A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-02-05

AUTHORS

Jinqiang Zhang, Bing Sun, Yufei Zhao, Anastasia Tkacheva, Zhenjie Liu, Kang Yan, Xin Guo, Andrew M. McDonagh, Devaraj Shanmukaraj, Chengyin Wang, Teofilo Rojo, Michel Armand, Zhangquan Peng, Guoxiu Wang

ABSTRACT

Due to the high theoretical specific energy, the lithium-oxygen battery has been heralded as a promising energy storage system for applications such as electric vehicles. However, its large over-potentials during discharge-charge cycling lead to the formation of side-products, and short cycle life. Herein, we report an ionic liquid bearing the redox active 2,2,6,6-tetramethyl-1-piperidinyloxy moiety, which serves multiple functions as redox mediator, oxygen shuttle, lithium anode protector, as well as electrolyte solvent. The additive contributes a 33-fold increase of the discharge capacity in comparison to a pure ether-based electrolyte and lowers the over-potential to an exceptionally low value of 0.9 V. Meanwhile, its molecule facilitates smooth lithium plating/stripping, and promotes the formation of a stable solid electrolyte interface to suppress side-reactions. Moreover, the proportion of ionic liquid in the electrolyte influences the reaction mechanism, and a high proportion leads to the formation of amorphous lithium peroxide and a long cycling life (> 200 cycles). In particular, it enables an outstanding electrochemical performance when operated in air. More... »

PAGES

602

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-019-08422-8

DOI

http://dx.doi.org/10.1038/s41467-019-08422-8

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https://app.dimensions.ai/details/publication/pub.1111906439

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30723193


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79 reaction mechanism
80 redox
81 redox mediator
82 short cycle life
83 shuttle
84 smooth lithium
85 solid electrolyte interface
86 solution-mediated performances
87 solvent
88 specific energy
89 stable solid electrolyte interface
90 storage system
91 stripping
92 system
93 tetramethyl-1-piperidinyloxy moiety
94 theoretical specific energy
95 values
96 vehicles
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