nl5036397", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038401130"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nnano.2015.340", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039604838", 
              "https://doi.org/10.1038/nnano.2015.340"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1103/physrevlett.111.136804", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040853259"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1103/physrevlett.111.136804", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040853259"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c5cc00803d", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043018480"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nmat3700", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048205566", 
              "https://doi.org/10.1038/nmat3700"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1126/science.1256815", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048460404"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.nanolett.6b01342", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048967913"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c5ta06840a", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053137141"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/nn405719x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053443572"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.chemmater.6b00379", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053765219"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.nanolett.6b02666", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055121694"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.nanolett.6b03467", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055121837"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsami.6b10972", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055132096"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acscatal.6b00761", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055134197"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.5b00501", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055136879"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.5b02399", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055137081"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/jacs.5b02772", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055873946"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c6tc05097b", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1083890224"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nphys4091", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1084758018", 
              "https://doi.org/10.1038/nphys4091"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nphys4091", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1084758018", 
              "https://doi.org/10.1038/nphys4091"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.nanolett.6b05199", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1085377893"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/adma.201700311", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1085443084"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c7nr04922f", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1091283539"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nature23668", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1091382614", 
              "https://doi.org/10.1038/nature23668"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nature23668", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1091382614", 
              "https://doi.org/10.1038/nature23668"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/s41598-017-14928-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1092429298", 
              "https://doi.org/10.1038/s41598-017-14928-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.7b06364", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1093099401"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.7b06364", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1093099401"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.7b06364", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1093099401"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.8b00398", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1100622035"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.8b00398", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1100622035"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acsnano.8b00398", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1100622035"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/c8ce00159f", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101142882"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/s41557-018-0035-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101891491", 
              "https://doi.org/10.1038/s41557-018-0035-6"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/s41557-018-0035-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101891491", 
              "https://doi.org/10.1038/s41557-018-0035-6"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/s41557-018-0035-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1101891491", 
              "https://doi.org/10.1038/s41557-018-0035-6"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/s41467-018-04395-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1103996415", 
              "https://doi.org/10.1038/s41467-018-04395-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/adfm.201801286", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1104255151"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/acs.nanolett.8b01341", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1105012596"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/s41563-018-0187-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1107542121", 
              "https://doi.org/10.1038/s41563-018-0187-1"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2019-12", 
        "datePublishedReg": "2019-12-01", 
        "description": "Crystal phase control in layered transition metal dichalcogenides is central for exploiting their different electronic properties. Access to metastable crystal phases is limited as their direct synthesis is challenging, restricting the spectrum of reachable materials. Here, we demonstrate the solution phase synthesis of the metastable distorted octahedrally coordinated structure (1T' phase) of WSe2 nanosheets. We design a kinetically-controlled regime of colloidal synthesis to enable the formation of the metastable phase. 1T' WSe2 branched few-layered nanosheets are produced in high yield and in a reproducible and controlled manner. The 1T' phase is fully convertible into the semiconducting 2H phase upon thermal annealing at 400\u2009\u00b0C. The 1T' WSe2 nanosheets demonstrate a metallic nature exhibited by an enhanced electrocatalytic activity for hydrogen evolution reaction as compared to the 2H WSe2 nanosheets and comparable to other 1T' phases. This synthesis design can potentially be extended to different materials providing direct access of metastable phases.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1038/s41467-019-08594-3", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": true, 
        "isFundedItemOf": [
          {
            "id": "sg:grant.2786229", 
            "type": "MonetaryGrant"
          }, 
          {
            "id": "sg:grant.3956845", 
            "type": "MonetaryGrant"
          }, 
          {
            "id": "sg:grant.2752435", 
            "type": "MonetaryGrant"
          }, 
          {
            "id": "sg:grant.2781251", 
            "type": "MonetaryGrant"
          }
        ], 
        "isPartOf": [
          {
            "id": "sg:journal.1043282", 
            "issn": [
              "2041-1723"
            ], 
            "name": "Nature Communications", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "1", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "10"
          }
        ], 
        "name": "Direct solution-phase synthesis of 1T\u2019 WSe2 nanosheets", 
        "pagination": "712", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "9728c0f4a50a043b90d83f5f0b79d3efae82c88c728ed4b374952220770c6f61"
            ]
          }, 
          {
            "name": "pubmed_id", 
            "type": "PropertyValue", 
            "value": [
              "30755619"
            ]
          }, 
          {
            "name": "nlm_unique_id", 
            "type": "PropertyValue", 
            "value": [
              "101528555"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1038/s41467-019-08594-3"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1112068918"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1038/s41467-019-08594-3", 
          "https://app.dimensions.ai/details/publication/pub.1112068918"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-11T12:53", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000364_0000000364/records_72856_00000001.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://www.nature.com/articles/s41467-019-08594-3"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08594-3'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08594-3'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08594-3'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08594-3'


     

    This table displays all metadata directly associated to this object as RDF triples.

    267 TRIPLES      21 PREDICATES      80 URIs      21 LITERALS      9 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1038/s41467-019-08594-3 schema:about anzsrc-for:09
    2 anzsrc-for:0912
    3 schema:author N5eccd6f5094648e5ab58d4a71bac8cde
    4 schema:citation sg:pub.10.1038/nature04165
    5 sg:pub.10.1038/nature23668
    6 sg:pub.10.1038/ncomms10671
    7 sg:pub.10.1038/ncomms5214
    8 sg:pub.10.1038/ncomms6143
    9 sg:pub.10.1038/ncomms8596
    10 sg:pub.10.1038/nmat3700
    11 sg:pub.10.1038/nnano.2015.340
    12 sg:pub.10.1038/nphys3314
    13 sg:pub.10.1038/nphys4091
    14 sg:pub.10.1038/s41467-018-04395-2
    15 sg:pub.10.1038/s41557-018-0035-6
    16 sg:pub.10.1038/s41563-018-0187-1
    17 sg:pub.10.1038/s41598-017-14928-2
    18 sg:pub.10.1038/srep10013
    19 https://doi.org/10.1002/adfm.201801286
    20 https://doi.org/10.1002/adma.201502134
    21 https://doi.org/10.1002/adma.201700311
    22 https://doi.org/10.1021/acs.chemmater.6b00379
    23 https://doi.org/10.1021/acs.nanolett.6b01342
    24 https://doi.org/10.1021/acs.nanolett.6b02666
    25 https://doi.org/10.1021/acs.nanolett.6b03467
    26 https://doi.org/10.1021/acs.nanolett.6b05199
    27 https://doi.org/10.1021/acs.nanolett.8b01341
    28 https://doi.org/10.1021/acsami.6b10972
    29 https://doi.org/10.1021/acscatal.6b00761
    30 https://doi.org/10.1021/acsnano.5b00501
    31 https://doi.org/10.1021/acsnano.5b02399
    32 https://doi.org/10.1021/acsnano.7b06364
    33 https://doi.org/10.1021/acsnano.8b00398
    34 https://doi.org/10.1021/ja506261t
    35 https://doi.org/10.1021/jacs.5b02772
    36 https://doi.org/10.1021/jacs.6b03714
    37 https://doi.org/10.1021/nl403661s
    38 https://doi.org/10.1021/nl5036397
    39 https://doi.org/10.1021/nl504200y
    40 https://doi.org/10.1021/nn405719x
    41 https://doi.org/10.1021/nn503832j
    42 https://doi.org/10.1039/c39920001386
    43 https://doi.org/10.1039/c3cc45416a
    44 https://doi.org/10.1039/c4nr02716g
    45 https://doi.org/10.1039/c5cc00803d
    46 https://doi.org/10.1039/c5ta06840a
    47 https://doi.org/10.1039/c6cc07832j
    48 https://doi.org/10.1039/c6nr04775k
    49 https://doi.org/10.1039/c6ta09409k
    50 https://doi.org/10.1039/c6tc05097b
    51 https://doi.org/10.1039/c7nr04922f
    52 https://doi.org/10.1039/c8ce00159f
    53 https://doi.org/10.1103/physrevlett.111.136804
    54 https://doi.org/10.1126/science.1256815
    55 schema:datePublished 2019-12
    56 schema:datePublishedReg 2019-12-01
    57 schema:description Crystal phase control in layered transition metal dichalcogenides is central for exploiting their different electronic properties. Access to metastable crystal phases is limited as their direct synthesis is challenging, restricting the spectrum of reachable materials. Here, we demonstrate the solution phase synthesis of the metastable distorted octahedrally coordinated structure (1T' phase) of WSe<sub>2</sub> nanosheets. We design a kinetically-controlled regime of colloidal synthesis to enable the formation of the metastable phase. 1T' WSe<sub>2</sub> branched few-layered nanosheets are produced in high yield and in a reproducible and controlled manner. The 1T' phase is fully convertible into the semiconducting 2H phase upon thermal annealing at 400 °C. The 1T' WSe<sub>2</sub> nanosheets demonstrate a metallic nature exhibited by an enhanced electrocatalytic activity for hydrogen evolution reaction as compared to the 2H WSe<sub>2</sub> nanosheets and comparable to other 1T' phases. This synthesis design can potentially be extended to different materials providing direct access of metastable phases.
    58 schema:genre research_article
    59 schema:inLanguage en
    60 schema:isAccessibleForFree true
    61 schema:isPartOf N4ff774ec403941f29a08209d06c00cd5
    62 Nc137077f29ac4d379e7fcfa286bac662
    63 sg:journal.1043282
    64 schema:name Direct solution-phase synthesis of 1T’ WSe2 nanosheets
    65 schema:pagination 712
    66 schema:productId N3478889c873546fea489dfb044122a00
    67 N53b9a2446e24467eac7bb120686d3f4c
    68 N77e5902c64274fcfb56da300a7d5497a
    69 N84d5fdca06b748129f19f9987bf6d768
    70 Nd0e9c6cf401e453eb3f3c9e737b68fd9
    71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112068918
    72 https://doi.org/10.1038/s41467-019-08594-3
    73 schema:sdDatePublished 2019-04-11T12:53
    74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    75 schema:sdPublisher N563ce3ceb80246e7a9aa8c63fdaeb75a
    76 schema:url https://www.nature.com/articles/s41467-019-08594-3
    77 sgo:license sg:explorer/license/
    78 sgo:sdDataset articles
    79 rdf:type schema:ScholarlyArticle
    80 N144b025aaba840faaee132ab0fae2995 schema:affiliation https://www.grid.ac/institutes/grid.7445.2
    81 schema:familyName Mattevi
    82 schema:givenName Cecilia
    83 rdf:type schema:Person
    84 N21a84ab47058449a8423e37881b7b26a schema:affiliation https://www.grid.ac/institutes/grid.7445.2
    85 schema:familyName Bemmer
    86 schema:givenName Victoria L.
    87 rdf:type schema:Person
    88 N3478889c873546fea489dfb044122a00 schema:name dimensions_id
    89 schema:value pub.1112068918
    90 rdf:type schema:PropertyValue
    91 N4e80093678bd4e9baa4c7bee95ccb7d8 rdf:first N21a84ab47058449a8423e37881b7b26a
    92 rdf:rest Nfec1416ae42a41b9a7d8c166ee005e4e
    93 N4ff774ec403941f29a08209d06c00cd5 schema:issueNumber 1
    94 rdf:type schema:PublicationIssue
    95 N53b9a2446e24467eac7bb120686d3f4c schema:name pubmed_id
    96 schema:value 30755619
    97 rdf:type schema:PropertyValue
    98 N563ce3ceb80246e7a9aa8c63fdaeb75a schema:name Springer Nature - SN SciGraph project
    99 rdf:type schema:Organization
    100 N5eccd6f5094648e5ab58d4a71bac8cde rdf:first Na4a35b4736bd42f394aa77431c2f787e
    101 rdf:rest N6d129a966b4c4e8fa1bdf63053139d99
    102 N695f786181a54d9c9e5883c5d9b6dcbc rdf:first Na5690eda93f24c6099cb1d947248828c
    103 rdf:rest N4e80093678bd4e9baa4c7bee95ccb7d8
    104 N6d129a966b4c4e8fa1bdf63053139d99 rdf:first N93d9eea0bf9b4c7a91b5d66fc0fb7289
    105 rdf:rest N695f786181a54d9c9e5883c5d9b6dcbc
    106 N77e5902c64274fcfb56da300a7d5497a schema:name nlm_unique_id
    107 schema:value 101528555
    108 rdf:type schema:PropertyValue
    109 N84d5fdca06b748129f19f9987bf6d768 schema:name doi
    110 schema:value 10.1038/s41467-019-08594-3
    111 rdf:type schema:PropertyValue
    112 N93d9eea0bf9b4c7a91b5d66fc0fb7289 schema:affiliation https://www.grid.ac/institutes/grid.7445.2
    113 schema:familyName Sherrell
    114 schema:givenName Peter C.
    115 rdf:type schema:Person
    116 Na4a35b4736bd42f394aa77431c2f787e schema:affiliation https://www.grid.ac/institutes/grid.7445.2
    117 schema:familyName Sokolikova
    118 schema:givenName Maria S.
    119 rdf:type schema:Person
    120 Na5690eda93f24c6099cb1d947248828c schema:affiliation https://www.grid.ac/institutes/grid.7445.2
    121 schema:familyName Palczynski
    122 schema:givenName Pawel
    123 rdf:type schema:Person
    124 Nc137077f29ac4d379e7fcfa286bac662 schema:volumeNumber 10
    125 rdf:type schema:PublicationVolume
    126 Nd0e9c6cf401e453eb3f3c9e737b68fd9 schema:name readcube_id
    127 schema:value 9728c0f4a50a043b90d83f5f0b79d3efae82c88c728ed4b374952220770c6f61
    128 rdf:type schema:PropertyValue
    129 Nfec1416ae42a41b9a7d8c166ee005e4e rdf:first N144b025aaba840faaee132ab0fae2995
    130 rdf:rest rdf:nil
    131 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    132 schema:name Engineering
    133 rdf:type schema:DefinedTerm
    134 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
    135 schema:name Materials Engineering
    136 rdf:type schema:DefinedTerm
    137 sg:grant.2752435 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-08594-3
    138 rdf:type schema:MonetaryGrant
    139 sg:grant.2781251 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-08594-3
    140 rdf:type schema:MonetaryGrant
    141 sg:grant.2786229 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-08594-3
    142 rdf:type schema:MonetaryGrant
    143 sg:grant.3956845 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-08594-3
    144 rdf:type schema:MonetaryGrant
    145 sg:journal.1043282 schema:issn 2041-1723
    146 schema:name Nature Communications
    147 rdf:type schema:Periodical
    148 sg:pub.10.1038/nature04165 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037774712
    149 https://doi.org/10.1038/nature04165
    150 rdf:type schema:CreativeWork
    151 sg:pub.10.1038/nature23668 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091382614
    152 https://doi.org/10.1038/nature23668
    153 rdf:type schema:CreativeWork
    154 sg:pub.10.1038/ncomms10671 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004281997
    155 https://doi.org/10.1038/ncomms10671
    156 rdf:type schema:CreativeWork
    157 sg:pub.10.1038/ncomms5214 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029630399
    158 https://doi.org/10.1038/ncomms5214
    159 rdf:type schema:CreativeWork
    160 sg:pub.10.1038/ncomms6143 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006171529
    161 https://doi.org/10.1038/ncomms6143
    162 rdf:type schema:CreativeWork
    163 sg:pub.10.1038/ncomms8596 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024404290
    164 https://doi.org/10.1038/ncomms8596
    165 rdf:type schema:CreativeWork
    166 sg:pub.10.1038/nmat3700 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048205566
    167 https://doi.org/10.1038/nmat3700
    168 rdf:type schema:CreativeWork
    169 sg:pub.10.1038/nnano.2015.340 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039604838
    170 https://doi.org/10.1038/nnano.2015.340
    171 rdf:type schema:CreativeWork
    172 sg:pub.10.1038/nphys3314 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034846896
    173 https://doi.org/10.1038/nphys3314
    174 rdf:type schema:CreativeWork
    175 sg:pub.10.1038/nphys4091 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084758018
    176 https://doi.org/10.1038/nphys4091
    177 rdf:type schema:CreativeWork
    178 sg:pub.10.1038/s41467-018-04395-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103996415
    179 https://doi.org/10.1038/s41467-018-04395-2
    180 rdf:type schema:CreativeWork
    181 sg:pub.10.1038/s41557-018-0035-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101891491
    182 https://doi.org/10.1038/s41557-018-0035-6
    183 rdf:type schema:CreativeWork
    184 sg:pub.10.1038/s41563-018-0187-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1107542121
    185 https://doi.org/10.1038/s41563-018-0187-1
    186 rdf:type schema:CreativeWork
    187 sg:pub.10.1038/s41598-017-14928-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092429298
    188 https://doi.org/10.1038/s41598-017-14928-2
    189 rdf:type schema:CreativeWork
    190 sg:pub.10.1038/srep10013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004529818
    191 https://doi.org/10.1038/srep10013
    192 rdf:type schema:CreativeWork
    193 https://doi.org/10.1002/adfm.201801286 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104255151
    194 rdf:type schema:CreativeWork
    195 https://doi.org/10.1002/adma.201502134 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033634270
    196 rdf:type schema:CreativeWork
    197 https://doi.org/10.1002/adma.201700311 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085443084
    198 rdf:type schema:CreativeWork
    199 https://doi.org/10.1021/acs.chemmater.6b00379 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053765219
    200 rdf:type schema:CreativeWork
    201 https://doi.org/10.1021/acs.nanolett.6b01342 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048967913
    202 rdf:type schema:CreativeWork
    203 https://doi.org/10.1021/acs.nanolett.6b02666 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055121694
    204 rdf:type schema:CreativeWork
    205 https://doi.org/10.1021/acs.nanolett.6b03467 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055121837
    206 rdf:type schema:CreativeWork
    207 https://doi.org/10.1021/acs.nanolett.6b05199 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085377893
    208 rdf:type schema:CreativeWork
    209 https://doi.org/10.1021/acs.nanolett.8b01341 schema:sameAs https://app.dimensions.ai/details/publication/pub.1105012596
    210 rdf:type schema:CreativeWork
    211 https://doi.org/10.1021/acsami.6b10972 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055132096
    212 rdf:type schema:CreativeWork
    213 https://doi.org/10.1021/acscatal.6b00761 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055134197
    214 rdf:type schema:CreativeWork
    215 https://doi.org/10.1021/acsnano.5b00501 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055136879
    216 rdf:type schema:CreativeWork
    217 https://doi.org/10.1021/acsnano.5b02399 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055137081
    218 rdf:type schema:CreativeWork
    219 https://doi.org/10.1021/acsnano.7b06364 schema:sameAs https://app.dimensions.ai/details/publication/pub.1093099401
    220 rdf:type schema:CreativeWork
    221 https://doi.org/10.1021/acsnano.8b00398 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100622035
    222 rdf:type schema:CreativeWork
    223 https://doi.org/10.1021/ja506261t schema:sameAs https://app.dimensions.ai/details/publication/pub.1023406315
    224 rdf:type schema:CreativeWork
    225 https://doi.org/10.1021/jacs.5b02772 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055873946
    226 rdf:type schema:CreativeWork
    227 https://doi.org/10.1021/jacs.6b03714 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031871795
    228 rdf:type schema:CreativeWork
    229 https://doi.org/10.1021/nl403661s schema:sameAs https://app.dimensions.ai/details/publication/pub.1018188457
    230 rdf:type schema:CreativeWork
    231 https://doi.org/10.1021/nl5036397 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038401130
    232 rdf:type schema:CreativeWork
    233 https://doi.org/10.1021/nl504200y schema:sameAs https://app.dimensions.ai/details/publication/pub.1013112395
    234 rdf:type schema:CreativeWork
    235 https://doi.org/10.1021/nn405719x schema:sameAs https://app.dimensions.ai/details/publication/pub.1053443572
    236 rdf:type schema:CreativeWork
    237 https://doi.org/10.1021/nn503832j schema:sameAs https://app.dimensions.ai/details/publication/pub.1031874223
    238 rdf:type schema:CreativeWork
    239 https://doi.org/10.1039/c39920001386 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030574054
    240 rdf:type schema:CreativeWork
    241 https://doi.org/10.1039/c3cc45416a schema:sameAs https://app.dimensions.ai/details/publication/pub.1023875048
    242 rdf:type schema:CreativeWork
    243 https://doi.org/10.1039/c4nr02716g schema:sameAs https://app.dimensions.ai/details/publication/pub.1021100177
    244 rdf:type schema:CreativeWork
    245 https://doi.org/10.1039/c5cc00803d schema:sameAs https://app.dimensions.ai/details/publication/pub.1043018480
    246 rdf:type schema:CreativeWork
    247 https://doi.org/10.1039/c5ta06840a schema:sameAs https://app.dimensions.ai/details/publication/pub.1053137141
    248 rdf:type schema:CreativeWork
    249 https://doi.org/10.1039/c6cc07832j schema:sameAs https://app.dimensions.ai/details/publication/pub.1008471902
    250 rdf:type schema:CreativeWork
    251 https://doi.org/10.1039/c6nr04775k schema:sameAs https://app.dimensions.ai/details/publication/pub.1013339361
    252 rdf:type schema:CreativeWork
    253 https://doi.org/10.1039/c6ta09409k schema:sameAs https://app.dimensions.ai/details/publication/pub.1018526455
    254 rdf:type schema:CreativeWork
    255 https://doi.org/10.1039/c6tc05097b schema:sameAs https://app.dimensions.ai/details/publication/pub.1083890224
    256 rdf:type schema:CreativeWork
    257 https://doi.org/10.1039/c7nr04922f schema:sameAs https://app.dimensions.ai/details/publication/pub.1091283539
    258 rdf:type schema:CreativeWork
    259 https://doi.org/10.1039/c8ce00159f schema:sameAs https://app.dimensions.ai/details/publication/pub.1101142882
    260 rdf:type schema:CreativeWork
    261 https://doi.org/10.1103/physrevlett.111.136804 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040853259
    262 rdf:type schema:CreativeWork
    263 https://doi.org/10.1126/science.1256815 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048460404
    264 rdf:type schema:CreativeWork
    265 https://www.grid.ac/institutes/grid.7445.2 schema:alternateName Imperial College London
    266 schema:name Department of Materials, Imperial College London, SW7 2AZ, London, UK
    267 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...