A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-02-05

AUTHORS

Jinqiang Zhang, Bing Sun, Yufei Zhao, Anastasia Tkacheva, Zhenjie Liu, Kang Yan, Xin Guo, Andrew M. McDonagh, Devaraj Shanmukaraj, Chengyin Wang, Teofilo Rojo, Michel Armand, Zhangquan Peng, Guoxiu Wang

ABSTRACT

Due to the high theoretical specific energy, the lithium-oxygen battery has been heralded as a promising energy storage system for applications such as electric vehicles. However, its large over-potentials during discharge-charge cycling lead to the formation of side-products, and short cycle life. Herein, we report an ionic liquid bearing the redox active 2,2,6,6-tetramethyl-1-piperidinyloxy moiety, which serves multiple functions as redox mediator, oxygen shuttle, lithium anode protector, as well as electrolyte solvent. The additive contributes a 33-fold increase of the discharge capacity in comparison to a pure ether-based electrolyte and lowers the over-potential to an exceptionally low value of 0.9 V. Meanwhile, its molecule facilitates smooth lithium plating/stripping, and promotes the formation of a stable solid electrolyte interface to suppress side-reactions. Moreover, the proportion of ionic liquid in the electrolyte influences the reaction mechanism, and a high proportion leads to the formation of amorphous lithium peroxide and a long cycling life (> 200 cycles). In particular, it enables an outstanding electrochemical performance when operated in air. More... »

PAGES

602

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-019-08422-8

DOI

http://dx.doi.org/10.1038/s41467-019-08422-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111906439

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30723193


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Jinqiang", 
        "id": "sg:person.07347521713.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07347521713.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sun", 
        "givenName": "Bing", 
        "id": "sg:person.01172152477.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172152477.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Materials Science and Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808 People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.459466.c", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
            "Department of Materials Science and Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808 People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhao", 
        "givenName": "Yufei", 
        "id": "sg:person.01275144364.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01275144364.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tkacheva", 
        "givenName": "Anastasia", 
        "id": "sg:person.013300212607.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013300212607.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China", 
          "id": "http://www.grid.ac/institutes/grid.453213.2", 
          "name": [
            "State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Zhenjie", 
        "id": "sg:person.07677277760.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07677277760.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yan", 
        "givenName": "Kang", 
        "id": "sg:person.010764670711.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010764670711.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Guo", 
        "givenName": "Xin", 
        "id": "sg:person.016476112737.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016476112737.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "McDonagh", 
        "givenName": "Andrew M.", 
        "id": "sg:person.01246335136.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01246335136.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "CIC EnergiGUNE, Parque Tecnol\u00f3gico de \u00c1lava, 48, 01510 Mi\u00f1ano, \u00c1lava Spain", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "CIC EnergiGUNE, Parque Tecnol\u00f3gico de \u00c1lava, 48, 01510 Mi\u00f1ano, \u00c1lava Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shanmukaraj", 
        "givenName": "Devaraj", 
        "id": "sg:person.016051622266.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016051622266.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "College of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu, 225002 People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.268415.c", 
          "name": [
            "College of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu, 225002 People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Chengyin", 
        "id": "sg:person.01124547363.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01124547363.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "CIC EnergiGUNE, Parque Tecnol\u00f3gico de \u00c1lava, 48, 01510 Mi\u00f1ano, \u00c1lava Spain", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "CIC EnergiGUNE, Parque Tecnol\u00f3gico de \u00c1lava, 48, 01510 Mi\u00f1ano, \u00c1lava Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rojo", 
        "givenName": "Teofilo", 
        "id": "sg:person.0614402222.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0614402222.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "CIC EnergiGUNE, Parque Tecnol\u00f3gico de \u00c1lava, 48, 01510 Mi\u00f1ano, \u00c1lava Spain", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "CIC EnergiGUNE, Parque Tecnol\u00f3gico de \u00c1lava, 48, 01510 Mi\u00f1ano, \u00c1lava Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Armand", 
        "givenName": "Michel", 
        "id": "sg:person.01322540671.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01322540671.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China", 
          "id": "http://www.grid.ac/institutes/grid.453213.2", 
          "name": [
            "State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Peng", 
        "givenName": "Zhangquan", 
        "id": "sg:person.0727143347.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0727143347.14"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia", 
          "id": "http://www.grid.ac/institutes/grid.117476.2", 
          "name": [
            "Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Guoxiu", 
        "id": "sg:person.01253462737.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01253462737.51"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nature25984", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101634229", 
          "https://doi.org/10.1038/nature25984"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat3191", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029037852", 
          "https://doi.org/10.1038/nmat3191"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2132", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044085118", 
          "https://doi.org/10.1038/nchem.2132"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms12925", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039712601", 
          "https://doi.org/10.1038/ncomms12925"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nenergy.2016.128", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017811962", 
          "https://doi.org/10.1038/nenergy.2016.128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nenergy.2017.118", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090931136", 
          "https://doi.org/10.1038/nenergy.2017.118"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2101", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023506421", 
          "https://doi.org/10.1038/nchem.2101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.1646", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013223530", 
          "https://doi.org/10.1038/nchem.1646"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nenergy.2016.66", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002674100", 
          "https://doi.org/10.1038/nenergy.2016.66"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat4629", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032412790", 
          "https://doi.org/10.1038/nmat4629"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms3383", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040320141", 
          "https://doi.org/10.1038/ncomms3383"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-02-05", 
    "datePublishedReg": "2019-02-05", 
    "description": "Due to the high theoretical specific energy, the lithium-oxygen battery has been heralded as a promising energy storage system for applications such as electric vehicles. However, its large over-potentials during discharge-charge cycling lead to the formation of side-products, and short cycle life. Herein, we report an ionic liquid bearing the redox active 2,2,6,6-tetramethyl-1-piperidinyloxy moiety, which serves multiple functions as redox mediator, oxygen shuttle, lithium anode protector, as well as electrolyte solvent. The additive contributes a 33-fold increase of the discharge capacity in comparison to a pure ether-based electrolyte and lowers the over-potential to an exceptionally low value of 0.9 V. Meanwhile, its molecule facilitates smooth lithium plating/stripping, and promotes the formation of a stable solid electrolyte interface to suppress side-reactions. Moreover, the proportion of ionic liquid in the electrolyte influences the reaction mechanism, and a high proportion leads to the formation of amorphous lithium peroxide and a long cycling life (> 200 cycles). In particular, it enables an outstanding electrochemical performance when operated in air.", 
    "genre": "article", 
    "id": "sg:pub.10.1038/s41467-019-08422-8", 
    "inLanguage": "en", 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.5127874", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1043282", 
        "issn": [
          "2041-1723"
        ], 
        "name": "Nature Communications", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "10"
      }
    ], 
    "keywords": [
      "lithium-oxygen batteries", 
      "ionic liquids", 
      "high theoretical specific energy", 
      "promising energy storage system", 
      "stable solid electrolyte interface", 
      "ether-based electrolyte", 
      "theoretical specific energy", 
      "outstanding electrochemical performance", 
      "solid electrolyte interface", 
      "long cycling life", 
      "short cycle life", 
      "electrolyte solvent", 
      "electrochemical performance", 
      "lithium peroxide", 
      "redox mediator", 
      "electrolyte interface", 
      "discharge capacity", 
      "oxygen shuttle", 
      "cycle life", 
      "cycling life", 
      "electrolyte influence", 
      "reaction mechanism", 
      "specific energy", 
      "cycling lead", 
      "energy storage system", 
      "liquid", 
      "batteries", 
      "electrolyte", 
      "formation", 
      "solvent", 
      "moiety", 
      "redox", 
      "molecules", 
      "storage system", 
      "peroxide", 
      "lithium", 
      "Herein", 
      "electric vehicles", 
      "potential", 
      "stripping", 
      "shuttle", 
      "air", 
      "interface", 
      "energy", 
      "lead", 
      "lower values", 
      "applications", 
      "capacity", 
      "multiple functions", 
      "performance", 
      "mechanism", 
      "influence", 
      "vehicles", 
      "values", 
      "system", 
      "increase", 
      "comparison", 
      "protectors", 
      "mediators", 
      "function", 
      "proportion", 
      "higher proportion", 
      "life", 
      "discharge-charge cycling lead", 
      "tetramethyl-1-piperidinyloxy moiety", 
      "lithium anode protector", 
      "anode protector", 
      "pure ether-based electrolyte", 
      "smooth lithium", 
      "amorphous lithium peroxide", 
      "solution-mediated performances"
    ], 
    "name": "A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries", 
    "pagination": "602", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1111906439"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/s41467-019-08422-8"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "30723193"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/s41467-019-08422-8", 
      "https://app.dimensions.ai/details/publication/pub.1111906439"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:44", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_829.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1038/s41467-019-08422-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08422-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08422-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08422-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-019-08422-8'


 

This table displays all metadata directly associated to this object as RDF triples.

290 TRIPLES      22 PREDICATES      110 URIs      89 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/s41467-019-08422-8 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 anzsrc-for:09
4 anzsrc-for:0912
5 schema:author Ndc1a5e6b7de644ea886e61f949922598
6 schema:citation sg:pub.10.1038/nature25984
7 sg:pub.10.1038/nchem.1646
8 sg:pub.10.1038/nchem.2101
9 sg:pub.10.1038/nchem.2132
10 sg:pub.10.1038/ncomms12925
11 sg:pub.10.1038/ncomms3383
12 sg:pub.10.1038/nenergy.2016.128
13 sg:pub.10.1038/nenergy.2016.66
14 sg:pub.10.1038/nenergy.2017.118
15 sg:pub.10.1038/nmat3191
16 sg:pub.10.1038/nmat4629
17 schema:datePublished 2019-02-05
18 schema:datePublishedReg 2019-02-05
19 schema:description Due to the high theoretical specific energy, the lithium-oxygen battery has been heralded as a promising energy storage system for applications such as electric vehicles. However, its large over-potentials during discharge-charge cycling lead to the formation of side-products, and short cycle life. Herein, we report an ionic liquid bearing the redox active 2,2,6,6-tetramethyl-1-piperidinyloxy moiety, which serves multiple functions as redox mediator, oxygen shuttle, lithium anode protector, as well as electrolyte solvent. The additive contributes a 33-fold increase of the discharge capacity in comparison to a pure ether-based electrolyte and lowers the over-potential to an exceptionally low value of 0.9 V. Meanwhile, its molecule facilitates smooth lithium plating/stripping, and promotes the formation of a stable solid electrolyte interface to suppress side-reactions. Moreover, the proportion of ionic liquid in the electrolyte influences the reaction mechanism, and a high proportion leads to the formation of amorphous lithium peroxide and a long cycling life (> 200 cycles). In particular, it enables an outstanding electrochemical performance when operated in air.
20 schema:genre article
21 schema:inLanguage en
22 schema:isAccessibleForFree true
23 schema:isPartOf N68bdb089252146ea8f34e434ad745142
24 N913776afc03f4508bbb5e141ace15975
25 sg:journal.1043282
26 schema:keywords Herein
27 air
28 amorphous lithium peroxide
29 anode protector
30 applications
31 batteries
32 capacity
33 comparison
34 cycle life
35 cycling lead
36 cycling life
37 discharge capacity
38 discharge-charge cycling lead
39 electric vehicles
40 electrochemical performance
41 electrolyte
42 electrolyte influence
43 electrolyte interface
44 electrolyte solvent
45 energy
46 energy storage system
47 ether-based electrolyte
48 formation
49 function
50 high theoretical specific energy
51 higher proportion
52 increase
53 influence
54 interface
55 ionic liquids
56 lead
57 life
58 liquid
59 lithium
60 lithium anode protector
61 lithium peroxide
62 lithium-oxygen batteries
63 long cycling life
64 lower values
65 mechanism
66 mediators
67 moiety
68 molecules
69 multiple functions
70 outstanding electrochemical performance
71 oxygen shuttle
72 performance
73 peroxide
74 potential
75 promising energy storage system
76 proportion
77 protectors
78 pure ether-based electrolyte
79 reaction mechanism
80 redox
81 redox mediator
82 short cycle life
83 shuttle
84 smooth lithium
85 solid electrolyte interface
86 solution-mediated performances
87 solvent
88 specific energy
89 stable solid electrolyte interface
90 storage system
91 stripping
92 system
93 tetramethyl-1-piperidinyloxy moiety
94 theoretical specific energy
95 values
96 vehicles
97 schema:name A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries
98 schema:pagination 602
99 schema:productId N6dd473c0fa9440c48cfabe6e5a35bfdc
100 N834496bfd5d94894be81b0e0b3bc86f1
101 Na59be201e5ea432c901eeac1b856eee3
102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1111906439
103 https://doi.org/10.1038/s41467-019-08422-8
104 schema:sdDatePublished 2021-12-01T19:44
105 schema:sdLicense https://scigraph.springernature.com/explorer/license/
106 schema:sdPublisher N60dbb3a02fdb42ab9769cc2b8704c466
107 schema:url https://doi.org/10.1038/s41467-019-08422-8
108 sgo:license sg:explorer/license/
109 sgo:sdDataset articles
110 rdf:type schema:ScholarlyArticle
111 N277e5d7db13e4fda896087f21152589d rdf:first sg:person.010764670711.22
112 rdf:rest Nc7bb3348d46a40fca2c03562cd5b1782
113 N491fd366cc7c460db58b7c94243fa9c0 rdf:first sg:person.07677277760.34
114 rdf:rest N277e5d7db13e4fda896087f21152589d
115 N58368b57388f42e392d98663933bd051 rdf:first sg:person.01253462737.51
116 rdf:rest rdf:nil
117 N60dbb3a02fdb42ab9769cc2b8704c466 schema:name Springer Nature - SN SciGraph project
118 rdf:type schema:Organization
119 N68bdb089252146ea8f34e434ad745142 schema:issueNumber 1
120 rdf:type schema:PublicationIssue
121 N6dd473c0fa9440c48cfabe6e5a35bfdc schema:name pubmed_id
122 schema:value 30723193
123 rdf:type schema:PropertyValue
124 N73209c233dd249caa3b5c0f72e310357 rdf:first sg:person.016051622266.08
125 rdf:rest Ne327663b6574437799de53b8ffdabd3f
126 N82600898aac341379ece1f7ee355ace8 rdf:first sg:person.0614402222.11
127 rdf:rest N98a7d2a7e3e647508048b6a332f1705e
128 N834496bfd5d94894be81b0e0b3bc86f1 schema:name dimensions_id
129 schema:value pub.1111906439
130 rdf:type schema:PropertyValue
131 N913776afc03f4508bbb5e141ace15975 schema:volumeNumber 10
132 rdf:type schema:PublicationVolume
133 N98a7d2a7e3e647508048b6a332f1705e rdf:first sg:person.01322540671.91
134 rdf:rest Na070d0c2384542a698cf298471bf3c51
135 Na070d0c2384542a698cf298471bf3c51 rdf:first sg:person.0727143347.14
136 rdf:rest N58368b57388f42e392d98663933bd051
137 Na59be201e5ea432c901eeac1b856eee3 schema:name doi
138 schema:value 10.1038/s41467-019-08422-8
139 rdf:type schema:PropertyValue
140 Na713cd3c7cf44182b82e3abe4028ab14 rdf:first sg:person.01172152477.12
141 rdf:rest Nd1ba1b0916bc47b59f238b2e1f53e762
142 Na735cc4cec1b4ddab65fdb7469410fc1 rdf:first sg:person.013300212607.52
143 rdf:rest N491fd366cc7c460db58b7c94243fa9c0
144 Nc7bb3348d46a40fca2c03562cd5b1782 rdf:first sg:person.016476112737.37
145 rdf:rest Nfce4edc2ca054c0f8b452566c7f235b7
146 Nd1ba1b0916bc47b59f238b2e1f53e762 rdf:first sg:person.01275144364.94
147 rdf:rest Na735cc4cec1b4ddab65fdb7469410fc1
148 Ndc1a5e6b7de644ea886e61f949922598 rdf:first sg:person.07347521713.75
149 rdf:rest Na713cd3c7cf44182b82e3abe4028ab14
150 Ne327663b6574437799de53b8ffdabd3f rdf:first sg:person.01124547363.63
151 rdf:rest N82600898aac341379ece1f7ee355ace8
152 Nfce4edc2ca054c0f8b452566c7f235b7 rdf:first sg:person.01246335136.28
153 rdf:rest N73209c233dd249caa3b5c0f72e310357
154 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
155 schema:name Chemical Sciences
156 rdf:type schema:DefinedTerm
157 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
158 schema:name Physical Chemistry (incl. Structural)
159 rdf:type schema:DefinedTerm
160 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
161 schema:name Engineering
162 rdf:type schema:DefinedTerm
163 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
164 schema:name Materials Engineering
165 rdf:type schema:DefinedTerm
166 sg:grant.5127874 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-019-08422-8
167 rdf:type schema:MonetaryGrant
168 sg:journal.1043282 schema:issn 2041-1723
169 schema:name Nature Communications
170 schema:publisher Springer Nature
171 rdf:type schema:Periodical
172 sg:person.010764670711.22 schema:affiliation grid-institutes:grid.117476.2
173 schema:familyName Yan
174 schema:givenName Kang
175 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010764670711.22
176 rdf:type schema:Person
177 sg:person.01124547363.63 schema:affiliation grid-institutes:grid.268415.c
178 schema:familyName Wang
179 schema:givenName Chengyin
180 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01124547363.63
181 rdf:type schema:Person
182 sg:person.01172152477.12 schema:affiliation grid-institutes:grid.117476.2
183 schema:familyName Sun
184 schema:givenName Bing
185 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172152477.12
186 rdf:type schema:Person
187 sg:person.01246335136.28 schema:affiliation grid-institutes:grid.117476.2
188 schema:familyName McDonagh
189 schema:givenName Andrew M.
190 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01246335136.28
191 rdf:type schema:Person
192 sg:person.01253462737.51 schema:affiliation grid-institutes:grid.117476.2
193 schema:familyName Wang
194 schema:givenName Guoxiu
195 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01253462737.51
196 rdf:type schema:Person
197 sg:person.01275144364.94 schema:affiliation grid-institutes:grid.459466.c
198 schema:familyName Zhao
199 schema:givenName Yufei
200 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01275144364.94
201 rdf:type schema:Person
202 sg:person.01322540671.91 schema:affiliation grid-institutes:None
203 schema:familyName Armand
204 schema:givenName Michel
205 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01322540671.91
206 rdf:type schema:Person
207 sg:person.013300212607.52 schema:affiliation grid-institutes:grid.117476.2
208 schema:familyName Tkacheva
209 schema:givenName Anastasia
210 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013300212607.52
211 rdf:type schema:Person
212 sg:person.016051622266.08 schema:affiliation grid-institutes:None
213 schema:familyName Shanmukaraj
214 schema:givenName Devaraj
215 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016051622266.08
216 rdf:type schema:Person
217 sg:person.016476112737.37 schema:affiliation grid-institutes:grid.117476.2
218 schema:familyName Guo
219 schema:givenName Xin
220 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016476112737.37
221 rdf:type schema:Person
222 sg:person.0614402222.11 schema:affiliation grid-institutes:None
223 schema:familyName Rojo
224 schema:givenName Teofilo
225 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0614402222.11
226 rdf:type schema:Person
227 sg:person.0727143347.14 schema:affiliation grid-institutes:grid.453213.2
228 schema:familyName Peng
229 schema:givenName Zhangquan
230 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0727143347.14
231 rdf:type schema:Person
232 sg:person.07347521713.75 schema:affiliation grid-institutes:grid.117476.2
233 schema:familyName Zhang
234 schema:givenName Jinqiang
235 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07347521713.75
236 rdf:type schema:Person
237 sg:person.07677277760.34 schema:affiliation grid-institutes:grid.453213.2
238 schema:familyName Liu
239 schema:givenName Zhenjie
240 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07677277760.34
241 rdf:type schema:Person
242 sg:pub.10.1038/nature25984 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101634229
243 https://doi.org/10.1038/nature25984
244 rdf:type schema:CreativeWork
245 sg:pub.10.1038/nchem.1646 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013223530
246 https://doi.org/10.1038/nchem.1646
247 rdf:type schema:CreativeWork
248 sg:pub.10.1038/nchem.2101 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023506421
249 https://doi.org/10.1038/nchem.2101
250 rdf:type schema:CreativeWork
251 sg:pub.10.1038/nchem.2132 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044085118
252 https://doi.org/10.1038/nchem.2132
253 rdf:type schema:CreativeWork
254 sg:pub.10.1038/ncomms12925 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039712601
255 https://doi.org/10.1038/ncomms12925
256 rdf:type schema:CreativeWork
257 sg:pub.10.1038/ncomms3383 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040320141
258 https://doi.org/10.1038/ncomms3383
259 rdf:type schema:CreativeWork
260 sg:pub.10.1038/nenergy.2016.128 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017811962
261 https://doi.org/10.1038/nenergy.2016.128
262 rdf:type schema:CreativeWork
263 sg:pub.10.1038/nenergy.2016.66 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002674100
264 https://doi.org/10.1038/nenergy.2016.66
265 rdf:type schema:CreativeWork
266 sg:pub.10.1038/nenergy.2017.118 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090931136
267 https://doi.org/10.1038/nenergy.2017.118
268 rdf:type schema:CreativeWork
269 sg:pub.10.1038/nmat3191 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029037852
270 https://doi.org/10.1038/nmat3191
271 rdf:type schema:CreativeWork
272 sg:pub.10.1038/nmat4629 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032412790
273 https://doi.org/10.1038/nmat4629
274 rdf:type schema:CreativeWork
275 grid-institutes:None schema:alternateName CIC EnergiGUNE, Parque Tecnológico de Álava, 48, 01510 Miñano, Álava Spain
276 schema:name CIC EnergiGUNE, Parque Tecnológico de Álava, 48, 01510 Miñano, Álava Spain
277 rdf:type schema:Organization
278 grid-institutes:grid.117476.2 schema:alternateName Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia
279 schema:name Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia
280 rdf:type schema:Organization
281 grid-institutes:grid.268415.c schema:alternateName College of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu, 225002 People’s Republic of China
282 schema:name College of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu, 225002 People’s Republic of China
283 rdf:type schema:Organization
284 grid-institutes:grid.453213.2 schema:alternateName State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
285 schema:name State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
286 rdf:type schema:Organization
287 grid-institutes:grid.459466.c schema:alternateName Department of Materials Science and Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808 People’s Republic of China
288 schema:name Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW 2007 Australia
289 Department of Materials Science and Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808 People’s Republic of China
290 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...