Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2018-05-29

AUTHORS

Ashley J. Wooles, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Gareth T. W. Law, Adam J. Fuller, Felipe Kremer, Mark Ridgway, William Lewis, Laura Gagliardi, Bess Vlaisavljevich, Stephen T. Liddle

ABSTRACT

Despite the fact that non-aqueous uranium chemistry is over 60 years old, most polarised-covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and VI. The paucity of uranium(III) congeners is because, in common with metal-ligand multiple bonding generally, such linkages involve strongly donating, charge-loaded ligands that bind best to electron-poor metals and inherently promote disproportionation of uranium(III). Here, we report the synthesis of hexauranium-methanediide nanometre-scale rings. Combined experimental and computational studies suggest overall the presence of formal uranium(III) and (IV) ions, though electron delocalisation in this Kramers system cannot be definitively ruled out, and the resulting polarised-covalent U = C bonds are supported by iodide and δ-bonded arene bridges. The arenes provide reservoirs that accommodate charge, thus avoiding inter-electronic repulsion that would destabilise these low oxidation state metal-ligand multiple bonds. Using arenes as electronic buffers could constitute a general synthetic strategy by which to stabilise otherwise inherently unstable metal-ligand linkages. More... »

PAGES

2097

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-018-04560-7

DOI

http://dx.doi.org/10.1038/s41467-018-04560-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1104192193

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/29844376


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wooles", 
        "givenName": "Ashley J.", 
        "id": "sg:person.0627703471.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0627703471.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mills", 
        "givenName": "David P.", 
        "id": "sg:person.0736207041.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0736207041.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tuna", 
        "givenName": "Floriana", 
        "id": "sg:person.0750046556.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0750046556.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "McInnes", 
        "givenName": "Eric J. L.", 
        "id": "sg:person.015541514657.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015541514657.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Law", 
        "givenName": "Gareth T. W.", 
        "id": "sg:person.01305606655.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01305606655.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fuller", 
        "givenName": "Adam J.", 
        "id": "sg:person.010225650662.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010225650662.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, 2601, Canberra, ACT, Australia", 
          "id": "http://www.grid.ac/institutes/grid.1001.0", 
          "name": [
            "Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, 2601, Canberra, ACT, Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kremer", 
        "givenName": "Felipe", 
        "id": "sg:person.011211636267.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011211636267.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, 2601, Canberra, ACT, Australia", 
          "id": "http://www.grid.ac/institutes/grid.1001.0", 
          "name": [
            "Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, 2601, Canberra, ACT, Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ridgway", 
        "givenName": "Mark", 
        "id": "sg:person.0733162102.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0733162102.95"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry, University Park, University of Nottingham, NG7 2RD, Nottingham, UK", 
          "id": "http://www.grid.ac/institutes/grid.4563.4", 
          "name": [
            "School of Chemistry, University Park, University of Nottingham, NG7 2RD, Nottingham, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lewis", 
        "givenName": "William", 
        "id": "sg:person.01254243147.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01254243147.65"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Supercomputing Institute and Chemical Theory Center, University of Minnesota, 207 Pleasant Street SE, 55455, Minneapolis, MN, USA", 
          "id": "http://www.grid.ac/institutes/grid.17635.36", 
          "name": [
            "Department of Chemistry, Supercomputing Institute and Chemical Theory Center, University of Minnesota, 207 Pleasant Street SE, 55455, Minneapolis, MN, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gagliardi", 
        "givenName": "Laura", 
        "id": "sg:person.01061612032.32", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01061612032.32"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of South Dakota, 414 E Clark Street, 57069, Vermillion, SD, USA", 
          "id": "http://www.grid.ac/institutes/grid.267169.d", 
          "name": [
            "Department of Chemistry, Supercomputing Institute and Chemical Theory Center, University of Minnesota, 207 Pleasant Street SE, 55455, Minneapolis, MN, USA", 
            "Department of Chemistry, University of South Dakota, 414 E Clark Street, 57069, Vermillion, SD, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vlaisavljevich", 
        "givenName": "Bess", 
        "id": "sg:person.0676340537.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0676340537.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK", 
          "id": "http://www.grid.ac/institutes/grid.5379.8", 
          "name": [
            "School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liddle", 
        "givenName": "Stephen T.", 
        "id": "sg:person.0701217443.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0701217443.37"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nchem.2692", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018392398", 
          "https://doi.org/10.1038/nchem.2692"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms16053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090358002", 
          "https://doi.org/10.1038/ncomms16053"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms14137", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083524744", 
          "https://doi.org/10.1038/ncomms14137"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.2777", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085211385", 
          "https://doi.org/10.1038/nchem.2777"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.1028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040056200", 
          "https://doi.org/10.1038/nchem.1028"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-05-29", 
    "datePublishedReg": "2018-05-29", 
    "description": "Despite the fact that non-aqueous uranium chemistry is over 60 years old, most polarised-covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and VI. The paucity of uranium(III) congeners is because, in common with metal-ligand multiple bonding generally, such linkages involve strongly donating, charge-loaded ligands that bind best to electron-poor metals and inherently promote disproportionation of uranium(III). Here, we report the synthesis of hexauranium-methanediide nanometre-scale rings. Combined experimental and computational studies suggest overall the presence of formal uranium(III) and (IV) ions, though electron delocalisation in this Kramers system cannot be definitively ruled out, and the resulting polarised-covalent U\u2009=\u2009C bonds are supported by iodide and \u03b4-bonded arene bridges. The arenes provide reservoirs that accommodate charge, thus avoiding inter-electronic repulsion that would destabilise these low oxidation state metal-ligand multiple bonds. Using arenes as electronic buffers could constitute a general synthetic strategy by which to stabilise otherwise inherently unstable metal-ligand linkages.", 
    "genre": "article", 
    "id": "sg:pub.10.1038/s41467-018-04560-7", 
    "inLanguage": "en", 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.3797781", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.3957945", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.2771597", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.4319810", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.5498240", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.4057637", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.3789243", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1043282", 
        "issn": [
          "2041-1723"
        ], 
        "name": "Nature Communications", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "9"
      }
    ], 
    "keywords": [
      "multiple bonding", 
      "multiple bonds", 
      "metal-ligand multiple bonding", 
      "metal-ligand multiple bonds", 
      "general synthetic strategy", 
      "oxidation state IV", 
      "uranium chemistry", 
      "synthetic strategy", 
      "\u03b4 bonding", 
      "electron delocalisation", 
      "C bond", 
      "inter-electronic repulsion", 
      "computational study", 
      "state IV", 
      "bonds", 
      "arenes", 
      "bonding", 
      "Kramers system", 
      "ring", 
      "chemistry", 
      "disproportionation", 
      "delocalisation", 
      "ligands", 
      "ions", 
      "synthesis", 
      "repulsion", 
      "iodide", 
      "metals", 
      "charge", 
      "linkage", 
      "scale rings", 
      "buffer", 
      "congeners", 
      "electronic buffers", 
      "bridge", 
      "binds", 
      "presence", 
      "system", 
      "strategies", 
      "such linkages", 
      "study", 
      "reservoir", 
      "fact", 
      "years", 
      "paucity"
    ], 
    "name": "Uranium(III)-carbon multiple bonding supported by arene \u03b4-bonding in mixed-valence hexauranium nanometre-scale rings", 
    "pagination": "2097", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1104192193"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/s41467-018-04560-7"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "29844376"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/s41467-018-04560-7", 
      "https://app.dimensions.ai/details/publication/pub.1104192193"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-06-01T22:18", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_785.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1038/s41467-018-04560-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-018-04560-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-018-04560-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-018-04560-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-018-04560-7'


 

This table displays all metadata directly associated to this object as RDF triples.

232 TRIPLES      22 PREDICATES      76 URIs      63 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/s41467-018-04560-7 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N21cf3dde7b3942f1badbca41078b4247
4 schema:citation sg:pub.10.1038/nchem.1028
5 sg:pub.10.1038/nchem.2692
6 sg:pub.10.1038/nchem.2777
7 sg:pub.10.1038/ncomms14137
8 sg:pub.10.1038/ncomms16053
9 schema:datePublished 2018-05-29
10 schema:datePublishedReg 2018-05-29
11 schema:description Despite the fact that non-aqueous uranium chemistry is over 60 years old, most polarised-covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and VI. The paucity of uranium(III) congeners is because, in common with metal-ligand multiple bonding generally, such linkages involve strongly donating, charge-loaded ligands that bind best to electron-poor metals and inherently promote disproportionation of uranium(III). Here, we report the synthesis of hexauranium-methanediide nanometre-scale rings. Combined experimental and computational studies suggest overall the presence of formal uranium(III) and (IV) ions, though electron delocalisation in this Kramers system cannot be definitively ruled out, and the resulting polarised-covalent U = C bonds are supported by iodide and δ-bonded arene bridges. The arenes provide reservoirs that accommodate charge, thus avoiding inter-electronic repulsion that would destabilise these low oxidation state metal-ligand multiple bonds. Using arenes as electronic buffers could constitute a general synthetic strategy by which to stabilise otherwise inherently unstable metal-ligand linkages.
12 schema:genre article
13 schema:inLanguage en
14 schema:isAccessibleForFree true
15 schema:isPartOf N2a937f9a7f294cd3b6ad689274eb048d
16 N3ef84b6e6e0f4523b2ea7a425ec883ce
17 sg:journal.1043282
18 schema:keywords C bond
19 Kramers system
20 arenes
21 binds
22 bonding
23 bonds
24 bridge
25 buffer
26 charge
27 chemistry
28 computational study
29 congeners
30 delocalisation
31 disproportionation
32 electron delocalisation
33 electronic buffers
34 fact
35 general synthetic strategy
36 inter-electronic repulsion
37 iodide
38 ions
39 ligands
40 linkage
41 metal-ligand multiple bonding
42 metal-ligand multiple bonds
43 metals
44 multiple bonding
45 multiple bonds
46 oxidation state IV
47 paucity
48 presence
49 repulsion
50 reservoir
51 ring
52 scale rings
53 state IV
54 strategies
55 study
56 such linkages
57 synthesis
58 synthetic strategy
59 system
60 uranium chemistry
61 years
62 δ bonding
63 schema:name Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
64 schema:pagination 2097
65 schema:productId N8ee9832fed444d1990fc98ab41e61bd1
66 Nd656f61d8c004a79a9b0af0e115ba99f
67 Ne58325f8361d4c9e975eb48a7fc867af
68 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104192193
69 https://doi.org/10.1038/s41467-018-04560-7
70 schema:sdDatePublished 2022-06-01T22:18
71 schema:sdLicense https://scigraph.springernature.com/explorer/license/
72 schema:sdPublisher N3024fd0014a6490596148b1875c08755
73 schema:url https://doi.org/10.1038/s41467-018-04560-7
74 sgo:license sg:explorer/license/
75 sgo:sdDataset articles
76 rdf:type schema:ScholarlyArticle
77 N1d5ed0e8bced417db9ebe46c906ee395 rdf:first sg:person.010225650662.15
78 rdf:rest Nb8a571d449404894ad57bdc2ce7f6790
79 N21cf3dde7b3942f1badbca41078b4247 rdf:first sg:person.0627703471.90
80 rdf:rest N21f289e05eb2445cb10d10c6e8eaacda
81 N21f289e05eb2445cb10d10c6e8eaacda rdf:first sg:person.0736207041.27
82 rdf:rest N9b4f376fa3e540eb91607bda7a11a3ce
83 N2a937f9a7f294cd3b6ad689274eb048d schema:volumeNumber 9
84 rdf:type schema:PublicationVolume
85 N3024fd0014a6490596148b1875c08755 schema:name Springer Nature - SN SciGraph project
86 rdf:type schema:Organization
87 N32dd906f2d764987aa0d910bcf8b7cbf rdf:first sg:person.01254243147.65
88 rdf:rest Nfd436e764d874ed6b8e5a22582f81b6b
89 N3ef84b6e6e0f4523b2ea7a425ec883ce schema:issueNumber 1
90 rdf:type schema:PublicationIssue
91 N4d3aa60f97db4cd09cf0adbc9a4f330d rdf:first sg:person.0733162102.95
92 rdf:rest N32dd906f2d764987aa0d910bcf8b7cbf
93 N58ce3b67cf1445ec99e975bf55ed32d9 rdf:first sg:person.015541514657.63
94 rdf:rest N6253db414b5646c6a7d0e9de87ca8c5e
95 N6253db414b5646c6a7d0e9de87ca8c5e rdf:first sg:person.01305606655.22
96 rdf:rest N1d5ed0e8bced417db9ebe46c906ee395
97 N873b40c3e733490ca12e742b9d6afdd4 rdf:first sg:person.0676340537.03
98 rdf:rest Ne77c5e6d260c472688fa98e92eac3d10
99 N8ee9832fed444d1990fc98ab41e61bd1 schema:name pubmed_id
100 schema:value 29844376
101 rdf:type schema:PropertyValue
102 N9b4f376fa3e540eb91607bda7a11a3ce rdf:first sg:person.0750046556.15
103 rdf:rest N58ce3b67cf1445ec99e975bf55ed32d9
104 Nb8a571d449404894ad57bdc2ce7f6790 rdf:first sg:person.011211636267.31
105 rdf:rest N4d3aa60f97db4cd09cf0adbc9a4f330d
106 Nd656f61d8c004a79a9b0af0e115ba99f schema:name doi
107 schema:value 10.1038/s41467-018-04560-7
108 rdf:type schema:PropertyValue
109 Ne58325f8361d4c9e975eb48a7fc867af schema:name dimensions_id
110 schema:value pub.1104192193
111 rdf:type schema:PropertyValue
112 Ne77c5e6d260c472688fa98e92eac3d10 rdf:first sg:person.0701217443.37
113 rdf:rest rdf:nil
114 Nfd436e764d874ed6b8e5a22582f81b6b rdf:first sg:person.01061612032.32
115 rdf:rest N873b40c3e733490ca12e742b9d6afdd4
116 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
117 schema:name Chemical Sciences
118 rdf:type schema:DefinedTerm
119 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
120 schema:name Inorganic Chemistry
121 rdf:type schema:DefinedTerm
122 sg:grant.2771597 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
123 rdf:type schema:MonetaryGrant
124 sg:grant.3789243 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
125 rdf:type schema:MonetaryGrant
126 sg:grant.3797781 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
127 rdf:type schema:MonetaryGrant
128 sg:grant.3957945 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
129 rdf:type schema:MonetaryGrant
130 sg:grant.4057637 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
131 rdf:type schema:MonetaryGrant
132 sg:grant.4319810 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
133 rdf:type schema:MonetaryGrant
134 sg:grant.5498240 http://pending.schema.org/fundedItem sg:pub.10.1038/s41467-018-04560-7
135 rdf:type schema:MonetaryGrant
136 sg:journal.1043282 schema:issn 2041-1723
137 schema:name Nature Communications
138 schema:publisher Springer Nature
139 rdf:type schema:Periodical
140 sg:person.010225650662.15 schema:affiliation grid-institutes:grid.5379.8
141 schema:familyName Fuller
142 schema:givenName Adam J.
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010225650662.15
144 rdf:type schema:Person
145 sg:person.01061612032.32 schema:affiliation grid-institutes:grid.17635.36
146 schema:familyName Gagliardi
147 schema:givenName Laura
148 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01061612032.32
149 rdf:type schema:Person
150 sg:person.011211636267.31 schema:affiliation grid-institutes:grid.1001.0
151 schema:familyName Kremer
152 schema:givenName Felipe
153 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011211636267.31
154 rdf:type schema:Person
155 sg:person.01254243147.65 schema:affiliation grid-institutes:grid.4563.4
156 schema:familyName Lewis
157 schema:givenName William
158 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01254243147.65
159 rdf:type schema:Person
160 sg:person.01305606655.22 schema:affiliation grid-institutes:grid.5379.8
161 schema:familyName Law
162 schema:givenName Gareth T. W.
163 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01305606655.22
164 rdf:type schema:Person
165 sg:person.015541514657.63 schema:affiliation grid-institutes:grid.5379.8
166 schema:familyName McInnes
167 schema:givenName Eric J. L.
168 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015541514657.63
169 rdf:type schema:Person
170 sg:person.0627703471.90 schema:affiliation grid-institutes:grid.5379.8
171 schema:familyName Wooles
172 schema:givenName Ashley J.
173 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0627703471.90
174 rdf:type schema:Person
175 sg:person.0676340537.03 schema:affiliation grid-institutes:grid.267169.d
176 schema:familyName Vlaisavljevich
177 schema:givenName Bess
178 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0676340537.03
179 rdf:type schema:Person
180 sg:person.0701217443.37 schema:affiliation grid-institutes:grid.5379.8
181 schema:familyName Liddle
182 schema:givenName Stephen T.
183 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0701217443.37
184 rdf:type schema:Person
185 sg:person.0733162102.95 schema:affiliation grid-institutes:grid.1001.0
186 schema:familyName Ridgway
187 schema:givenName Mark
188 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0733162102.95
189 rdf:type schema:Person
190 sg:person.0736207041.27 schema:affiliation grid-institutes:grid.5379.8
191 schema:familyName Mills
192 schema:givenName David P.
193 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0736207041.27
194 rdf:type schema:Person
195 sg:person.0750046556.15 schema:affiliation grid-institutes:grid.5379.8
196 schema:familyName Tuna
197 schema:givenName Floriana
198 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0750046556.15
199 rdf:type schema:Person
200 sg:pub.10.1038/nchem.1028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040056200
201 https://doi.org/10.1038/nchem.1028
202 rdf:type schema:CreativeWork
203 sg:pub.10.1038/nchem.2692 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018392398
204 https://doi.org/10.1038/nchem.2692
205 rdf:type schema:CreativeWork
206 sg:pub.10.1038/nchem.2777 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085211385
207 https://doi.org/10.1038/nchem.2777
208 rdf:type schema:CreativeWork
209 sg:pub.10.1038/ncomms14137 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083524744
210 https://doi.org/10.1038/ncomms14137
211 rdf:type schema:CreativeWork
212 sg:pub.10.1038/ncomms16053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090358002
213 https://doi.org/10.1038/ncomms16053
214 rdf:type schema:CreativeWork
215 grid-institutes:grid.1001.0 schema:alternateName Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, 2601, Canberra, ACT, Australia
216 schema:name Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, 2601, Canberra, ACT, Australia
217 rdf:type schema:Organization
218 grid-institutes:grid.17635.36 schema:alternateName Department of Chemistry, Supercomputing Institute and Chemical Theory Center, University of Minnesota, 207 Pleasant Street SE, 55455, Minneapolis, MN, USA
219 schema:name Department of Chemistry, Supercomputing Institute and Chemical Theory Center, University of Minnesota, 207 Pleasant Street SE, 55455, Minneapolis, MN, USA
220 rdf:type schema:Organization
221 grid-institutes:grid.267169.d schema:alternateName Department of Chemistry, University of South Dakota, 414 E Clark Street, 57069, Vermillion, SD, USA
222 schema:name Department of Chemistry, Supercomputing Institute and Chemical Theory Center, University of Minnesota, 207 Pleasant Street SE, 55455, Minneapolis, MN, USA
223 Department of Chemistry, University of South Dakota, 414 E Clark Street, 57069, Vermillion, SD, USA
224 rdf:type schema:Organization
225 grid-institutes:grid.4563.4 schema:alternateName School of Chemistry, University Park, University of Nottingham, NG7 2RD, Nottingham, UK
226 schema:name School of Chemistry, University Park, University of Nottingham, NG7 2RD, Nottingham, UK
227 rdf:type schema:Organization
228 grid-institutes:grid.5379.8 schema:alternateName School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK
229 School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK
230 schema:name School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK
231 School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK
232 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...