Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Tomoki Ogoshi, Ryuta Sueto, Masafumi Yagyu, Ryosuke Kojima, Takahiro Kakuta, Tada-aki Yamagishi, Kazuki Doitomi, Anil Kumar Tummanapelli, Hajime Hirao, Yoko Sakata, Shigehisa Akine, Motohiro Mizuno

ABSTRACT

Confinement of polymers in nano-spaces can induce unique molecular dynamics and properties. Here we show molecular weight fractionation by the confinement of single polymer chains of poly(ethylene oxide) (PEO) in the one-dimensional (1D) channels of crystalline pillar[5]arene. Pillar[5]arene crystals are activated by heating under reduced pressure. The activated crystals are immersed in melted PEO, causing the crystals to selectively take up PEO with high mass fraction. The high mass fractionation is caused by the greater number of attractive CH/π interactions between PEO C-H groups and the π-electron-rich 1D channel of the pillar[5]arene with increasing PEO chain length. The molecular motion of the confined PEO (PEO chain thickness of ~3.7 Å) in the 1D channel of pillar[5]arenes (diameter of ~4.7 Å) is highly restricted compared with that of neat PEO. More... »

PAGES

479

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-019-08372-1

DOI

http://dx.doi.org/10.1038/s41467-019-08372-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111767073

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30696824


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Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

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