Ontology type: schema:ScholarlyArticle Open Access: True
2018-12
AUTHORSYifei Xu, Koen C. H. Tijssen, Paul H. H. Bomans, Anat Akiva, Heiner Friedrich, Arno P. M. Kentgens, Nico A. J. M. Sommerdijk
ABSTRACTMany biomineral crystals form complex non-equilibrium shapes, often via transient amorphous precursors. Also in vitro crystals can be grown with non-equilibrium morphologies, such as thin films or nanorods. In many cases this involves charged polymeric additives that form a polymer-induced liquid precursor (PILP). Here, we investigate the CaCO3 based PILP process with a variety of techniques including cryoTEM and NMR. The initial products are 30-50 nm amorphous calcium carbonate (ACC) nanoparticles with ~2 nm nanoparticulate texture. We show the polymers strongly interact with ACC in the early stages, and become excluded during crystallization, with no liquid-liquid phase separation detected during the process. Our results suggest that "PILP" is actually a polymer-driven assembly of ACC clusters, and that its liquid-like behavior at the macroscopic level is due to the small size and surface properties of the assemblies. We propose that a similar biopolymer-stabilized nanogranular phase may be active in biomineralization. More... »
PAGES2582
http://scigraph.springernature.com/pub.10.1038/s41467-018-05006-w
DOIhttp://dx.doi.org/10.1038/s41467-018-05006-w
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PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/29968713
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